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《Acta Physico-chimica Sinica》 2003-12
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Study on the Relationship between Charge and Structure of Montmorillonite

Hu Xiu Rong LüGuang Lie Gu Jian Ming Chen Lin Shen (Central Laboratory of Zhejiang University, Hangzhou 310028)  
Chemical composition analysis, CEC method, and alkylammonium method were used to study the charge density and distribution of 12 montmorillonite samples coming from different sources. The results show that the total charge of all dioctahedron montmorillonites is between 0.40 to 0.45 eq/[(Al,Si)4O10], but the layer charge and the variable surface charge vary with the ratio of Al/Mg in octahedron. For the montmorillonites with lower layer charge and higher variable surface charge, the occupancy of Al and Mg in the octahedron site is above 1.5 and 0.3~0.4 respectively, while for the montmorillonites with higher layer charge and lower variable surface charge, the occupancy of that is 1.3~1.4 and about 0.3 respectively. Charge that mostly origin from Mg2+substituting Al3+in octahedron and Al3+substituting Si4+in tetrahedron is mainly related to Mg content and Al/Mg ratio in montmorillonites. Generally, montmorillonites with higher Mg content have higher charge. The difference of Al/Mg ratio and Fe content accounts for the structural variety, charge and physicochemical property of montmorillonites.
【Fund】: 国家自然科学基金(59872008);; 浙江省自然科学基金(598102)资助项目~~
【CateGory Index】: O611
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【References】
Chinese Journal Full-text Database 10 Hits
1 MA Yu-long1,YANG Bo2 (1.College of Chemistry and Chemical Engineering,Ningxia University,Yinchuan 750021,China;2.College of Life Science,Ningxia University,Yinchuan 750021,China);Preparation and characterization of antibacterial Cu~(2+)-ZnO/cetylpyridinium-montmorillonite complexes[J];Journal of Functional Materials;2010-03
2 CAI Jia-jia1,2,XU Hui2,WANG Ai-qin1(1.Research and Development Center of Xuyi Attapulgite Applied Technology,Lanzhou Institute of Chemical Physics,Chinese Academy of Science,Lanzhou 730000,China; 2.College of Petrochemical Technology,Lanzhou University of Technology,Lanzhou 730050,China);Effects of Modification by Magnesium Acetate on Microstructure and Viscosity of Attapulgite Clay[J];Bulletin of the Chinese Ceramic Society;2012-03
3 MA Yulong , GUO Tong , XU Zirong , ZHAO Tang ( College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021; College of Life Science, Shanghai Fisheries University, Shanghai 200090; Institute of Feed Science, Zhejiang University, Hangzhou 310029, China);PREPARATION AND CHARACTERIZATION OF COPPER-LOADED MONTMORILLONITE[J];Journal of The Chinese Ceramic Society;2005-08
4 Chen Juxiang,Weng Yong,Zhang Haiyao(College of Structural and civil Engineering,Xinjiang University,Urumqi 830047,China);The Progress of Bentonite Purification[J];Guangdong Chemical Industry;2012-15
5 Xiang Niannian1 ZhuXiaping1* Tian Yingfeng1 Tan Jun1 Liu Wenhua2 Zhao Qiuxiang2 Li Haiping2(1 College of Materials and Chemistry & Chemical Engineering,Mineral Resources Chemistry Key Laboratory of Sichuan Higher Education Institutions,Chengdu University of Technology,Chengdu,Sichuan 610059;2 The Material Test Center of Guangdong Province,Guangzhou,Guangdong 510080);Preparation,Characterization and Adsorption Ability to Cu~(2+),Ni~(2+),Cd~(2+) of Amine-modified Bentonite[J];Non-Metallic Mines;2013-04
6 LIU Xiaowen;GAO Haiqing;ZHAO Huang;LIU Xiaoxu;School of Resources Processing and Bioengineering,Central South University;;Study on the Thermal Action of Ni/Al-pillared Montmorillionite[J];Materials Review;2014-06
7 Hao Lixia Wang Biaobing Hu Guosheng(Institute of Macromolecules & Bioengineering,North University of China,Taiyuan 030051);Preparation and characterization of the organic montmorillonite with 11-aminoundecanoic acid[J];New Chemical Materials;2010-03
8 SHI Hong-xing~(1, 2), LIU Hui-juan~1, QU Jiu-hui~1, DAI Rui-hua~(1, 3), WANG Ming-hua~(1, 3)(1.State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; 2.Graduate School of the Chinese Academy of Sciences,Beijing 100039,China;3.China University of Mining & Technology (Beijing), Beijing 100083,China);Property of Adsorption about Ammonium on Suspended Mineral Matters in Eutrophic Water[J];Environmental Science;2005-05
9 SUN Hong-juan1,2,PENG Tong-jiang1,LIU Ying2(1.Institute of Mineral Materials & Application,Southwest University of Science and Technology Mianyang,Sichuan 621010,China;2.College of Materials Science and Engineering,Sichuan University,Chengdu 610065,China);MEASUREMENT AND MECHANISM OF LAYER CHARGE OF PHYLLOSILICATE WITH EXPANSIVE LAYERS[J];Acta Mineralogica Sinica;2007-01
10 WANG Fei-fei1,WU Ye-chang1,YU Rui1,XU Chuan-yun21.HangZhou Institute of Municipal Construction Sciences,Hangzhou 310003,China;2.Zhejiang Institute of Geology and Mineral Resources,Hangzhou 310007,China;Microwave Induced Catalysis Treatment of Landfill Leachate Using Delaminated Iron-Pillared Montmorillonite as Catalyst[J];Bulletin of Mineralogy,Petrology and Geochemistry;2010-04
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Hu Xiurong , Lu Guanglie, Yang Yun (Centre Laboratory of Zhejiang University, Xixi Campus, Hangzhou 310028);Determination of Cation-exchange Capacity in Clay [Co(NH_3)_6]~( 3+) Exchange Method[J];Chinese Journal of Analytieal Chemistry;2000-11
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 LUO Li-qiang, MA Guang-zu and ZHAN Xiu-chun (National Research Center of Geoanalysis, Beijing, 100037);Geochemical analysis[J];Analytical Laboratory;2002-02
2 GUO Xin-feng,LI Yan,WANG Juan-fang,WANG Xiao-jun(Xinjiang Research Institute of Physics and Chemistry Technolagy,the Chinese Academy of Sciences,Urumqi 830011,China);Comparison of Several Measuring Methods for Bentonite Cation Exchange Capacity[J];Industrial Measurement;2008-01
3 RUAN Xiuxiu,ZHU Lizhong,CHEN Baoliang Department of Environmental Science,Zhejiang University,Ministry of Education Key Lab of Environmental Remediation and Ecosystem Health,Hangzhou 310028;The sorption of aromatic amines onto the interlayer siloxane surface of organobentonites[J];Acta Scientiae Circumstantiae;2009-04
4 CHEN, Jin-Yuan a,b PENG, Tu-Zhi ,a XIAO, Yan-Feng b ( a Department of Chemistry, Xixi Campus, Zhejiang University, Hangzhou 310028) ( b School of Vocational and Technique, Zhejiang University of Technology, Hangzhou 310014);Preparation of Titanium Dioxide/Bentonite Composite Material with High Activity and Study on Its Photo-catalysis[J];Acta Chimica Sinica;2003-08
5 WANG Wei-ying1,MA Li1,YUAN Xiao-zhu1,XIA Jian2,SHI Hui-ning2,SUN Yu-ying2(1.MOE Key Lab of Oil Gas Resources and Exploration Technology(Yangtze University),Jingzhou 434023,China;2.Petro China Huabei Oilfield Company,Renqiu 062550,China);Positive Ion Exchange Volume of Coal Bed Methane Reservoir and Influence to Coal Physical Natures[J];Coal Science and Technology;2011-09
6 Ying Tang;Hang Li;Xinmin Liu;Hualing Zhu;Rui Tian;Chongqing Key Laboratory of Soil Multi-Scale Interfacial Process, College of Resources and Environment, Southwest University;Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences;;Unraveling the size distributions of surface properties for purple soil and yellow soil[J];环境科学学报(英文版);2015-06
7 LIN Xiao-qin;WANG Yue-bo;ZHU Jian-xi;HE Hong-ping;Guangzhou Institute of Geochemistry, Chinese Academy of Sciences;Guangdong Provincial Key Laboratory of Mineral Physics and Materials;University of Chinese Academy of Sciences;;Preparation and Characterization of Acid Activated Montmorillonites for VOCs Removal[J];Acta Mineralogica Sinica;2015-03
8 Chen Baoliang 1Zhu Lizhong 1 Lin Bin 1 Tao Shu 2 (1 Department of Environmental Science, Zhejiang University, Hangzhou310028, C hina) (2 Department of Urban and Environmental Sciences, Peking University, Beijing1 00871, China);ENHANCEMENT OF CATIONIC SURFACTANT ON IMMOBILIZING P-NITROPHENOL AND PHEN OL IN SOILS[J];Acta Pedologica Sinica;2004-01
9 HUANG Baogui,ZHANG Zhiyong,YANG Lin,GAO Jing,LI Yuru,CHENG Shu(Changsha Research Institute of Mining and Metallurgy,Changsha,Hunan 410012,China);Recent Achievements on Chemical Phase Analysis in China(Second Half)[J];Chinese Journal of Inorganic Analytical Chemistry;2011-03
10 Wang Weiying(Key Laboratory of Exploration Technologies for Oil and Gas Resources(Yangtze University),Ministry of Education,Hubei 434023);Coalbed Methane′s CEC and Its Influence on Coal′s Physical Property[J];China Coalbed Methane;2011-04
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Wang Xinyu, Qi Zongneng, Wang Fosong (State Key Lab of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080);PREPARATION AND APPLICATION OF POLYMER-LAYERED SILICATE NANOCOMPOSITE[J];Engineering Plastics Application;1999-02
2 Yu Shujuan; Zhang Junfang; Wang Junshan(AISC Technology Center);Experimental Investigation on Improving Pellet Strength with organic Binder[J];;1998-11
3 Hu Qinghua(Department of Geology, Hefe University of Technology);THE PHYSICAL AND CHEMICAL PROPERTIES OF PYROPHYLLITE ORE POWDER AND ITS APPLICATION STUDY[J];GEOLOGY OF ANHUI;1996-01
4 Wu Guohua (Department of Materials Engineering);INVESTIGATION ON THE COATING'S STATIC SHEAR STRESS AND SURFACE TENSION[J];;1993-03
5 MIAO Heng-feng et al(Key Laboratory of Industrial Biotechnology,Ministry of Education,Southern Yangtze University,Wuxi,Jiangsu 214122);Study on the Ozonization of Microcystic aeruginosa and the Removal of Its Algae Toxins[J];Journal of Anhui Agricultural Sciences;2008-05
6 YU Shi-long et al (College of Resource and Environment Management,Jiangxi University of Finance and Economics,Nanchang,Jiangxi 330032);Research Progresses on the Phytoremediation of Eutrophic Water Body[J];Journal of Anhui Agricultural Sciences;2008-31
7 LIU Yin et al(Key Laboratory of Mine Disaster Prevention and Control,Shandong University of Science and Technology,Qingdao,Shandong 266510);Research Progress on the Phytoremediation Technique of Polluted Water Bodies[J];Journal of Anhui Agricultural Sciences;2009-15
8 KUANG Qi-jun~1, MA Pei-ming~(1,2), HU Zheng-yu~1,ZHOU Guang-jie~(1,2)(1 Institute of Hydrobiology, The Chinese Academy of Sciences, Wuhan 430072, China; 2 Graduate School, The Chinese Academy of Sciences, Beijing 100039, China);Study on the evaluation and treatment of lake eutrophication by means of algae biology[J];Journal of Safety and Environment;2005-02
9 CHEN Hou-he~1 KONG Jian-jian~2 WANG Shu-xian~3 (1.3 Fengxian Environmental Pretecting Department,Xuzhou 221700,China; 2.Shenyang Normal University,Shenyang 110000,China);Experimental Test of Environmental Factor Influence of Bottom Silt NH_4~+-N Release in Deep Lake[J];Environmental Science and Management;2006-07
10 Li Zhuo,Wang Yan,Kong Jin(Liaoning Province Environmental of Monitoring Centre,Jinzhou 121001,China);Discussion and Research of the Determination of Soil Redox Potentials[J];Environmental Science and Management;2008-10
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 WEN Jun-hui,WANG Yan-bo,HAN Jian-zhong Key Laboratory of Food Safety of Zhejiang Province,Food Quality & Safety Department,Zhejiang Gongshang University,Hangzhou 310035,China);Effect of Probiotics-loaded Montmorillonite on Water Quality and Growth Performances of Cultured Allogynogenetic Crucian Carp[J];Fisheries Science;2008-11
2 Lv Yinghai Zhou Shixue Li Guijiang Zhou Zhenghui Yang Minjian(College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266510);Effects of Coupling Agent on Adsorption of Montmorillonite to Arginine[J];Non-Metallic Mines;2009-05
3 Lv Yinghai1 Cui Liqiang1 Zhang Wenping2 Han Zongying1 Zhou Shixue1(1 College of Chemical and Environmental Engineering,Shandong University of Science and Technology,Qingdao 266510;2 Shandong Gold Group Changyi Mine Co.,Ltd,Changyi,Shandong 261300);Analysis and Characterization of Complexes of Montmorillonite Intercalated with Proteins,Peptide,Amino Acid[J];Non-Metallic Mines;2010-06
4 Wu Hongdan1,2 Yu Jishun2 Lei Xinrong1 Guan Junfang3 Zhang Jinhua1(1 Faculty of Material Science and Chemical Engineering,China University of Geosciences,Wuhan 430074;2 State Key Laboratory of Geological Pro-cesses and Mineral Resources,Wuhan 430074;3 School of Resource & Environmental Engineering,Wuhan University of Technology,Wuhan 430070);Study on Structure of Amines/ Montmorillonite Organic Complexes[J];Non-Metallic Mines;2011-01
5 Cong Xingshun (Department of Chemistry,Zaozhuang University,Zaozhuang 277160,China);Research on Preparation Technology of Inorganic Gel with High Pure Bentonite[J];Guangdong Chemical Industry;2010-05
6 MA Yu-long1,YANG Bo2 (1.College of Chemistry and Chemical Engineering,Ningxia University,Yinchuan 750021,China;2.College of Life Science,Ningxia University,Yinchuan 750021,China);Preparation and characterization of antibacterial Cu~(2+)-ZnO/cetylpyridinium-montmorillonite complexes[J];Journal of Functional Materials;2010-03
7 MO Wen-sheng(Wuping Center for Scientific Technology,Wuping 364300,China);Preparation of Inorganic Gel with Bentonite in West Fujian[J];Technology & Development of Chemical Industry;2010-05
8 CAI Jia-jia1,2,WANG Wen-bo1,KANG Yu-ru1,XU Hui2,WANG Ai-qin1(1.R&D Center of Xuyi Attapulgite Applied Technology,Lanzhou Institute of Chemical Physics,Chinese Academy of Science, Lanzhou 730000,China;2.College of Petrochemical Technology,Lanzhou University of Technology,Lanzhou 730050,China);Effects of High-pressure Homogenization on the Microstructure and Viscosity of Attapulgite Modified by Sodium Pyrophosphate[J];Bulletin of the Chinese Ceramic Society;2012-06
9 Castor Oil Xie Youli1,Zhang Meng1,2,Zhou Yonghong1,2,Yang Xiaohui1 (1.Institute of Chemical Industry of Forestry Products,Chinese Academy of Forestry;National Engineering Lab for Biomass Chemical Utilization;Key and Lab on Forest Chemical Engineering,State Forestry Administration Key Lab of Biomass Energy and Material,Nanjing?210042,China;? 2.Jiangsu Qianglin Bio-energy and Bio-materials Limited Company,Liyang?213364,China);Preparation and Application of Montmorillonite Intercalated with Quaternary Ammonium Based on[J];Engineering Plastics Application;2012-12
10 ZHANG Zepeng,WAN Fang,LIAO Libing,DU Gaoxiang (School of Materials Science and Technology,China University of Geosciences(Beijing),Beijing 100083,China);Preparation and Characterization of Anion-Non-ionic Surfactants Modified Montmorillonites[J];China Powder Science and Technology;2013-01
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