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WU GUANG\|MING WANG JUE \ TANG XUE\|FENG\ GU MU\ CHEN LING\|YANG\ SHEN JUN (Pohl Institute of Solid State Physics,Tongji University,Shanghai\ 200092,China)  
The growth kinetics of the oxide film and oxidation mechanism on tin films prepared by the electron\|beam evaporation in the temperature range of 250—400℃ by an isothermal process were investigated. Based on an X\|ray diffraction, auger electron spectrum, scanning electron microscope and alpha-step instrument, the evolution of the structure, composition, morphology and thickness of the oxide on tin films has been studied. In the studied temperature region, the growth of the oxide film was found to obey a parabolic growth\|rate law with an activation energy of about 0.34?eV, and is controlled by the oxygen diffusion from the loose oxide. It is concluded that the growth of the oxide begins from the formation of a SnO phase,with the increase of the oxidation time, the SnO phase decomposes and a Sn\-3O\-4 phase forms due to the SnO thermal and chemical unstability, and the deeper oxidation transfers the Sn\-3O\-4 phase to a SnO\-2 phase.
【Fund】: 国家高技术研究发展计划!(批准号 :863 410 3 9)资助的课题&&
【CateGory Index】: O484
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5 CHEN Fang1,DU Chang-hua1,DU Yun-fei2,WANG Wei-sheng1,GAN Gui-sheng1(1.College of Material Science and Engineering,Chongqing Institute of Technology,Chongqing 400050,China;2.College of Foreign Language,Chongqing University,Chongqing 400044,China);Thermooxidation Capability of Liquid Sn-Cu Solder on Constant Temperature[J];Electronic Components and Materials;2006-01
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8 CHEN Yonghu; SHI Chaoshu; HU Guanqin(Department of Physics, University of Science and Technology of China, Hefei 230026, China)(Shanghai Institute of Ceramics, Chinese Academy Of Sciences, Shanghai 200050, China);IMPROVEMENT ON LUMINESCENTPROPERTIES OF PbWO_4 BY Sb DOPING[J];CHINESE JOURNAL OF LUMINESCENCE;1999-04
9 WU An-ru~1,DAI Xiao-yuan~2 (1.Dept.of Mech.and Elect. Eng.,Hunan Institute of Engineering,Xiangtan 411101,China; 2.Institute of Material Science and Engineering , Central South University , Changsha 410083, China);Study on Basic Properties of Sn-Ag-Sb+M System Alloys[J];Journal of Hunan Institute of Engineering;2004-03
10 WANG Ying *, ZHANG Xiao-Yan, CAI Bing-Chu, ZHANG Ya-Fei (Key Laboratory for Thin Film and Microfabrication Technology of Ministry of Education, Research Institute of Micro/Nanometer Science and Technology, Shanghai Jiaotong University, Shanghai 200030, China);Preparation of FePt Nanoparticle Monolayer by Langmuir-Blogett Method[J];Chemical Research In Chinese Universities;2004-12
【Secondary References】
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1 CAI Chao1,2, LI Jianmei1,3, XUE Minzhao3, LIU Yangang3(1 School of Chemistry and Chemical Engineering, Ningxia University,Yinchuan 750021;2 State Key Laboratory for Mechanical Behavior of Materials Science and Engineering, Xi’an Jiaotong University, Xi’an 710049; 3 School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240);Preparation and Development of Transparent Oxide Films[J];Materials Review;2007-S1
2 Liu Tingyu Zhang Qiren Zhuang Songling (Science College, University of Shanghai for Science and Technology, Shanghai 200093);Simulation on the Optical Properties for the PbWO_4 Crystal Containing Lead Vacancy[J];Acta Optica Sinica;2005-03
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4 SUN Guifang (School of Physics Science and Information Engineering,Liaocheng University,Liaocheng 252059,Shandong,China);LUMINESCENCE PROPERTIES OF MgF_2 DOPED LEAD TUNGSTATE CRYSTAL[J];Journal of the Chinese Ceramic Society;2008-02
5 SUN Guifang,QIAN Xia,SHENG Shufang,RUAN Shuren(School of Physics Science and Information Engineering,Liaocheng University,Liaocheng 252059,Shandong,China);INFRARED REFLECTION SPECTRA OF LEAD TUNGSTATE CRYSTAL[J];Journal of the Chinese Ceramic Society;2009-02
6 KE Chun-shan~1 , YING Xing-juan~2(1.Ningbo Mechanical Industrial College, Ningbo 315000,China ;2.University of Shanghai for Science and Technology, Shanghai 200093,China);Simulations on the electronic structure and optical properties for the perfect raspite-structured PbWO_4 crystal[J];Optical Instruments;2005-04
7 Liu Tingyu1, Zhang Qiren1, Zhuang Songlin2 1 College of Science, University of Shanghai for Science and Technology,Shanghai 200093 2 College of Optics and Electronics Engineering, University of Shanghai for Science and Technology, Shanghai 200093;Simulation of the Optical Properties for the Perfect PbWO_4 Single Crystal[J];Acta Photonica Sinica;2005-08
8 NIU Xinshu,SUN Jingxia,DENG Weina(College of Chemistry & Environmental Science,Henan Normal University,Henan Province Key Laboratory of Environmental Pollution Control,Xinxiang 453007,Henan Province,China);Preparation and NO_2 gas sensing property of Sm~(3+)-doped WO_3 nano powder[J];Electronic Components and Materials;2009-09
9 SHA Ren,WANG Xi-gui (College of Chemistry and Environmental Science,Inner Mongolia Normal University,Huhhot 010022,Nei Mongol,P.R.China);Preparation and Luminescence Properties of LaAlO_3∶Eu~(3+) Nanocrystals by Complex Precipate Method[J];Imaging Science and Photochemistry;2009-06
10 LI Rui-hong,HAN Yue-ping,ZHOU Han-chang,HAN Yan National Key Laboratory for Electronic Measurement Technology,North University of China,Taiyuan 030051,China;Measurement Technology for Multi-Parameter Spectral Responsivity of X-Ray Scintillation Crystals[J];Spectroscopy and Spectral Analysis;2010-08
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