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《Journal of Xi'an Polytechnic University》 2008-06
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Study on the electrochemical behavior of iron-amine complex on the hanging mercury drop electrod

LI Bing,ZHENG Chang-zheng(School of Environmental & Chemical Engineering,Xi′an Polytechnic University,Xi′an 710048,China)  
The electrochemical behavior of iron-amine complex is studied by the cyclic voltammetry on the hanging mercury drop electrod.The results show that iron-amine complex gets one electron as the redox mediator on the electrod,this is a quasi-reversible diffusion controlled process.After adding the indigo,the electrochemical reduction of the complex is an adsorption controlled process while the electrochemical oxidation is a diffusion controlled process.And it is a quasi-reversible process which is believed to follow chemical catalysis mechanism(EC).
【Fund】: 陕西省自然科学基础研究计划项目(2006B11);; 西安市科技计划项目(CXY08025)
【CateGory Index】: O646.54
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