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《Modern Chemical Industry》 2004-07
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Styrene-butadiene rubber/attapulgite nanocomposites prepared by in situ emulsion polymerizatiotn

YANG Jin-Tao, FAN Hong, BU Zhi-Yang, LI Bo-Geng rsity, Hangzhou 310027, China)  
Styrene-butadiene rubber (SBR)/attapulgite nanocomposites were prepared by in situ emulsion polymerization.The copolymerization rate was decreased monotonically with the increasing of the amount of attapulgite while the molecular weight and the molecular weight distribution SBR extracted from nanocomposites remained basically unchanged.The attapulgite was uniformly dispersed in SBR matrix as fibers with a length of 0.5-5 μm and diameter of 20-50 nm.The nanoscale dispersed attapulgite fibers contributed to form interpenetrating polymer network(IPN) structure with SBR during vulcanization,hence the crosslinking degree increased,meanwhile it offered the composites excellent mechanical properties.The nanocomposites exhibited about a 20%-100% increase in the 300% modulus and tensile strength and significantly lower the abrasion loss depending on the content and showed a better reinforcement efficiency than with the same content of carbon black N330 as the filling material.
【Fund】: 国家杰出青年科学基金资助项目(20125617)
【CateGory Index】: TB383
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