Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《JOURNAL OF XIAMEN UNIVERSITY(NATURAL SCIENCE)》 1998-06
Add to Favorite Get Latest Update

Determination and Study on Properties of Thermodynamics of RbCl in Water Containing Mixtures at 298.15K

Li Linwei (Dept. of Chem., Liaocheng Teach. Coll., Liaocheng 252059) Chu Deying Liu Ruilin (Coll. of Chem. and Molecular Engin., Pejing Univ.,Beijing 100871)  
The reversaible cells consists of the Corning monovalent cation selective electrode (M + ISE) and chloride selective electrode (Cl - ISE),nameiy namely Cl - ISE/RbCl(m),H 2O(1- x ),MeOH( x) or DMF (x) /M + ISE The standard electromotive forces ( E 0 m/mV) of the measured cells have been determined at 298.15 K,and standard Gibbs free energies of transfer ( ΔG 0 t/kJ·mol -1 ) of RbCl from H 2O to (H 2O MeOH) and (H 2O DMF) mixtures and activity coefficients ( γ ±) in the mixed solvents have been calculated and discussed on the basis of theory of solvation of electrolyte solution.
【Fund】: 国家自然科学基金
【CateGory Index】: O645.164
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 2 Hits
1 WANG Wei-Dong,HUA Yong(1.Hubei Key Laboratory of Bioanalytical Technique,Hubei Normal University,Huangshi 435002,Hubei China;2.Department of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,Hubei China);The Properties of Thermodynamics of CuCl_2 in DMF-H_2O Mixed Solvent[J];吉首大学学报(自然科学版);2006-05
2 HOU Xiang-yang;WANG Ji-wu;GAO Lou-jun YANG Xiang-kui;SHEN Ying-jun (College of chemistry and Chemical Engineering,Yanan University,Yanan 716000,China );Study on thermodynamics properties of zine chloride in mixed solvent of alcohol and water[J];延安大学学报(自然科学版);2005-02
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Chu De-Ying~* Zhang Ying Yi Ying Liu Rui-Lin (Department of Chemistry,Peking University,Beijing);Using Ion-Selective Electrodes to Study the Thermodynamics of Solution——Ⅳ.The Standard Gibbs Free Energies and Entropies of Transfer of Sodium Chloride from Water to N,N-Dimethylformamide—Water Mixture at Nine Temperatures from 5℃ to 45℃[J];化学学报;1988-09
【Co-citations】
Chinese Journal Full-text Database 7 Hits
1 Li Linwei1 Chu Deying Liu Ruilin ( College of Chemistry and Molecular Engineering,Peking University, Beijing 100871; 1Department of Chemistry,Liaocheng Teachers College, Liaocheng City 252059);Determination of Standard Transfer Entropies of RbCl from H_2O to Mixtures of H_2O-DMF[J];物理化学学报;1999-03
2 Li Linwei 1) Diao Zhaoyu 2) Chu Deying 3) Liu Ruilin 3) ( 1)Department of Chemistry,Liaocheng Teachers' College,252059,Liaocheng,Shandong,P R C; 2)Department of Chemistry,Shandong Normal Universitry,250014,Jinan,P R C;;THE MEDIUM EFFECT OF RbCl IN MIXED SOLVENTS[J];山东师大学报(自然科学版);1998-04
3 Li Linwei (Dept. of Chem., Liaocheng Teach. Coll., Liaocheng 252059) Chu Deying Liu Ruilin (Coll. of Chem. and Molecular Engin., Pejing Univ.,Beijing 100871);Determination and Study on Properties of Thermodynamics of RbCl in Water Containing Mixtures at 298.15K[J];厦门大学学报(自然科学版);1998-06
4 Li Linwei; Chu Deying; Liu Rmhn(College of Chemiastry and Moleculer Engineering. Peking University Beijing 100871: Departmentof Chemistry, Liaocheng Teache's College' Liaocheng 252O59);Determination of Activity Coefficients of RbCl in (H_2O-DMF) Mixed Solvents at 283.15 to 318.15K[J];物理化学学报;1998-08
5 Li Linwei Chu Deying Liu Ruilin (College of Chemistry and Molecular Engineering,Beijing University,Beijing 100871);USING ION SELECTIVE ELECTRODE TO STUDY THE THERMODYNAMICS OF SOLUTION ⅠⅩ.Determinations of Relative Partial Molar Free Energies, Enthalpies and Entropies of RbCl in Water and Mixtures[J];华中师范大学学报(自然科学版);1998-02
6 Xu Lamei; Ni Liang; Lu Jie;(Zhenjiang Educational Bureau, 212001, Zhenjiang, PRC; Department of Chemistry, Zhenjiang Teacher's College 212003, Zhenjiang, PRC.);Study on the Influence of Solvent on the Equilibrium Properties of Thermodynamics[J];南京师大学报(自然科学版);1995-04
7 Zhang Luzheng Lu Xiaohua Wang Fanru Shi Jun (Department of Chemical Engineering);A SHORT-CUT DETERMINATION OF ACTIVITY COEFFICIENTS FOR ELECTROLYTE IN MIXED SOLVENT BY ADDING CONTINUOUSLY A CONCENTRATED ELECTROLYTE SOLUTION[J];南京工业大学学报(自然科学版);1992-01
【Co-references】
Chinese Journal Full-text Database 8 Hits
1 WANG Wei-dong,XIANG Cui-li,HU Zhen-zhu,LU Jiang-ling(Department of chemistry,Hubei Normal University,Huangshi 435002 China);Determination of Activity Coefficients in Non-Aqueous Solvents:the experimental determination of the activity coefficients of NaCl in 1,2-propanediol solvent[J];盐湖研究;2004-01
2 Wang Qin Ping LüDian Zhen Zhang Li Sun Xue Li Yang Jia Zhen(Department of Chemistry, Liaoning University, Shenyang 110036);Thermodynamics of Mixed Electrolytes in Mixed Solvents of Glycol and Water[J];物理化学学报;2003-02
3 Li Zhiguang, Huang Hongjun*, Yan Jun (Section of Physi-Chemistry, Mchenical Engineering College, Shijiazhuang 050003);The Study of Activity Coefficients on the Ternary System of NaCl-KCl-H_2O at 35℃[J];化学物理学报;2002-06
4 YU Caihong,YU Dahong,QIN Yuan,LIU Honglai and HU Ying (Department of Chemistry, East China University of Science and Technology, Shanghai 2000237,China);MEASUREMENT OF MEAN ACTIVITY COEFFICIENTS OF NaCl IN POLYELECTROLYTE SOLUTIONS[J];化工学报;2001-08
5 Li Linwei (Dept. of Chem., Liaocheng Teach. Coll., Liaocheng 252059) Chu Deying Liu Ruilin (Coll. of Chem. and Molecular Engin., Pejing Univ.,Beijing 100871);Determination and Study on Properties of Thermodynamics of RbCl in Water Containing Mixtures at 298.15K[J];厦门大学学报(自然科学版);1998-06
6 Li Linwei; Chu Deying; Liu Rmhn(College of Chemiastry and Moleculer Engineering. Peking University Beijing 100871: Departmentof Chemistry, Liaocheng Teache's College' Liaocheng 252O59);Determination of Activity Coefficients of RbCl in (H_2O-DMF) Mixed Solvents at 283.15 to 318.15K[J];物理化学学报;1998-08
7 Li Linwei Chu Deying Liu Ruilin (College of Chemistry and Molecular Engineering,Beijing University,Beijing 100871);USING ION SELECTIVE ELECTRODE TO STUDY THE THERMODYNAMICS OF SOLUTION ⅠⅩ.Determinations of Relative Partial Molar Free Energies, Enthalpies and Entropies of RbCl in Water and Mixtures[J];华中师范大学学报(自然科学版);1998-02
8 BAO Jian-Bin;ZHOU Qiu-Hong; LI Ang; HAN Shi-Jun(Department of Chemistry,Zhejiang University,Hangzhou,310027);Experimentally Limiting Ternary Activity Coefficients[J];高等学校化学学报;1994-12
【Secondary References】
Chinese Journal Full-text Database 1 Hits
1 ZHANG Shuyuan;ZHANG Xin;ZHANG Hua;College of Chemistry,Tianjin Normal University;;Synthesis and antibacterial activity of metal complex from ofloxacin[J];天津师范大学学报(自然科学版);2014-03
【Secondary Citations】
Chinese Journal Full-text Database 2 Hits
1 Chu Deying Liu Li Liu Ruilin (Department of Chemistry,Peking University);THE STANDARD GIBBS ENERGIES OF TRANSFER AND THE ACTIVITY COEFFICIENTS OF NaF AND NaCl FROM WATER TO DIOXAN+WATER MIXTURES——USING IONSELECTIVE ELECTRODES TO STUDY THE THERMODYNAMICS OF SOLUTIONS[J];物理化学学报;1987-05
2 FANG LI-QI LIU RUI-LIN (Institute of Physical Chemistry,Peking University Beijing);THE FREE ENERGIES AND ENTROPIES OF THE TRANSFER OF NaCl,KCl,FROM WATER TO WATER AND BUTANOL MIXTURES——DOUBLE CELL EMF DETERMINATION[J];化学学报;1985-05
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved