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《Journal of The Chinese Rare Earth Society》 2003-02
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Research on Glass-Forming Abilities of Erbium Borosilicate Glasses

Zhang Qitu, Fu Zhenxiao, Lu Chunhua, Xu Zhongzi (Material Science & Technology College, Nanjing University of Technology, Nanjing 210009, China)  
The study of glass formation properties is important for rare earth glasses, which have been a kind of concernful materials used in the high technology fields. Glass formation range of erbium borosilicate glasses was explored in this paper by the new method. The effects of Al2O3 and Er2O3 on glassforming region were researched and the glassforming regions of various concentrations of Al2O3 and Er2O3 were presented respectively. Results show that the area of glass formation range increases when Al2O3 concentration from 20% to 15%, while it decreased when Er2O3 concentration from 20% to 30%. The stability of the glasses against crystallization was discusses also, by the value of β, the parameter of crystallization tendency calculated from the thermoanalysis data. Glass forming ability of erbium borosilicate glasses is relatively poor. But in a limited range of Er2O3 concentration, it will improve with the increasing concentration of Eu2O3. In addition, adding Al2O3 into erbium borosilicate glasses system could strengthen the network structure, then would improve the glass forming ability.
【Fund】: 江苏省"333工程"资助项目;; 教育部优秀青年骨干教师基金资助项目(教技司[2000]65)
【CateGory Index】: TQ171
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