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《Journal of the Chinese Society of Rare Earths》 2013-01
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Geochemical Characteristics of REE in Limestone Across Neoproterozoic-Cambrian Transition on Northern Anhui Province

Chen Song1,2,Fu Xuehai2,Sun Linhua1,Gui Herong1(1.School of Earth Sciences and Engineering,Suzhou University,Suzhou 234000,China;2.School of Resource and Earth Science,China University of Mining and Technology,Xuzhou 221116,China)  
The analysis of petrological and rare earth elemental(REE) had been carried out for the limestone collected from the Neoproterozoic(Gouhou Formation) and Cambrian(Houjiashan Formation) in northern Anhui province,and the origin of REE and its characteristics in limestone had been studied.The rare earth elemental distribution patterns of seawater which precipitated limestone and tectonic background in Neoproterozoic-Cambrian also discussed respectively.The results showed that the REE in limestone from Gouhou Formation were characterized by the more high total REE(10.66~30.68 ppm),the LREE(light REE) enrichment with the NdSN/YbSN ranging from 1.12 to 1.46,intensive fractionation between LREE and HREE(high REE) and serious effect with terrestrial materials;the characteristics of REE in limestone from Houjiashan Formation included the lower total REE(1.63~7.79 ppm),light LREE depletion(NdSN/YbSN=1.12~1.46),light fractionation between LREE and HREE and the slight contamination of clastic.All limestone samples showed various degrees in negative Ce anomaly,positive La and Y anomaly.The REE characteristics of inversed seawater from Houjiashan limestone conformed to the modern seawater,with slight difference from the seawater in Neoproterozoic.The limestone from Gouhou Formation and Houjiashan Formation were deposited in the continental and oceanic island arc,respectively.
【Fund】: 国家自然科学基金(41173106);; 安徽省教育厅自然科学项目(KJ2011B177);; 宿州学院科研平台开放课题(2011YKF22)资助
【CateGory Index】: P595
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