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《JOURNAL OF THE CHINESE RARE EARTH SOCIETY》 1998-03
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Synthesis of Phosphors(Ce 0.67 Tb 0.33 )MgAl 11 O 19 and BaMgAl 10 O 17 ∶Eu 2+ by Microwave Irradiation Technique and Their Luminescent Properties

Dai Dechang, Li Yuanying, Cai Shaohua( Department of Chemistry, Zhongshan University, Guangzhou 510275, China ), Xie Yuzhou, He Hanbo( Guangzhou Institute of Nonferrous Metals, Guangzhou 510651, China )  
The phosphors(Ce 0 67 Tb 0 33 )MgAl 11 O 19 (P G) and BaMgAl 10 O 17 ∶Eu 2+ (P B) were synthesized using the microwave irradiation technique. The data of X ray powder diffraction( d values and I/I 0 values) are basically coincided with the data of JCPDF 36 73 and 26 163 cards. The calculated cell dimensions are a =0 5582 nm, c =2 1884 nm for P G, and a =0 5616 nm, c =2 2614 nm for P B. The excitation spectrum and the emission spectrum of the phosphors were measured. The chromatic coordinates are x =0 316, y =0 565 for P G, and x =0 156, y =0 106 for P B. The relative luminescent intensity is about 88%(P G) and 80%(P B) respectively compared with the same commercial phosphors. The pictures of SEM of the phosphors were also detected.
【Fund】: 广东省自然科学基金
【CateGory Index】: O614.33
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