Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chinese Rare Earths》 2010-04
Add to Favorite Get Latest Update

Synthesis of Isobutyl Isobutyrate with Solid Superacid SO_4~(2-)/SnO_2-CeO_2-kaolin as Catalyst

ZHOU Hui1,ZHANG Xia2,HE Jian-ying1,CHEN Dan-yun1(1.Chemistry and Chemical Engineering College of Henan University,Institute of Fine Chemistry and Engineering,Henan Kaifeng 475004;2.College of Continuous Education,Zhengzhou University of Light Industry,Zhengzhou 450002,China)  
Isobutyl isobutyrate was synthesized from isobutyric acid and isobutyl alcohol with solid superacid catalyst SO42-/SnO2-CeO2-kaolin.The catalyst was prepared under the conditions of mass ratio of ammonium ceric nitrate to kaolin to SnCl4·5H2O 1:9:20,concentration of sulfuric acid 2.0mol/L,impregnation time 12h,and calcination at 350℃ for 3h.The catalyst was characterized by Hammett indicator method and XRD.As using synthesis of isobutyl isobutyrate,the optimal conditions were:mass fraction of catalyst in all of reaction system 2.5%,mole ratio of isobutyl alcohol to isobutyric acid 1.4,reaction time 100min and toluene 10mL,the yield was 94.5%.The catalyst also has excellent stability.When it was reused for six times,the yield could be greater than 80%.The catalyst takes advantages of low cost,highly active,non-polluting and reusable.
【Fund】: 河南省科技厅2009年科技发展计划项目(092102210171);; 河南省教育厅自然科学研究计划项目(2008A150002)
【CateGory Index】: TQ225.241
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 6 Hits
1 Zhang Fumin1,2,Zhong Yijun1,Zhu Weidong1,Wang Jun2(1.Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Institute of Physical Chemistry,Zhejiang Normal University,Jinhua Zhejiang 321004,China;2.State Key Laboratory of Materials-Oriented Chemical Engineering,College of Chemistry andChemical Engineering,Nanjing University of Technology,Nanjing Jiangsu 210009,China);Synthesis of Fructone over Phosphotungstic Acid-Silica Catalysts Prepared by Sol-Gel Method[J];Petrochemical Technology;2007-11
2 WU Yan-ni~1, CUI Xiu-lan~1, GUO Hai-fu~2,LI Qing-yu~1(1.School of Engineering, Inner Mongolia Polytechnical University ,Huhhot 010062,China;2.Department of Light Industry and Chemistry,Zhaoqing University,Zhaoqing 526061,China);Preparation of the New Type Rare Earth Solid Super Acid Catalyst and the Synthesis of Butyl Lactate[J];Chinese Rare Earths;2003-06
3 CHEN Xian-tao(Department of Chemistry and Chemical Engineering,Hunan Institute of Science and Technology,Yueyang 414000,China);Catalytic Synthesis of Isobutyrate over LaCl_3·7H_2O[J];Chinese Rare Earths;2006-05
4 YANG Yi-wen 1,LI Lei1,CHEN Hui-zong2 (1.School of Biology and Chemical Engineering,Jiaxing University,Jiaxing 314001,China; 2.Institute of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330027,China);Synthesis of Octyl Acetate Catalyzed by Rare Earth Composite Solid Superacid SO_4~(2-)/ZrO_2-2%Sm_2O_3[J];Chinese Rare Earths;2008-03
5 ZHOU Hui,CAI Yong-hong,CHEN Dan-yun(College of Chemistry and Chemical Engineering,Henan University,Kaifeng 475004,China);Synthesis of Butyl Lactate Catalyzed by Lanthanum Chloride[J];Chinese Rare Earths;2009-02
6 CHEN Dan-yun,CAI Yong-hong,HE Jian-ying(Chemistry and Chemical Engineering College of Henan University,Kaifeng 475004);Synthesis of butyl paraben catalyzed by stannic chloride[J];China Food Additives;2008-01
Chinese Journal Full-text Database 10 Hits
1 DENG Bin1,LIANG Chao-lun2,CHEN Liu-ping3 (1.Department of Chemistry and Life Science,Xiangnan University,Chenzhou 423000,China;2.Instrumentation Analysis & Research Center,Sun Yat-Sen University,Guangzhou 510275,China;3.School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275,China);Synthesis and Its Kinetics of Cyclohexyl Acetate with Rare Earth Composite Solid Superacid SO_4~(2-)/TiO_2/Ce~(4+) as Catalyst[J];Journal of Xiangnan University;2007-05
2 HAN Chun-yu,LIU Chun-sheng,LUO Gen-xiang(School of Chemistry and Materials Science,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China.);Catalytic Synthesis of Benzylaldehyde Ethylene Glycol Acetal by Neodymium Trifluoroacetate[J];Journal of Liaoning University of Petroleum & Chemical Technology;2008-02
3 WU Yan-ni~(1),GUO Hai-fu~(1),CUI Xiu-lan~(2)(1.Department of Light Industry and Chemistry,Zhaoqing University, Zhao Qing 526061,China;2.College of Chemical Engineering,Inner Mongolia Polytechnic University,Huhhot 010062,China);Study on the New Type Rare Earth Solid Super Acid Catalyst by IR Spectra[J];Journal of Molecular Catalysis;2006-04
4 CHEN Shao-feng1, 2, GUO Hai-fu1, HAO Xiang-ying1, YAN Peng1 (1. College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China; 2. College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, Inner Mongolia, China);Preparation and Characterization of Solid Superacid Ni/SO_4~(2-)-SnO_2[J];Journal of Molecular Catalysis;2009-04
5 XIE Bao-hua et al (College of Chemistry and Chemical Engineering,Jiujiang University,Jiujiang,Jiangxi 332005);Catalytic Synthesis of n-Octyl Acetate with H_6P_2W_(18)O_(62)·nH_2O/ZrO_2[J];Journal of Anhui Agricultural Sciences;2009-32
6 Chen Danyun Zhou Hui He Jianying(Institute of Fine Chemistry and Engineering,Henan University,Kaifeng 475004);Synthesis of Butyl-isobutyrate with Composite Kaolin Solid Acid as Catalyst[J];Non-Metallic Mines;2010-01
7 SONG Hua,YANG Dongming,LI Feng,LIU Quanfu,Xu Qian(College of Chemistry and Chemical Engineering,Daqing Petroleum Institute,Daqing 163318,Heilongjiang,China);Progress in SO_4~(2-)/M_xO_y solid superacid catalysts[J];Chemical Industry and Engineering Progress;2007-02
8 Liu Yuting,Yan Huixin,Yin Dawei,L(u|¨)Bo (School of Chemistry and Chemical Engineering,Shaanxi University of Science & Technology,Xi'an 710021,China);Research progress on catalytic esterification by solid superacids[J];Journal of Chemical Industry & Engineering;2008-06
9 LAI Jun-ling,CHEN Yong-li,LIU Chun-sheng,LUO Gen-xiang (School of Chemistry and Materials Science,Liaoning Petrochemical University,Fushun 113001,China);Catalytic synthesis of isopropyl chloroacetate by neodymium trifluoroacetate[J];Chemical Reagents;2009-03
10 Deng Bin~1 Liang Chaolun~2 Chen Liuping~3 (1.Department of Chemistry and Life Science,Xiangnan University,Chenzhou 423000; 2.Instrumentation Analysis & Research Center,Sun Yat-Sen University,Guangzhou 510275; 3.School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275);Study on Synthesis of Phenethyl Acetate Catalyzed by Lanthanum Chloride Supported on Activated Carbon[J];Advances in Fine Petrochemicals;2007-11
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 LIAO Shijun YANG Zhaoxi ZHANG Xiaoling LIU Ying(Department of Applied Chemistry, South China University of Technology Guangzhou 510641)WANG Lefu HUANG Zhongtao(Department of Chemical Engineering, South China University of Technology Guan;Preparation of Catalyst SO_4~(2-)/ZrO_2SiO_2 and Its Catalysis for Esterification of Acetic Acid with Butanol[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1998-01
2 Xia Jinghong (Chemistry Department,The Teaching Training School of Yulin Yulin 53700) Liang Fupei (Department of Chemical Ind., The Teaching University of Guangxi Guilin 541004);The Catalysis of Rare Earth Compound in Synthesis of Butyl Lactate[J];GUANGXI CHEMICAL INDUSTRY;1997-01
3 WU Wen-liang1, YU Qing-yue2, WANG Jun1, WANG Yan-ru1 (1. Department of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China; 2. Department of Chmical Engineering, Nanjing College of Chemical Technology, Nanjing 210048, China);Isopropylation of Naphthalene over Catalysts PW/C[J];Journal of Chemical Engineering of Chinese Universities;2004-05
4 ZHANG Fu-min, YUAN Chao-shu, WANG Jun (College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China);Catalytic Behavior of SBA-15 Supported Heteropoly Compounds in Synthesis of Fructone[J];Journal of Chemical Engineering of Chinese Universities;2006-06
5 DONG Jing hua, HUANG Ling , ZHANG De hua (Department of Chemistry and Environment Engineering, Hubei Normal University, Huangshi 435002,China);Catalytic synthesis of n-butyl isobutyrate with p-toluene sulfonic acid[J];Journal of Hubei Normal University(Natural Science);2004-02
6 WANG Hong (Institute of Shijiazhuang Product Quality Supervision and Inspection,Shijiazhuang 050031,China);Study on the Synthesis of Butyl Isobutyrate Catalyzed by Amidosulphonic Acid[J];;2000-04
7 ZHANG Fumin, YUAN Chaoshu, REN Xiaoqian, WANG Jun (Key Laboratory of Materials-Oriented Chemical Engineering of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009,Jiangsu,China);Characterization of supported heteropoly acid (salt) and its catalytic behavior in synthesis of fructone[J];Journal of Chemical Industry and Engineering(China);2006-04
8 SUN Ting, WU Chang-zeng (Department of Chemistry, Xuchang College, Xuchang 461000, China);Synthesis of n- butyl lactate catalyzed by TiSiW_(12)O_(40)/TiO_2[J];Journal of Natural Science of Heilongjiang University;2003-03
9 Yu Shanxin Zeng Shaohua (Department of Chemistry,Hunan Normal University,Changsha 410006),;Synthesis of alkyl isobutyrate catalyzed with strongly acidic cationic exchange resin[J];Chemical Reagents;1993-02
10 Zhang Zhihong *,Xue Laiqi ,Qi Hongjiang,Zhao Xiufeng (Department ofChemistry,Xinjiang Changji Education Institute,Changji831100),Huaxue Shiji,2000,22(4),21~232。;The synthesis of nAbutyl lactate catalyzed by the compoAsite solid superacid SO_4~(2-)/TiO_2AFe_2O_3[J];CHEMICAL REAGENTS;2000-04
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved