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《Chinese Rare Earths》 2015-03
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Structure and XPS Analysis of CdS / CdS and CdS / Dy / CdS Thin Films

ZOU Kai;LI Rong-ping;School of Physical Science and Technology,Inner Mongolia University;Key Laboratory of Semiconductor Photovoltaic Technology at Universities of Inner Mongolia Autonomous Region;  
Pure CdS thin film with the structure of CdS / CdS was prepared by means of chemical bath deposition.Rare earth Dy doped film with the structure of CdS / Dy / CdS was also prepared by connecting with the electron beam evaporation method.XRD andSEM tests show that the crystallographic structure of un-doped film is found to be cubic with a preferential orientation along the(111) plane.But CdS film is a mixed structure of cubic and hexagonal phase after the deposition of Dy layer,and Dy-doping increases the grain size and lattice constant of CdS.XPS analysis indicates that the two samples are all rich in Cd.Doping with Dy helps to reduce the concentration of O and C in the films,and then inhibits the formation of oxide.The inside and surface proportion of Cd,S atoms in un-doped film are 1 0.63 and 1 0.71,respectively.While they are10.81 and 10.83 in CdS / Dy / CdS sample,respectively.So the deposition of Dy layer between the two CdS layers promotes the combination of Cd andS,and leads to a uniform chemical composition.
【Fund】: 内蒙古自治区教育厅项目(NJ09006)
【CateGory Index】: O484
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