Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Metallurgical Analysis》 2011-03
Add to Favorite Get Latest Update

Determination of rare earth elements in polymetallic ore by inductively coupled plasma mass spectrometry after alkali fusion and ion exchange

YANG Xiao-li,CUI Sen,YANG Mei,LI Xiao-dan(Wuhan Institute of Geology and Minerals Resources,Wuhan 443000,China)  
The polymetallic ore samples were treated by alkali fusion-ion exchange and the rare earth elements in the samples were determined by inductively coupled plasma mass spectrometry(ICP-MS).The instrument operating parameters were optimized,and the factors affecting the analytical results including ion exchange speed and eluant were discussed.Experiment results indicated that the matrix interferences and mass interferences could be eliminated by ion exchange speration and selecting appropriate analytical isotopes,and analytical signal drift could be inhibited with Rh,Re as internal standard elements.The method has been used for the determination of rare earth elements in polymetallic ore certified reference materials which mainly contained zinc ore and copper ore respectively(GBW07237,GBW07233).The results were in good agreement with the certified values.Detection limits of the method were in the range of 0.001-0.009 μg/g with relative standard deviations of 1.3%-7.8% and recoveries of 91%-109%.
【Fund】: 国土资源公益性行业专项项目资助(1212010816022)
【CateGory Index】: O657.63
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 2 Hits
1 LI Xiang-rong1,CHEN Yong-xin1,LIU Shun-qiong1,YUAN Huan-ming2, RUAN Gui-wu1,MA Li-fang1(1.Fangchenggang Entry-Exit Inspection and Quarantine Bureau,Fangchenggang 538001,China; 2.China Certification & Inspection Guangxi Co.,Ltd.,Fangchenggang 538001,China);Determination of major and minor elements in polymetallic ore by inductively coupled plasma atomic emission spectrometric method[J];Metallurgical Analysis;2012-08
2 HU Shan-ling1,2,ZHOU Jian-guang1 (1.State Key Lab of Industrial Control Technology,Institute of Cyber-Systems and Control,Research Center for Analytical Instrumentation, Zhejiang University,Hangzhou 310058,China; 2.College of Chemistry and Chemical Engineering,Gannan Normal University,Ganzhou 341000,China);Research Progress in Rare Earth Determination by Inductively Coupled Plasma Mass Spectrometry[J];Chinese Rare Earths;2012-05
【Citations】
Chinese Journal Full-text Database 10 Hits
1 Li Lixing,Li Houmin,Wang Denghong,Zhang Changqing Institute of Mineral Resources,Chinese Academy of Geological Sciences,MRL Key Laboratory of Metallogeny and Mineral Assessment,Beijing 100037,China;Trace element and REE geochemistry and its metallogenic significance for Cu-Zn deposits in the Tongbai area,Henan[J];Earth Science Frontiers;2009-06
2 Chen Hangting *, Cao Shuqin, Zeng Xianjin (Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, National Analytical Research Center of Electrochemistry & Spectroscopy, Changchun 130022);Application of Inductively Coupled Plasma Mass Spectrometry in Biological Samples Analysis[J];Chinese Journal of Analytieal Chemistry;2001-05
3 XU Tao*,CUI Aai-duan,DU Mei,ZHANG Hong-qiang(Baotou Research Institute of Rear Earth,Baotou 014010);Determination of Nb,Ta and Zr in RE-Nb-Ta Ore by ICPAES[J];Journal of Analytical Science;2007-03
4 YANG Hong-xia, Li Bing and Ma Xin-rong(National Research Center of Geoanalysis, Beijing 100037);Determination of boron in blood and sperm by inductively coupled plasma mass spectrometry (ICP-MS)[J];Analytical Laboratory;2005-10
5 CHEN Yi-Jun DAI Le-Mei HU Xin CAI Xiu-Lan~a(Center of Materials Analysis,Nanjing University,Nanjing 210093,P.R.China)a(Department of Chemistry,Nanjing University,Nanjing 210093,P.R.China);Determination of As,Cd,Cr,Cu,Pb,Se and Zn in Dried Corn Steep Liquor Powder by ICP-MS[J];Chinese Journal of Spectroscopy Laboratory;2006-06
6 ZHANG Xin-quan 1 ,LIUJing-lei 1 ,JIANG Yu-mei 1 ,YI Yong 1 ,TONG Ying-dong 1 ,LIN Ping 2 (1.Jiangxi Institute of Analyzing and Testing,Nanchang330029,China;2.Jiangxi Center of Diseased Controlled,Nanchang330029,China);Determination of Impurities in High Purity Samarium by Inductively Coupled Plasma Mass Spectrometry[J];Journal of Instrumental Analysis;2005-01
7 CHEN Guo-you(Inspection and Testing Center for Quality of Cereals and Their Products(Harbin),Ministry of Agriculture ofP.R.of China,Heilongjiang Academy of Agricultural and Sciences,Harbin 150086,China);Simultaneous Determination of 14 Elements in Vegetables by ICP-MS with Microwave Digestion[J];Journal of Instrumental Analysis;2007-05
8 Guo Wei~(1,2),Li Ming~(1,2),Shuai Qin~(1,2),Hu Shenghong~(1,3*)(1.State Key Laboratory of Geo-Processing and Mineral Resources,2.Faculty of Material Science and Chemical Engineering,3.Faculty of Earth Sciences,China University of Geosciences,Wuhan 430074,China);Accurate Determination of Rare Earth Elements in Clinopyroxenes by Inductively Coupled Plasma Mass Spectrometry[J];Journal of the Chinese Rare Earth Society;2006-S1
9 ZHANG Yi-ming1,2,HAO Dong-mei3,JIA Tao1,2,XU Tao1,2,HAO Qian1,2,BAO Xiang-chun1,2(1.Ruike National Engineering Research Centre of Rare Earth Metallurgy and Function Materials,Baotou 014030,China; 2.Baotou Research Institute of Rare Earths,Baotou 014030,China; 3.Yantai University,Yantai 264005,China);Determination of Rare Earth and Thorium in Rare Earth-niobium-tantalum-mineral by ICP-MS[J];Chinese Rare Earths;2008-06
10 HUANG Hui-ping~(*1),LI Yan-ling~1,TAO De-gang~2,XIONG Cai-hua~2,FANG Jin-dong~2(1.Faculty of Material Science and Chemical Engineering,China University of Geoscience,Wuhan 430074,China;2.Hubei Geological Research Laboratory,Wuhan 430022,China);Determination of trace rare earth elements in monomineralic rocks of chromite by inductively coupled plasma mass spectrometry[J];Metallurgical Analysis;2005-06
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 SU Wen-bin(Faculty of Chemistry and Material Science,Lang Fang Teachers College,Langfang,Hebei 065000);Simultaneous Determination of Zinc and Copper in Foods by Differential Pulse Stripping Voltammetry Based on Bismuth-film Electrode[J];Journal of Anhui Agricultural Sciences;2011-03
2 TONG Chun-lin,LIU Yong-sheng,HU Sheng-hong,HU Zhao-chu,ZONG Ke-qing and CHEN Hai-hong(State Key Laboratory of Geological Processes and Mineral Resources,Faculty of Earth Sciences,China University of Geosciences,Wuhan 430074,China);Specific chemical behavior of Nb and Ta in geological sample preparation with PTFE Bomb for ICP-MS analysis[J];Geochimica;2009-01
3 LI Bing, YANG Hong xia (National Research Center of Geoanalysis, Beijing 100037, China);APPLICATIONS OF INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY IN EARTH SCIENCE[J];Earth Science Frontiers;2003-02
4 LI BingNational Research Center of Geological Analysis, Beijing, 100037;Application of Inductively Coupled Plasma Mass Spectrometry in Geological Survey[J];Geological Review;2006-06
5 HU Xiao-geng1,WANG Chun-yan2,LI Rui-xian1,ZHANG Wang-qiang1, ZHU Jian-guo1,MAO Zhen-cai1(1.Lanzhou Testing and Quality Supervision Center for Geological and Mineral Products, Ministry of Land Resources,Lanzhou 730050,China; 2.LanZhou LS Heat Exchange Equipment Co.Ltd,Lanzhou 730050,China);Determination of Cu,Pb,Zn and Fe in Tomb Soil Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry[J];Analysis and Testing Technology and Instruments;2011-04
6 Duan Taicheng, Kang Jianzhen, Yu Guihong, Liu Jie, Zeng Xianjin, Chen Hangting * (State Key Laboratory of Electroanalytical Chemistry, National Analytical Research Center of Electrochemistry & Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);Evaluation and Application of Micro-Sampling System for Inductively Coupled Plasma Mass Spectrometry[J];Chinese Journal of Analytieal Chemistry;2002-12
7 Zhu Xiashi, Jiang Zucheng, Hu Bin *, Li Mingfang (College of Chemistry & Molecular Science, Wuhan University, Wuhan 430072);Cloud Point Extraction for Speciation of Chromium by Electrothermal Atomic Absorption Spectrometry[J];Chinese Journal of Analytical Chemistry;2003-11
8 Wang Chang1, 2, Xie Wen-Bing3, Liu Jie3, Liu Jian-Tong*1 1(Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430072) 2(Graduate School of Chinese Academy of Sciences, Beijing 100039) 3(National Analytical Research Center of Electrochemistry & Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);Simultaneous Determination of Chromium(Ⅵ) and Chromium(Ⅲ) of Bioavailable Fraction in Bottom Mud by Flow Injection-Atomic Absorption Spectroscopy[J];Chinese Journal of Analytical Chemistry;2007-03
9 ZENG Yan,ZHAN Hong-mei,HU Bin(College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072);Nanometer-Sized ZrO_2 Microcolumn Separation Combined with ICP-MS for the Speciation of Chromium in Water Samples[J];Journal of Analytical Science;2010-02
10 LI Bing and YANG Hong-xia(National Research Center of Geoanalysis Beijing 100037);Recent advances in inductively coupled plasma mass spectrometry[J];Analytical Laboratory;2003-01
China Proceedings of conference Full-text Database 3 Hits
1 Su Zipeng~(1,2) Ye Jianzhi~(1,2) Yang Chunliang~(1,2) Jing Wei~1 1 Agricultural Product Processing Research Institute at Chinese Academy of Tropical Agricultural Sciences,Zhanjiang 524001; 2 Center for food quality supervision and testing (Zhanjiang),Ministry of Agriculture,524001;Effects of Solution Acidity on Determination of Cd and Cu in Rice by ICP-MS[A];[C];2011
2 Yin Ming;Progress and Prospect on Geoanalytical Techniques[A];[C];2008
3 WANG Hai-tao *,QU Zhi-yong,LU Di,QU Xia,WANG Jia-chun,GAO Jian-min (Yantai Entry-Exit Espection and Quarantine Bureau,Yantai 264200,China);Comparative Study on Determinations of Chromium in Medical Gelatin Capsule Shells by GFAAS and ICP-MS[A];[C];2012
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Lu Shaobo(Liaoning Province Chemical Industry and Geology Investigation Institute,Jinzhou 121000,China);Determination of high content silver in polymetallic ore by flame atomic absorption spectrophotometry[J];Fujian Analysis & Testing;2008-02
2 GUO Peng-Ran1,4,JIA Xiao-Yu1,4,DUAN Tai-Cheng1,ZHANG Yi-Ming3,XU Tao3,CHEN Hang-Ting1,2(National Analytical Research Center of Electrochemistry & Spectroscopy,Changchun Institute of Applied Chemistry1,State Key Laboratory of Electroanalytical Chemistry,Chinese Academy of Sciences2,Changchun 130022)3(Center of Physical Testing and Chemical Analysis,Baotou Research Institute of Rare Earth,Baotou 014010)4(Graduate School of Chinese Academ y of Sciences,Beijing 100039);Speciation Analysis of Rare Earth Elements in Soil[J];Chinese Journal of Analytical Chemistry;2008-11
3 SONG Xue-Jie1,2,LIU Xin-Li1,DUAN Tai-Cheng1,CHEN Hang-Ting1 1(State Key Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022) 2(Quality Center of Yangzi Pharmacy,Taizhou 225321);Determination of Impurities in High Pure Neodymium Oxide with Inductively Coupled Plasma Mass Spectrometry[J];Chinese Journal of Analytical Chemistry;2009-12
4 SHUAI Qin~(*1,2), YANG Wei~(2), HU Sheng-hong~(3), LU Ai-min~(2), ZHENG Chu-guang~(1)(1.National Laboratory of Coal Combustion of Huazhong University of Science and Technology,Wuhan 430074; 2.Faculty of Materials Sciences and Chemical Engineering;3.Faculty of Earth Sciences of China University of Geosciences,Wuhan 430074);Determination of Trace Rare Earth Elements in Air Particulate Matter by ICP-MS with Microwave Digestion[J];Journal of Analytical Science;2005-04
5 LI Ji-dong~*, WU Xing and ZHENG Yong-zhang (General Research Institute for Non-Ferrous Metals, Beijing,100088);Micro-column separation-ICP-MS determination of 14 REE impurities in highly-purified Tb_4O_7[J];Analytical Laboratory;2004-04
6 LIU Jiang-hui,JIAO Hong,XIE Shou-xin,XIE Xiang-na,HU Si and XIE Yu-shan(Guangdong Entry-Exit Inspection & Quarantine Bureau,Guangzhou 510623);Study on determination of rare earth elements in plant food by ICP-MS[J];Chinese Journal of Analysis Laboratory;2007-12
7 PAN Jian-zhong1,DENG Dong-qing2 and OU Yang-hui3 (1.Ganzhou Nonferrous Metallurgy Institute,Gznzgou 341000; 2.Gannan Normal University High School,Ganzhou 341000;3.Nanchang University,Nanchang 330031);Determination of Al、Mn、Ni、Zn、Pb、Th in rare earth chloride and carbonate by inductively coupled plasma-mass spectrometry[J];Chinese Journal of Analysis Laboratory;2010-11
8 Zheng Houlin(Beijing Institute of Gcology and Mineral Sources,ChinaNational Non- Ferrous Metals Industry Corp.Beijing 100012) and Wu Minjian(Central South University ofTechnology);Determination of Pb, Zn, Cu, Fe and Mn in Ores byThin Film X-Rau Fluorescence Spectrometry[J];ANALYTICAL LABORATORY;1994-01
9 WANG Pei-long, SU Xiao-ouInstitute of Quality Standards and Testing Technology for Agricultural Products, China Agricultural Academy of Science, Beijing 100081, China;Study on Determination of Rare Earth La and Ce in Feed by Using ICP-MS[J];Spectroscopy and Spectral Analysis;2007-11
10 FENG Zhong-wei(Guangxi Modern Polytechnic College,Hechi 547000,China);Rapid Determination of Copper,Lead,Zinc and Iron in Polymetallic Ore By Titrimetry[J];Technology & Development of Chemical Industry;2011-08
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 LI Xian hua, LIU Ying, TU Xiang lin, HU Guang qian, ZENG Wen(Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China);Precise determination of chemical compositions in silicate rocks using ICP AESand ICP MS: A comparative study of sample digestion techniquesof alkali fusion and acid dissolution[J];Geochimica;2002-03
2 Zhang Qi; Qian Qing(The Institute of Geology, Chinese Academy of Science, Beijing, 100029)Wang Yan(The Department of Geology, Northwest University, Xi 'an, 710069);GEOCHEMICAL STUDY ON IGNEOUS ROCKS OF OROGENIC BELTS[J];EARTH SCIENCE FRONTIERS;1999-03
3 Yang Weiran Yang Kunguang(China University of Geosciences, Wuhan, 430074)Liu Zhongming(Hubei Institute of Geological Science, Wuhan, 430030)Jian Ping(Yichang Institute of Geology and Mineral Resources, Yichang, Hubei, 433003);CALEDONIAN TECTONO THERMAL EVENT IN TONGBAI-DABIE OROGENIC BELT AND ITS SINGNIFICANCE[J];EARTH SCIENCE FRONTIERS;1999-04
4 Zhang Jing1, Chen Yanjing2,3, Chen Huayong3, Zhang Guan4, Yang Yan11.State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China2.Key Laboratory for Metallogenic Dynamics, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China3.Key Laboratory of Orogen and Crust Evolution, Peking University, Beijing 100871, China4.No.3 Geology and Survey Team, Henan Bureau of Geology and Mineral Resource, Xinyang 464000, China;Isotope geochemistry of the Weishancheng stratabound gold-silver ore belt,Tongbai County,Henan Province,China[J];Earth Science Frontiers;2008-04
5 WEI Chang-shan~1, YANG Zhen-qiang~(1), FU Jian-ming~(1,2), WEI Jun-qi~(1,2), ZHANG Ye-ming~(1,2) (1.Yichang Institute of Geology and Mineral Resources, Yichang Hubei 443003, China; 2.Graduate School,China University of Geosciences, Wuhan Hubei 430074,China);ORIGIN AND PALAEOTECTONIC SETTING OF LIUSHANYAN COPPER-ZINC DEPOSIT IN TONGBAI,HENAN PROVINCE[J];Geological Science and Technology Information;2004-02
6 CHEN Jian-li~(1,2)(1.Geological Survey Institute of Henan Province, Zhengzhou450007;2.No. 1 Institute of Geology and Exploration, Henan Geology and Exploration Bureau, Nanyang473056);THE CHARACTERISTICS AND ORE EXPLORATION OF MASSIVE SULFIDE DEPOSITS IN ER'LANGPING GROUP MARINE VOLCANIC ROCKS[J];Geology and Prospecting;2004-06
7 Sun Weidong Li Shuguang(Department of Earth and Space Sciences, University of Science and Technology of China,Hefei, Anhui)Sun Yong, Zhang Guowei(Department of Geology, Northwest University, X?an, Shaanxi)Zhang Zongqing(Institute of Geology, CAGS, Beijing);CHRONOLOGY AND GEOCHEMISTRY OF A LAVA PILLOW IN THE ERLANGPING GROUP AT XIXIA IN THE NORTH QINLING MOUNTAINS[J];Geological Review;1996-02
8 PENG Yi, YAN Changhai, WAN Shouquan, MA Hongwei, ZHAO Rongjun Henan Institute of Geological Survey, Zhengzhou, Henan, 450007;Geological-Geochemical Characteristics of the Liushanyan Massive Sulfide Deposit in the Eastern Qingling Mountains[J];Geological Review;2005-05
9 Chen Yongjun Liu Yijian (Institute of Rock & Mineral Analysis,Beijing,100037);Determination of Trace and Major Eelements in Niobium-Tantalum and Rare Earth Minerals by X-Ray Fluorescence Spectrometry[J];Chinese Journal of Analytical Chemistry;1991-05
10 Liu Xiangsheng (Beijing General Research Institute for Non-ferrous Metals, Beijing 100088);Current Status and Prospect for the Determination of Rare Earth Elements by Inductively Coupled Plasma Mass Spectrometry[J];Chinese Journal of Analytieal Chemistry;1995-10
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved