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《Chinese Journal of Organic cHEMISTRY》 1992-03
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The Asymetric Reduction of Acetophenone With Polymer-supported Borohydride Reducing Systems

ZHONG Jian-Hua;JIANG Ji-Long;CHEN Jia-Wei;XU Zhang-Huang;WU Min Department of Chemistry, Hubei University, 430062 Wuhan, Hubei  
Reaction of ion exchange resin D 151(P)-COOH made in China with sodium boro-hydride in glyme at 65℃ gives polymer-supported reagent Na~+[P-COO(BH_3)]~-. The poly-mer-supported reagent reacts with chiral acids or alcohols to provide the polymer-supportedreductants. Then acetophenone was reduced by the reductants in rather low enantioselectivity(less than 30.1% of optical yield.)
【Fund】: 国家自然科学基金
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【References】
Chinese Journal Full-text Database 2 Hits
1 Yang,GuiChun Huang,JinXia Chen,ZuXin Chen,JiaWei(Department of Chemistry, Hubei University,Wuhan,430062);The Application of SolidSupportedBorohydride Reducing Reagents in Organic Synthesis[J];CHINESE JOURNAL OF SYNTHETIC CHEMISTRY;1998-02
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【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Deng Wen-Li; Yang Da-Ben (Department of Materials Science and Engineering, EPRL, University of Electronic Science and Technology of China, Chengdu, 610054);Crystal and Molecular Structures of N-(Phenyl) phthalic Imidine and N-(p-Methylphenyl) phthalic Imidine[J];CHINESE JOURNAL OF STRUCTUNAL CHEMISTRY;1994-06
2 Sun Licheng;Shen Tao;Yang Jinzong Institute of Photographic Chemistry,Academia Sinica, Beijing 100101,P.R.China Department of Fine Chemicals Technology,Dalian University of Technology,Dalian 116012,P.R.China;The Elucidation of Structure for Two-equivalent Pyrazolone Magenta Coupler by 2D-N-NMR Spectroscopy[J];Journal of Instrumental Analysis;1992-02
3 Jiang Huajiang;Zhou Wanping Department of Bio-Chemistry;Application of Cp_2 Ticl_2 and its Derivative in Organic Synthesis[J];Journal of Taizhou Teachers College;1996-06
4 WANG Zhi-Min;ZHOU Wei-Shan Shanghai Institute of Organic Chemistry, Academia Sinica, 200032 Shanghai;The Effect of Catalytic Amount of Calcium Hydride and Silica Gel on Sharpless Asymmetric Epoxidation[J];Chinese Journal of Organic cHEMISTRY;1992-01
5 ZHANG Yong-Min;FU Chun-Ling;FAN Wei-Qiang Department of Chemistry, Hangzhou University, 310028 Hungzhou, Zhejiang;Cp_2 TiCl_2-Catalyzed Reaction of Grignard Reagent with gem-Dihaloalkanes[J];Chinese Journal of Organic cHEMISTRY;1992-01
6 CHEN Shu-Hua;LI Dong-Hong;CHEN Yan Depaertment of chemistry, Sichuan University 6l0064 Chengdu, Sichuan;Synthesis of Estrogenic Steroid-Porphyrins and Their Metal Complexes[J];Chinese Journal of Organic cHEMISTRY;1992-01
7 SUN Shi-Cheng;QIU Fa-Yang;LIU Zhu-Jin Shanghai Institute of Organic Chemistry, Academia Sinica, 200032 Shanghai;Novel Approach to Some Analogues of Methyl Jasmonate[J];Chinese Journal of Organic cHEMISTRY;1992-02
8 SHEN Fu-Ren;HU Ji-Ping;YANG Gao-Sheng Institute of Organic Chemistry, Anhui Normal University, 241000 Wuhu, Anhui;Synthesis of 1, 10-phenanthroline Complexes of Cyclopentadienyl Early Lanthanide Dichloride[J];Chinese Journal of Organic cHEMISTRY;1992-03
9 LIU Wan-Ying Chengdu Institute of Organic Chemistry, Academia Sinica, 610015 Chengdu, Sichuan;Advances in Organic Chemistry of Nonequilibrium Plasma[J];Chinese Journal of Organic cHEMISTRY;1992-04
10 WANG De-Xin Institute of Materia Medica, Chinese Academy of Medical Sciences, Beijing 100050;Studies on Enhancing the Coupling Completeness in Peptide Synthesis[J];Chinese Journal of Organic cHEMISTRY;1992-04
【Co-references】
Chinese Journal Full-text Database 8 Hits
1 QIN Cai-Qin CHEN Jia-Wei(Wuhan Pharmaceutical Factory, Wuhan) (Department of Chemistry, Hubei University, Wuhan, 430062);Catalytic Reduction of Some Nitrogenous Functional Group Compounds with Borohydride Exchange Resin[J];Chemical Research In Chinese Universities;1993-08
2 Chen Jing Chen Yingwu (Department of Chemical Engineering,Wuhan Institute of Chemical Technology,Wuhan 430074),Huaxue Shiji,1993,15(5),268-9,279;Competition between carbonyl compounds and phenylethylene in reduction by borohydride anion exchange resin(BER)over PdCl_2 as the catalyst[J];Chemical Reagents;1993-05
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4 Yang Guichun; Zhong Jianhua ;Chen Jiawei ;Zhang Wanxuan (Department of Chemistry, Hubei University, Wuhan, 430062);REDUCTION OF CARBOXYLIC ACID WITH POLYMER-SUPPORTED BOROHYDRIDE ANION EXCHANGE RESIN AND I_2[J];ION EXCHANGE AND ADSORPTION;1997-04
5 P.Hodge~(**) CHEN Jia-Wei~* JIANG Ji-Long LIU Mu-Guang~(***) HU Mou-Gang LU Jun HU Quan-Yuan (Department of Chemistry,Hubei University,430062 Wuhan);Preparation of Borohydride Anion Exchange Resin (BER) and Reductions of Carbonyl Group and Acyl Chloride Compounds[J];Chinese Journal of Organic cHEMISTRY;1989-06
6 XIONG Gui-Rong (Science & Technology Department, Town and Towmship Enterprise Service Bureau of Wuhan, 430022 Wuhan, Hubei) HUANG Jin-Xia, ZHANG Wan-Xuan CHEN Jia-Wei (Department of Chemistry, Hubei University, 430062 Wuhan, Hubei);Preparation of Polystyryl Diphenyl Phosphine Copper (Ⅰ) Tetrahydroborate and Reduction of Acyl chloride[J];Chinese Journal of Organic Chemistry;1995-06
7 Chen Jiavvei and Huang Jinxia(Department of Chemistry,Hubei University,Wuhan 430062)Yue Xiali(Huazhong Agricultural University, Wuhan );Preparation of Polymeric Borohydride Anion Reductant and Its Application in Ester Reduction[J];CHINESE JOURNAL OF APPLIED CHEMISTRY;1994-04
8 HU Mou-Gang~* CHEN Jing CHEN Fen-Er CHEN Jia-Wei~a (Department of Chemical Engineering,Wuhan Institute of Chemical Technology,Hubei 430073;~aDepartment of Chemistry,Hubei University);REDUCTION OF SOME CARBONYL GROUPS BY ION EXCHANGE RESIN SUPPORTED BOROHYDRIDE[J];Chinese Journal of Pharmaceuticals;1991-10
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