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《Chinese Journal of Organic cHEMISTRY》 1993-04
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Study on the Mechanism for Reaction of p-Nitrotoluene with Sodium Polysulfide

CHEN Nian-Gai;ZHOU Bi-He;ZHONG Yu-Shan;LIU Chun-Hui;XIN Bai-Fu Department of Chemistry, Heilongjiang University, 150080 Harbin, Heilongjiang Centre of Analysis and Measurement, Heilongjiang University, 150080 Harbin, Heilongjiang  
In aqueous ethanolic solution of sodium polysulfide and sodium hydroxide, p-nitrotoluene isconverted to p-amino-benzaldehyde. The mechanism of this reaction is still obscure. Afterexamination of variation of UV and visible spectra and determination of ESR spectrum of this reactionmixture, we suggest a mechanism involvn?g a series of condensation reactions. This mechanismdoesn't contradict with our observations and other related experimental results.
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【Co-references】
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