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《Chinese Journal of Liquid Crystals and Displays》 2005-05
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Synthesis and Luminescent Properties of Schiff Bases and Their Zinc Complexes

ZHAO Zhe-hui~(1,2),YU Gui~2,DI Chong-an~2,SUN Xiao-bo~2,LI Nan~1,LIU Yun-qi~2,ZHU Dao-ben~2(1.College of Science,China Agriculture University,Beijing 100094,China;2.Laboratory of Organic Solids,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China)  
Two soluble Schiff bases and their Zn complexes functionalized with electron-donor groups were synthesized,characterized and evaluated for use in electroluminescence devices.The optical properties of these materials have been successfully manipulated with increasing conjugated structures.The absorption peaks of the compounds shifted from 397 nm to 429 nm,and the emission peaks shifted from 543 nm to 560 nm,respectively.An electroluminescence device of ITO/PVK∶ZnDEDN/BCP/Alq_3/LiF/Al was fabricated by spin-coating the blend of a polymer PVK and the ZnDEDN with precise(doping) ratio.The luminance efficiency and the maximum luminance were about 0.19 cd/A at current density 0.38 mA/cm~2 and 143 cd/m~2 at 27.5 V.The turn-on voltage was 14.5 V(at 1 cd/m~2).These preliminary results illustrated that this kind of complexes can be new candidates for light emitting(diodes.)
【Fund】: 国家自然科学基金资助项目(No.20082001 No.90206049);; 国家重点基础研究发展规划资助项目(No.G2000077505 No.2002CB613400 No.2001CB610507)
【CateGory Index】: TN104;
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