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《Journal of Yunnan University of Nationalities(Natural Sciences Edition)》 2012-01
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Study on the Synthesis of Copper Ion Imprinted Polymer byUsing Cu~(2+)-1,10-Phenanthroline Complex as Template Molecules

LI Li-ping,YANG Yun-jin,TAO Jin-Fei,LIU Peng,CAO Qiu-e (Key Laboratory of Medicinal Chemistry for Natural Resource,Ministry of Education,School of Chemical Science and Technology,Yunnan University,Kunming 650091,China)  
A copper ion imprinted polymer(Cu(Ⅱ)–IIP) was prepared from methanol by precipitation polymerization using Cu2+-1,10-Phenanthroline complex with the mole ratio of 1∶2 as template molecules,4-vinyl pyridine as the functional monomer,ethyleneglycol dimethacrylate as the cross-linking agent in the composition of template molecules,functional monomer and cross-linking agent of 1∶2∶30(mole ratio).The maximum adsorption capability(Qmax) and imprinting factor(IF) of this imprinted polymer was calculated as 75.01 mg/g and 1.77 at room temperature and pH 5.0,and the adsorption process could achieve its equilibrium within 1h.The recovery and relative standard deviation(RSD) for the extraction of Cu2+ from the solution containing 5.0μg/mL Cu2+ by the solid phase extraction column prepared with the Cu(Ⅱ)–IIP was 89.7% and 4.7%(n=5),respectively.The results showed that the Cu(Ⅱ)–IIP prepared in this paper possessed a good prospect in the application as a solid phase extraction reagent for the analysis and determination of Cu(Ⅱ).
【Key Words】： Cu(Ⅱ) ion-imprinted polymer precipitation polymerization solid phase extraction
【Fund】： 国家自然科学基金(20965009);; 云南省自然科学基金(2009CD08)
【CateGory Index】： O631.3
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