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《Chinese Journal of Applied Chemistry》 2008-08
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Preparation and Permeation Characteristics of Copper Ion Imprinted Polymer Membranes

ZHONG Shi-An, YUAN Zhou-Lü, LI Wei, QIAO Rong, TANG Chao-Fu(College of Chemistry and Chemical Engineering,Central South University,Changsha 410083)  
With Cu(Ⅱ) ions as the template, molecular imprinted polymer membranes with supporting membranes were synthesized by UV irradiation. The surface features of the membranes were analyzed by scanning electron microscopy. The imprinted membranes exhibited selective permeation for Cu(Ⅱ) ions(compared to Zn(Ⅱ) ions, Ca(Ⅱ) ions etc). Effects of different supporting membranes, porosifier and functional monomers on the imprinted membranes′ structure and permeation characteristics were investigated respectively, and pH value, cation and anion effects were also investigated. The results indicated that the membranes synthesized with PVDF membrane and cupric acetate exhibited selective permeation for Cu(Ⅱ) ions when the pH was 1 and the anion was acetate.
【Fund】: 湖南省自然科学基金(06JJ4117)资助项目
【CateGory Index】: O631
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