Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
Add to Favorite Get Latest Update

Catalytic Properties of CuO/CeO 2 and CuO/Al 2O 3 Catalysts

Zhong Yijun * (Department of Chemistry,Zhejiang Normal University,Jinhua 321004) Chen Ping, Zhou Bi, Luo Mengfei (Institute of Catalysis,Hangzhou University,Hangzhou)  
The oxidation activity of CuO supported on CeO 2 and Al 2O 3 was investigated using the oxidation of carbon monoxide as a model reaction. The reducibility and Cu oxide species of the catalysts were studied by XRD and TPR techniques. The susceptibility of CO to oxidation strongly depends on the support: the catalytic activity of CuO/CeO 2 is much higher than that of CuO/Al 2O 3. It is found that the existing forms of copper species, crystal particle size of CuO, the reducibility and activity of catalysts are affected by thermal treatment. The formation of CuAl 2O 4 spinal species at high temperature is the main reason for activity decrease of CuO/Al 2O 3 catalyst, and the increase of crystal particle size of CuO is the main reason for activity decrease of CuO/CeO 2.
【Fund】: 浙江省应用化学重点实验室资助
【CateGory Index】: O643.361
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 10 Hits
1 GUO Xikun*, LIU Qinghong, LIN Qichun(Department of Chemistry,Shantou University, Shantou 515063, Guangdong, China);Preparation of La-Modified Cu-Based Al-Ce Pillared Montmorillonite and Its Catalytic Properties for Selective Reduction of NO by Propylene[J];Chinese Journal of Catalysis;2004-12
2 ZHENG Xiucheng~(1,2*),ZHANG Xiaoli~1,WANG Shurong~2,YU Lihua~2,WANG Xiangyu~1,WU Shihua~(2*) (1 Department of Chemistry,Zhengzhou University,Zhengzhou 450052,Henan,China;2 Department of Chemistry,Nankai University,Tianjin 300071,China);Low-Temperature CO Oxidation over Different CuO/CeO_2 Catalysts[J];Chinese Journal of Catalysis;2005-11
3 YAO Guo-sheng(School of Science,Changzhou Institute of Technology,Changzhou 213002);Research on the Superficial Acid and Alkali Nature of Catalyst of ZnO/γ-Al_2O_3 and CuO/γ-Al_2O_3[J];Journal of Changzhou Institute of Technology;2007-02
4 ZHAO Hui-Zhong~(1,2*),GE Shan~(1),WANG Hou-Zhi~(1,2),ZHANG Wen-Jie~(2)(1.The Hubei Province Key Laboratory of Ceramics and Refractories,Wuhan University of Science and Technology,430081;2.Center of Nanomaterials and Technology,Wuhan University of Science and Technology,Wuhan 430081,China);Composition of Cu/SiO_(2) Nanometer Aerogel and Its Catalytic Properties for CO Oxidation[J];Chemical Journal of Chinese Universities;2006-05
5 WEI Shimin, DU Fanglin, Zhang Zhikun (Research Center for Nanostructured Materials, Qingdao Institute of Chemical Technology, Shandong Qingdao 266042, China);Latest researches in CO oxidation catalysts[J];Gongye Cuihua (Industrial Catalysis);2003-01
6 LI Jin-yun,LUO Lai-tao,WANG Ju-zhi (Institute of Applied Chemistry,Nanchang University,Nanchang Jiangxi,330047 PRC);The Effect of Transitional Metals on Cu_(60)-Zn_(30)-Al_(10) Catalysts for Water Gas Shift Reaction[J];Jiangxi Science;2004-03
7 Wang Enguo\ Chen Songying * and Wang Jianping ** (College of Material Science and Engineering, Taiyuan University of Technology,030024 Taiyuan; * Institute of Catalysis, Zhejiang University, 310028 Hangzhou; ** College of Chemical Engineering and;STUDY ON CO OXIDATION OVER CuO/ZrO_2 CATALYSTS[J];Coal Conversion;2001-02
8 WEI Shi-min, DU Fang-lin (Research Center for Nanostructured Materials, Qingdao Institute of Chemical Technology, Shandong Qingdao 266042);Research Progress of CO Oxidation Catalysts[J];Journal of Qingdao Institute of Chemical Technology;2002-04
9 GU Li-jun, XIE Ying, LIU Bao-sheng, CHEN Xiao-ping, WANG Le-fu (Institute of Chemical Engineering, Maoming College, Maoming525000, China);EFFECT OF CALCINATION TEMPERATURE ON C_3H_6-SCR OF NO OVER CuO/γ-Al_2O_3 AND CeO_2-CuO/γ-Al_2O_3[J];Journal of Fuel Chemistry and Technology;2004-02
10 FENG Xue-feng,JIN Wei-gen,CHEN Chang-lin(Faculty of Chemistry Biology and Materials Science,East China Institute of Technology,Fuzhou 344000,China);Effects of Rare Earths on the Performances of Cu/ZnO/Al_2O_3 Catalysts for Water-gas Shift Reaction[J];Natural Gas Chemical Industry;2007-06
Chinese Journal Full-text Database 4 Hits
1 Fang Shunong;Lin Peiyan;Fu Yilu(Department of Chemical Physics University of Science and Technology of China,Hefei 230026);A Study of the Dispersed States of Copper Species on CuO/γ-Al_2O_3 Catalysts[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1994-02
2 Xu Jinsong (Department of Chemical and Petroleum Industry, Jiangsu Province, Nanjing 210024)Wang Ren(Research Institute of Industrial Catalysis, East China Institute of Chemical Technology, Shanghai 200237);The Effect of ZnO and BaO on the Thermal Stability of CuO/γ-Al_2O_3 Catalyst[J];Petrochemical Technology;1992-02
3 Huang Xing liang and Yin Huiling(Chemical Engineering Dpartment, Petroleum University, Beijing 100083);Effect of the Pre-Treatment of γ-Al_2O_3 Support and Calcination Temperature on CuO-Supported Catalysts[J];Petrochemical Technology;1993-08
4 Wei Zhaobin~* Chen Yixuan Li Wenzhao (Dalian Institute of Chemical Physics, Academia Sinica);STUDIES ON THE REDUCTON AND OXIDATION CHARACTER OF Pd-CuO/TiO_2 CATALYST[J];Acta Physico-chimica Sinica;1988-01
Chinese Journal Full-text Database 10 Hits
1 Wei Zhao-bin, Xin Qin and Guo Xie-xian(Dalian Institute of Chemical Physics, Academia Sinica, Dalian 110023);STUDIES ON HYDRODESULFURIZATION CATALYST: EFFECT OF TiO_2-MODIFIED Al_2O_3 ON DISPERSION AND CHEMICAL BEHAVIOR OF MoO_3[J];Chinese Journal of Catalysis;1991-04
2 Luo, Xiao-ming; Chen, Yi(Department of Chemistry, Nanjing University, Nanjing 210008)and Han, Shi-ying(Center of Materials Analysis, Nanjing University, Nanjing 210003);REDUCIBILITY OF V_2O_5-SnO_2 CATALYSTS AND ITS RELATION WITH OXIDATION ACTIVITY[J];Chinese Journal of Catalysis;1992-04
3 Zheng, Bai-cun and Wang, Ren(Research Institute of Industrial Catalysis, East China University of Chemical Technology, Shanghai 200237);STATES OF CuO ON SURFACE OF TiO_2 SUPPORT[J];Chinese Journal of Catalysis;1992-06
4 Fu Xianzhi, Yang Xiyao and Pang Li (Department of Chemistry, Peking University, Beijing);STUDY ON THE HYDRODESULFURIZATION CATALYSTS ——Ⅱ.THE SURFACE CHEMICAL CHARACTERIZATION OF SULFIDED Mo-Co-Ti/γ-Al_2O_3BY XPS[J];Journal of Molecular Catalysis;1989-02
5 Zhu Bo;Chen ping;Luo Mengfei;Yuan Xianxin(Department of Chemistry,Hangzhou University,Hangzhou 310028)Wu Hongli(Central Laboratory,Hangzhou University,Hangzhou 310028);Reducibility of Cu-Ag/γ-Al_2O_3 Catalyst and Its Activity for Benzene Oxidation[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1995-04
6 Zhou Zhenhua ②, Yan Weihong ①, Zhang Yaojun ①, Wei Zhaobin ①, Den Chun ②, Xin Qin ① ( ① State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, the Chinese Academy of Sicences, Dalian 116023) ( ② Fujian Ningde N;Studies on Dispersion State and Catalytic Activities of MoO 3/(TiO 2 SiO 2)[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1996-03
7 ZHU Bo;LUO Meng-Fei;ZHONG Yi-Fen;LI Bin-Feng;YUAN-Xian-Xin(Institute of Catalysis, Hangzhou University, Hangzhou,310028)CHEN Ping;WU Hong-Li(Department of Chemistry,Hangzhou University)(Central Laboratory, Hangzhou Univeristy);Effect of the Performance of Cu/γ-Al_2O_3 Catalyst with the Addition of Ag[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1995-12
8 CHEN Xian, QIAO Xu, TANG Ji-hai, CUI Mi-fen (College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China);Preparation and Catalytic Performance of Rare Earth Composite Molecular Sieve Catalyst[J];Journal of Chemical Engineering of Chinese Universities;2008-01
9 Zong Qiuyun ;Mao Min;Yang Yanwei; Tang Fushan(Research Institute of Qilu Petrochemical Co, Zibo, Shandong, 255400);Effect of Titanium on the Activity of Sulfur-tolerant Shift Catalyst[J];GONGYE CUIHUA (INDUSTRIAL CATALYSIS);1994-01
10 YANG Tao1 LI Chun-xin2 WANG Cheng-xue3 (1 China Datang Hulunbeier Chemical Fertilizer Co.,Ltd,Hulunbeier,021008,China;2 Jilin Petrochemical Corporation Calcium Carbide Factory,Jilin,132021,China;3 Chemical Technology Institute Changchun University of Technology, Changchun ,130012,China);THE PREPARATION AND EVALUATION OF COPPER-BASED CATALYSTS FOR THE GAS DESULFURIZATION AND DENITRIFICATION[J];Environmental Chemistry;2009-03
Chinese Journal Full-text Database 10 Hits
1 Liu Xiaoqun1 Jiang Hongfu2 Yao Wenrui31. Jiangxi School of Industrial Engineering Professional Technique, Pingxiang 337005; 2. Chinese University of Sciences and Technology,Hefei 230022; 3. Anhui University of Technology,Maanshan 243002;Devlopment Study on Removing Hydrogen Sulfide[J];Anhui Chemical Industry;2004-05
2 FENG Chang-gen, ZHANG Jiang-shan, WANG Ya-jun (State Key Laboratory of Prevention and Control of Explosion Disasters, Beijing Institute of Technology, Beijing 100081, China);Advances on research of perovskite catalyst for purification of motor-vehicle's exhaust (part 1)[J];Journal of Safety and Environment;2004-03
3 FENG Chang-gen, ZHANG Jiang-shan, WANG Ya-jun (State Kay Laboratory of Prevention and Control of Explosion Disasters, Beijing Institute of Technology, Beijing 100081, China);Advances on research of perovskite catalyst for purification of motor-vehicle's exhaust (part 2)[J];Journal of Safety and Environment;2004-04
4 LIN Xiuhua (Xiamen University,Xiamen 361005,CHN);I V characteristics variation in LEDs with X ray irradiation[J];SEMICONDUCTOR OPTOELECTRONICS;1997-04
5 Gao Luhe Hu Dingjun (Beijing Vocational & Technical Institute of Industry, Beijing 100042,China);Study on the Catalyzing and Refining Technology of Car Emission[J];Journal of Beijing Vocational & Technical Institute of Industry;2003-04
7 ZHANG Wu-zhi,CHEN Qi,LI Hui-ping,HOU Feng-zhen(Department of Inorganic Materials,East China University of Science and Technology,Shanghai 200237,China);Synthesis of Bimodal Porous Bioglass[J];Glass & Enamel;2008-03
8 YANG Yi-long,XIN Xiu-lan,HU Dai-qiang,QIN Sheng-jun(College of Chemical and Environmental Engineering,Beijing Technology and Business University,Beijing 100037,China);ANALYSIS ON FACTORS AFFECTING PREPARATION OF TiO_2 GEL BY SOL-GEL METHOD[J];Journal of Beijing Technology and Business University(Natural Science Edition);2007-03
9 Lu Guan-zhong and Wang Ren(Research Institute of Industrial Catalysis, East China University of Chemical Technology, Shanghai 200237);ROLE OF CERIA IN NON-PRECIOUS METAL OXIDE CATALYSTS I. THE OXYGEN PROPERTIES OF Cu AND Ce OXIDES SUPPORTED ON γ-Al_2O_3[J];Chinese Journal of Catalysis;1991-02
10 Lu Guan-zhong and Wang Ren(Research Institute of Industrial Catalysis, East China University of Chemical Technology, Shanghai 200237);ROLE OF CERIA IN NON-PRECIOUS METAL OXIDE CATALYSTS Ⅱ. THE OXYGEN PROPERTIES OF Mn-O AND Mn-Ce-O SUPPORTED ON ALUMINA[J];Chinese Journal of Catalysis;1991-04
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 TENG Meiling,LUO Laitao(Institute of Applied Chemistry,Nanchang University,Nanchang 330031,Jiangxi,China);Catalytic Performance of Mesoporous Ce_(1-x)Zr_xO_2-Supported CuO-Based Catalyst for CO Selective Oxidation under H_2-Rich Conditions[J];Chinese Journal of Catalysis;2008-12
2 SU Wei-Guang,YING Pin-Liang,FENG Zhao-Chi,LI Can (State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China);FTIR Spectroscopy Study on Quantum Size Effect of CuO_x Nanoparticles in CuO_x/SiO_2[J];Chemical Journal of Chinese Universities;2010-05
3 ZHANG Si-Fang ZHANG Yue-Wen DONG Jin-Long FENG Wei (Department of Chemistry,Taiyuan Normal University,Shanxi,Taiyuan 030031,P.R.China);The Effect Study of Preparation on Composite Copper Cobalt Cerium System Catalysts for Dehydration of Methyl Alcohol[J];Chinese Journal of Spectroscopy Laboratory;2009-05
4 Li Guiju1,Zhu Lixiang1,He Yingchun2(1.Tianjin Key Laboratory of Marine Resources & Chemistry,College of Environmental Science and Engineering,Tianjin University of Science and Technology,Tianjin 300457,China;2.College of Mechanical Engineering,Tianjin University of Science and Technology,Tianjin 300457,China);Study on the application of wet catalytic oxidation process to the treatment of phenol-containing cleaning wastewater[J];Industrial Water Treatment;2010-05
5 YANG De-qiang,SUN Hua-jun,ZHOU Qing-hua(Heilongjiang University of Traditional Chinese Medicine,Heilongjiang Haerbin 150040,China);Effects of Different Calcination Temperature of ZnO/SBA-16 on the Catalytic Activity of CuO/ZnO/SBA-16 in CO Oxidation[J];Guangzhou Chemical Industry;2011-15
6 Xu Lixin,Zhu Mingqiao,He Chaohong Department of Chemical and Biochemical Engineering,Zhejiang University,Hangzhou 310027;Research progress of solid catalysts for selective oxidation of cyclohexane using oxygen[J];China Synthetic Fiber Industry;2006-01
7 Fan Xiaopeng Li Caiting Zeng Guangming Tian Lihui Gao Zhao Ding Yanmin(College of Environmental Science and Engineering,Hunan University,Changsha 410082,China);Experimental research of removing elemental mercury from flue gas by CuO-CeO_2/AC[J];Chinese Journal of Environmental Engineering;2010-02
8 GUO Xi-kun,WANG Xiao-ming(Department of Chemistry,Shantou University,Shantou 515063,China);Preparation of Cu/ZrO_2/S_2O~(2-)_8/γ-Al_2O_3 Solid Acid Catalyst and Its Catalytic Activity to Selective Reduction of NO[J];Environmental Science;2008-06
9 FENG Ru-bin , LI Ping , LONG Gui-mei (Dept. of Urban Construction ,HIAST, Handan 056038,China);The reaction of NO-O_2 on CuSO_4/Al_2O_3 surface[J];Journal of Hebei Institute of Architectural Science and Technology;2002-03
10 GONG Lei1,2,ZHANG Ning1,LUO Lai-Tao1,WANG Liang1,AO Zhi-Yong1(1.Department of Chemistry,Nanchang University,Nanchang,330031,China;2.Department of Chemistry,Jiangxi Agricultural University,Nanchang,330045,China);Effects of various supports on CO oxidation over Cu-based catalysts in H_2-rich gases[J];Chemical Research and Application;2010-07
China Proceedings of conference Full-text Database 3 Hits
1 He Mai, Fang Ping, Xie Yunlong, Luo Mengfei (Institute of Physical Chemistry, Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Zhejiang Normal University, Jinhua 321004, China);Distribution of CuO Species on CuO/Al_2O_3 and CuO/CeO_2-Al_2O_3 Catalysts[A];[C];2005
2 Wang Huifeng Gu Huazhi Wang Houzhi (Key Lab of Hubei Province for Ceramics and Refractories, Wuhan University of Science and Technology, Wuhan,430081 );Effect of Different Drying Conditions on Grain Size and Material Property of Cu-doped 3Y-ZrO2 Nanophase Material[A];[C];2004
3 FENG Yachen,TAN Qing(Southwest Research & Design Institute of Chemical Industry,Chengdu 610225,Sichuan,China);Research on denitration of selective catalytic reduction catalyst supported on honeycomb cordierite[A];[C];2011
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved