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《Transactions of China Pulp and Paper》 2008-01
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Preparation and Application of Copolymer of Styrene and Mono-maleate Octaester as Surface Sizing Agent

ZHANG Guo-yun ZHENG Shuang(Shaanxi University of Scinece and Technology, Xi'an, Shaanxi Province,710021)  
In this paper a new type of surface sizing agent was synthesised using styrene and maleic anhydride and mono-maleate octaester as raw material and benzoyl peroxide as initiator in the medium of toluene, the copolymer separated by precipitation and modified with ammonia. The molecule weight of the copolymer of styrene and maleic anhydride and mono-maleate octaester was determined by mean of GPC spectroscopy, the sized surface of paper was investigated by means of SEM. The copolymer of styrene and maleic anhydride and mono-maleate octaester is an efficient surface sizing agent which can improve the size degree and surface strength and printing performance of the paper, when the dosage of surface sizing agent (oxidized corn starch ∶copolymer emulision (3#)=40∶1) is 1.0 g/m2, size degree of the sized paper is 9s, tensile strength is increased by 6.8%, breaking strength is increased by 10.1%, the picking speed of the paper is 2.87 m/s, and the printing ink absorbency is 42%.
【Key Words】: surface sizing agent styrene-mono-maleate octaester random copolymer synthesis
【Fund】: 陕西科技大学创新团队基金(SUST-25)资助项目
【CateGory Index】: TS727.5
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