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《The Chinese Journal of Nonferrous Metals》 2003-04
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Mechanism and factors of breakdown of anode alumina film in organic electrolyte

ZHU Xufei, LIU Lin, ZHAO Baochang (School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China)  
The breakdown of anode oxidation film on highly pure aluminum in organic electrolyte and the process of electrolyte spark were described, and the mechanism was discussed. It is verified that the highpressure O2 evolution in the flaws and pores of oxidation film is the precursor of breakdown on oxidation film and electrolyte spark. The atmosphere pressure around formation slot affects the voltage of breakdown of oxidation film and electrolyte spark. When the atmosphere pressure is 0.01 MPa, the breakdown voltage of oxidation film is 435 V; when the atmosphere pressure is 0.10 MPa, the breakdown voltage is 460 V, and when the atmosphere pressure is 0.20 MPa, the breakdown voltage is above 500 V.
【CateGory Index】: TG174.4
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