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《The Chinese Journal of Nonferrous Metals》 2005-05
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Extraction of copper from nickel and cobalt sulfate solution with BK992

GUO Hua-jun1, WANG Xiao-qiong1, LI Xin-hai1,ZHANG Xin-ming2, WANG Zhi-xing1, PENG Wen-jie1, XU Sheng-fei1(1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China; 2. School of Materials Science and Engineering, Central South University, Changsha 410083, China)  
Copper was extracted from nickel and cobalt sulfate with BK992. The effects of pH of aqueous solution, the phase ratio(O/A), concentration of BK992 and reaction time on the extraction were investigated. The results show that the extraction reaches equilibrium quickly. With increasing pH of the aqueous solution, the effect of copper extraction from the solution is improved greatly, but the mass loss of nickel and cobalt occurs when the pH is ~above 4.0. The bigger the O/A ratio is, the better the effect of the extraction is. With the increasing content of BK992, the distribution ratio of copper increases. The optimum conditions are determined that concentration of BK992 in the organic phase is 20% (volume fraction), the phase ratio (O/A) is 1∶2, pH of the aqueous solution is 3.0, and the reaction time is 10min. Under the optimized operating conditions, copper can be extracted effectively and the extraction rate at the first stage reaches 93.06%, the extraction capacity of BK992 is 17.30g/L and the stripping rate reaches ~91.79% , the pure transfer mass of copper is 15.88g/L.
【Fund】： 国家自然科学基金资助项目(50302016);; 中南大学博士后基金资助项目
【CateGory Index】： TF816
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【References】
Chinese Journal Full-text Database 10 Hits
1 Li Changdong,Liu Genghao,Zhou Hanzhang,Tang Honghui,Qiu Jianshen(FOSHAN BRUNP RECYCLING TECHLOGY CO.,LTD.,FOSHAN 528244,China);The Recovery of Copper from Spent Lithium Ion Battery[J];Guangdong Chemical Industry;2013-02
2 ZHANG Xiaojuan1,LI Xingang1,2,CAO Hongbin3(1 School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China;2 National Engineering Research Center of Distillation Technology,Tianjin University,Tianjin 300072,China;3 Key Laboratory of Green Process and Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100090,China);Separation of Fe and Ni by solvent extraction with LK-C2 from nitric acid leaching solution of wasted printed circuit boards[J];Chemical Industry and Engineering Progress;2009-04
3 WEN Jun-jie,ZHANG Qi-xiu,ZHANG Gui-qing,ZHANG Li-ping(College of Metallurgical Science and Engineering,Central South University,Changsha 410083,Hunan,China);Deeply Removing Copper from Nickel Chloride Electrolyte with Novel Silica-polyamine Resin[J];Mining and Metallurgical Engineering;2007-03
4 LI Xue-peng(Institute of Research & Designing of YTC,Gejiu 661000,Yunnan,China);Nickel Sulphate Electrolyte Extraction Purified by M5640+P204+P507[J];Nonferrous Metals(Extractive Metallurgy);2011-12
5 LI Xue-peng (Institute of Research and Design of Yunnan Tin Company,Gejiu 660001,Yunnan,China);EXPERIMENTS ON PREPARATION OF 0~# NICKEL BY VACUUM DISTILLATION[J];Mining and Metallurgy;2013-01
6 WU Zhan,LI Wei,CHEN Zhi-hua,NING Rui(Rare & Precious Metals Plant,Daye Nonferrous Metals Co Ltd,Huangshi 435005,Hubei,China);Study on Recovering Copper from Crude Nickel Sulfate Solution with High Efficient Extractant AD100[J];Mining and Metallurgical Engineering;2013-02
7 Yin Xiafei;Liu Weiping;Jiang Lu;School of Chemistry and Environmental Engineering,Jiangsu University of Technology;;RECOVERY OF COPPER FROM COPPER-CONTAINED WASTEWATER BY USING A MICROBIAL FUEL CELL[J];Environmental Engineering;2014-09
8 ZHU Ai-lan(Shanghai Light Industry Research Institute Co.Ltd.,Shanghai 200031);Research Status on Purification Methods of Nickel Solution[J];Hydrometallurgy of China;2012-02
9 ZHENG Hua-jun,ZHENG Yun-peng(College of Chemical Engineering and Material Science,Zhejiang University of Technology,Hangzhou,310014,China);Investigation Progress on Copper Extraction Process[J];Zhejiang Chemical Industry;2009-05
10 Li Xuepeng,Yang Bin,Liu Dachun,Wang Lin(National Engineering Laboratory of Vacuum Metallurgy,Key Laboratory of Non-Ferrous metals Vacuum Metallurgy of Yunnan Province;Faculty of Materials and Metallurgy Engineering,Kunming University of Science and Technology,Kunming 650093,China);Purification of Nickel Sulphate Electrolyte[J];Chinese Journal of Rare Metals;2010-02
【Citations】
Chinese Journal Full-text Database 5 Hits
1 MA Qianling(Beijing General Research Institute of Mining and Metallurgy,Beijing 100044,China);APPLICATION PROSPECT OF COPPER EXTRACTANT BK-992 AS VIEWED FROM ENVIRONMENTAL PROTECTION[J];Mining and Metallurgy;2003-03
2 PENG Qin hua,CHEN Shu yi,LI Shao min,YANG Guang (Beijing General Institute of Mining and Metallurgy, Beijing 100044, China );Properties Study on Copper Extractant BK992 and LIX984[J];Nonferrous Metals;2002-05
3 PENG Qinhua,LI Shaomin,CHEN Shuyi,SONG Qingfu (Beijing General Research Institute of Mining and Metallurgy, Beijing 100044,China);APPLICATION OF COPPER EXTRACTANT BK992 IN HYDROMETALLURGY[J];Nonferrous Metals;2001-04
4 HE Huan hua;Present situation and Development Trend of World Nickel Industry[J];Non-ferrous Smelting;2001-06
5 Xu Qingren Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China;STRUCTURE OF ACIDIC ORGANOPHOSPHORUS EXTRACTANTS AND THEIR EXTRACTION BEHAVIOURS FOR CO(Ⅱ) AND Ni(Ⅱ)[J];THE CHINESE JOURNAL OF NONFERROUS METALS;1999-01
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 LUO Xian-ping,CHEN Jiang-an,XIONG Shu-hua(1.Jiangxi University of Science and Technology,Ganzhou 341000,Jiangxi,China);Research Process of Chemical Extraction Technology[J];Sichuan Nonferrous Metals;2006-03
2 LIU Yan, ZHAI Yuchun,WANG Hong(School of Materials and Metallurgy,Northeastern University,Shenyang 110004);Research on Production Process of Nickel[J];Materials Review;2006-03
3 LU Wen-dong, HAO Zhi-feng, WANG Ji-min(Guangdong University of Technology, Guangzhou 510090, China; Guangzhou Research Institute of Non ferrous Metals , Guangzhou 510651, China);Extractants in the copper hydrometallurgy[J];Journal of Guangdong Non-ferrous Metals;2004-02
4 LI Ling WEN Jiankang RUAN Renman (National Engineering Lab.of Biohydrometallurgy in General Research Institute for Nonferrous Metals,Beijing 100088,China);Research and Development in Recovery of Nickel from Solution by Ion-exchange[J];Precious Metals;2007-S1
5 HOU Xin-gang1,2,PAN Jiao1,WANG Yu-mian2,ZHANG Yan2(1.College of Material Science and Engineering,Lanzhou Univ.of Tech.,Lanzhou 730050,China;2.Key Laboratory of Gansu Advanced Nonferrous Metal Materials,Lanzhou Univ.of Tech.,Lanzhou 730050,China);Nickel recovery from low-concentration solution of nickel sulphate with ion exchange method[J];Journal of Lanzhou University of Technology;2010-05
6 MA Zhi-yuan,YANG Hong-ying,CHEN Guo-bao,LI Hai-jun School of Materials & Metallurgy,Northeastern University,Shenyang 110819,China.;Optimization of Extraction of Copper from Bio-leaching Solution Based on the Taguchi Methods[J];Journal of Northeastern University(Natural Science);2013-07
7 ZHAO Rui,YANG Wen-jun,ZHANG Min(School of Microelectronics and Solid-State Electronics,University of Electronic Science and Technology of China,Sichuan Chengdu 610054,China);A New Analytical Chemistry Design-New Process to Recover Copper from Scrap Printed Circuit Board[J];Guangzhou Chemical Industry;2013-09
8 DONG Fa-qin;XU Long-hua;Dai Qun-wei;Chen Shu;Liu Ming-xue;Key Laboratory of Solid Waste Treatment and Resource,Recycle Ministry of Education,Southwest University of Science and Technology;;New Progress in Investigation on Bioleaching of Low-grade Nickel-Cobalt Oxidized Ore[J];Earth and Environment;2013-04
9 HU Ren-hai;Shanghai Electric Seawater Desalination Engineering & Technologies;;Analysis on the Trend of Material Price for Seawater Desalination Device[J];Power Station Auxiliary Equipment;2013-03
10 ZHANG Xiaojuan1,LI Xingang1,2,CAO Hongbin3(1 School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China;2 National Engineering Research Center of Distillation Technology,Tianjin University,Tianjin 300072,China;3 Key Laboratory of Green Process and Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100090,China);Separation of Fe and Ni by solvent extraction with LK-C2 from nitric acid leaching solution of wasted printed circuit boards[J];Chemical Industry and Engineering Progress;2009-04
China Proceedings of conference Full-text Database 3 Hits
1 Xu Min~(1,2),Xu Qian~(1*),Liu Riqiang~1,Wang Zirui~1,Zhai Yuchun~1,You Jinglin~3(1.School of materials Science and Metallurgy, Northeastern University,Shenyang 110004,China;2.Heilongjiang Police Officer Vocational College,Harbin 150025,China;3.School of Materials Science and Engineering,Shanghai University,Shanghai 200072,China);Synthesis and Characterization of MgSiO_3 with the Method of Precipitation[A];[C];2010
2 MA Zhi-yuan,YANG Hong-ying*,TONG Lin-lin (School of Materials & Metallurgy,Northeastern University,Shenyang 110819,China. );Study on Extraction of Copper from Bio-leaching Solution Bearing High Iron[A];[C];2013
3 YANG Xue-shan;GUO Yuan-sheng;CHEN Bai-you;CUI Yin-liang;GUO Xin;Yunnan Nonferrous Metals Geology Bureau;Yunnan Land and Resources Vocational College;;The Distribution and the Exploration,Development and Utilization Situation of the Lateritic Nickel Ore Resources in the World[A];[C];2013
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Chen Yuan qiang,Lin Juan (Chengdu Electrometallurgical Factory, Chengdu,Sichuan 610081,China);Application of Ferrum-removal by Combining Carphosiderite and Natrojarosite in Cobalt System[J];Sichuan Nonferrous Metals;2002-01
2 Dan Yong,Feng Chi (Chengdu Electrometallurgy Factory,Chengdu 610061,China);A New Technology of Decoppering with Resin Exchange in Cobalt Chloride Solution[J];Sichuan Nonferrous Metals;2002-02
3 Liao Mengxia Deng Tianlong (College of Materials and Engineering,Chengdu University of Technology,610059,dtl@cdut.edu.cn);Progress and Prospect on Biohydrometallurgical Techniques to Recovery Valuable Metals from the Refractory Sulfides[J];Sichuan Nonferrous Metals;2003-03
4 ZHOU Xiao-wen1,ZHANG Jian-chun1,2,LUO Xian-ping1,3(1.Jiangxi University of Science and Technology,Ganzhou 341000,Jiangxi,China 2.Sichuan Research Institute of Non-ferrous Metals Metallurgy,Chengdu 610081,Sichuan,China 3.Engineering research center of high-efficiency development and application technology of tungsten resources,Ministry of Education,Ganzhou 341000,Jiangxi,China);The Current Situation and Prospects of the Process and Technology of Nickel Extraction from Laterite-nickel ore[J];Sichuan Nonferrous Metals;2008-01
5 JIANG Jing(Dep.of Mechanical & Electrical,Tongling Profession Technique College,Tongling 244000,China);Extraction Production of Nickel Sulfate[J];Anhui Chemical Industry;2008-06
6 Fu Ning1,Wang Bo2(1.Harbin Academy of Environmental Science,Harbin 150076,China; 2.Municipal and Environmental Engineering Department,Harbin Institute of Technology,Harbin 150090,China);Application of Microbial Fuel Cell in Wastewater Treatment[J];Environmental Science and Management;2012-04
7 CHEN Yi-hua, MU Yi-zhou, WEN Hui-na (Yellow River Basin Water Environment Monitoring and Management Center, Zhengzhou 450004, China);Study on Adsorption Capability to Heavy Metal of PAA-silica Gel for Water Clarifier[J];Journal of Beijing University of Technology;2006-01
8 ZHAO Yan1),PENG Ben2),GUO Min1),ZHANG Mei1) 1) State Key Laboratory of Advanced Metallurgy,University of Science and Technology Beijing,Beijing 100083,China 2) China Metallurgical Corporation Ltd.,Beijing 100038,China;Extraction of nickel and cobalt from laterite using a microwave assisted hydrothermal leaching method[J];Journal of University of Science and Technology Beijing;2012-06
9 MA Jiu tong 1, LI Luan ning 1, ZHANG Feng jun 1, ZHANG Gai xiang 1,MA Zhong cheng 2,ZHANG Min 2 (1.College of Applied Sciences, Jilin University, Changchun 130026, China;2.Metallurgy Research Institute of Jilin Province, Changchun 130012, China);RESEARCH AND APPLICATION ON EXTRACTION OF COPPER AND NICKEL IN LEACHING SOLUTION OF REFINED BRASSIL[J];Journal of Changchun University of Science and Technology;2001-02
10 Zhang Fengjun, Ma Jiutong, Li Luanning, Wang Yujie (Changchun University of Science and Technology, Changchun 130026);STUDY ON LEACHING TECHNOLOGY OF Cu AND Ni FROM BRASSIL[J];JOURNAL OF CHANGCHUN UNIVERSITY OF SCIENCE AND TECHNOLOGY;1998-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 HOU Xin-gang1,2,SU Rui-juan1,WEI Ji-ye1(1.College of Materials Science and Engineering,Lanzhou Univ.of Tech.,Lanzhou 730050,China;2.State Key Laboratory of Gansu Advanced Nonferrous Meta1 Materials,Lanzhou Univ.of Tech.,Lanzhou 730050,China);Thermodynamic analysis of copper removal from Cu-Ni-Cl-H_2O system[J];Journal of Lanzhou University of Technology;2012-02
2 CHEN Shu;YANG Yuan-kun;LIAO Guang-dan;CHEN Meng-jun;CHEN Hai-yan;Southwest University of Science and Technology,Solid Waste Treatment and Resource Recycle,Ministry of Education;;The Recovery of Metals from Printed Circuit Board Scrap by Bio-hydrometallurgical Processing-A Review[J];Earth and Environment;2013-04
3 ZHANG Yan-qing;Biology and Chemical Engineering,Hohhot Vocational College;;A Study on Adsorption Treatment of Measuring Pt(Ⅱ) in Wastewater[J];Guangzhou Chemical Industry;2014-04
4 ZHAO Si-jia(Hunan Research Institute of Nonferrous Metals,Changsha 410015,China);Research Progress of Copper Removal from Nickel Electrolyte[J];Hunan Nonferrous Metals;2012-02
5 Lü Jiping,Liu Zaiman,Miao Lijie,Qi Zhonglong(School of Chemical and Biological Engineering,Lanzhou Jiaotong University,Lanzhou 730070,China);Synthesis of dendrimer-like polyamidoamine on silica gel surface and their adsorption properties for Ni~(2+) from aqueous solution[J];Petrochemical Technology & Application;2008-01
6 ZHU Lei,DUAN Xue-chen,LIU Yang-lin,DING Xun,ZHANG Zhi-jian (1.School of Materials Science and Engineering,Central South University,Changsha 410083,China;2.Key Laboratory of Nonferrous Metal Materials Science and Engineering,Ministry of Education of China,Changsha 410083,China.);Ammonium Leaching and Cementation Method for Recycling Waste Copper[J];Journal of Kunming University of Science and Technology(Science and Technology);2010-04
7 LI Xue-peng(Institute of Research & Designing of YTC,Gejiu 661000,Yunnan,China);Nickel Sulphate Electrolyte Extraction Purified by M5640+P204+P507[J];Nonferrous Metals(Extractive Metallurgy);2011-12
8 LU Xing-wu,SHAO Chuan-bing,YI Chao,LI Yu-liang(Institute of Metallurgy New Materials of Northwest Institute of Mining and Metallurgy,Baiyin 730900,Gansu,China);Comprehensive Utilization of Copper Slag By-product in Zinc Hydrometallurgy[J];Nonferrous Metals(Extractive Metallurgy);2012-06
9 LI Xue-peng (Institute of Research and Design of Yunnan Tin Company,Gejiu 660001,Yunnan,China);EXPERIMENTS ON PREPARATION OF 0~# NICKEL BY VACUUM DISTILLATION[J];Mining and Metallurgy;2013-01
10 WU Zhan,LI Wei,CHEN Zhi-hua,NING Rui(Rare & Precious Metals Plant,Daye Nonferrous Metals Co Ltd,Huangshi 435005,Hubei,China);Study on Recovering Copper from Crude Nickel Sulfate Solution with High Efficient Extractant AD100[J];Mining and Metallurgical Engineering;2013-02
China Proceedings of conference Full-text Database 2 Hits
1 Li Qinxiang,Hu Huiping,Chen Qiyuan~*(College of Chemistry and Chemical Engineering,Central South University, Changsha 410083,China);Determination of Solubility of p-diketone-NH_3-H_2O System and β-diketone-H_2SO_4-H_2O System[A];[C];2012
2 Xiang Yanhong,Yin Zhoulan~*,Ran Ying,Hu Huiping,Chen Qiyuan(School of Chemistry and Chemical Engineering, Central South University,Changsha 410083,China);Solvent Extraction of Copper from Ammonia Solutions by Sterically Hindered β-diketone[A];[C];2012
【Secondary Citations】
Chinese Journal Full-text Database 6 Hits
1 Luo Aiping Zhang Qixiu(Department of Nonferrous Metallurgy, Central South University of Technology, 410083);INFLUENCE OF DILUENTS ON KINETICS AND PHASE DISENGAGEMENT OF COPPER EXFRACTION[J];MINING AND METALLURGICAL ENGINEERING;1998-02
2 Wang Chengyan; Zhan Huifang; Chen Feng(Beijing General Research Institute of Mining and Metallurgy);SURVEY OF INVESTMENT AND ECONOMIC BENEFIT OF LEACHING-SOLVENT EXTRACTION-ELECTROWINNING PLANTS FOR LOW-GRADE COPPER ORE IN CHINA[J];MINING AND METALLURGY;1999-01
3 PENG Qin hua,CHEN Shu yi,LI Shao min,YANG Guang (Beijing General Institute of Mining and Metallurgy, Beijing 100044, China );Properties Study on Copper Extractant BK992 and LIX984[J];Nonferrous Metals;2002-05
4 YANG Songrong 1,QIU Guanzhou 2,XIE Jiyuan 1,HU Yuehua 2 (1 Beijing Central Engineering and Research Institute for Nonferrous Metallurgical Industries,Beijing 100036,China; 2 Central South University,Changsha 410083,China);DEVELOPMENT OF BIOOXIDATION AND BIOLEACHING TECHNOLOGY IN ABROAD[J];Nonferrous Metals;2001-03
5 Yuan Chengye, Xu Qingren, Hu Shuisheng and Jiang Yadong(Shanghai Institute of Organic Chemistry, Academia Sinica);SYNTHESIS AND STRUCTURE-REACTIVITY STUDIES OF MONO-BUTYL ESTERS OF OCTYLPHOSPHONATES IN COBALT(Ⅱ)AND NICKEL(Ⅱ)EXTRACTION[J];Chinese Journal of Applied Chemistry;1988-01
6 Xu Qingren;Jiang Yadong Shanghai Institute of Organic Chemistry, Academia Sinica;STUDY ON RELATIONSHIP BETWEEN THE STRUCTURE OF ACIDIC ORGANOPHOSPHORUS EXTRACTANTS AND THEIR EXTRACTION PROPERTIES ON Co(Ⅱ)AND Ni(Ⅱ)[J];Chinese Journal of Applied Chemistry;1989-04
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