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《Journal of Anhui Normal University(Natural Science)》 1989-04
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Synthesis of Clicyclopentadienyl Neodymium Dicarboxylates

Wang Xiuran Du Baohui (Institue of Organic Chemistry)  
By the reaction of Cp,Nd ( Cp=C_5H_5) with dicarboxylic acid, five new cyclopentadienyl neodymium dicarboxylates have been synthesized. Namely: (COO)_2NdC_5H_5·THF(1), CH_2 (COO)_2NdC_5H_5·THF(2), (CHCOO)_2NdC_5H_5·THF(3), (CH_2COO)_2 NdC_5H_5·THF(4), O-C_6H_4(COO)_, NdC_5H_5·THF(5). They are stable by exposure to air. It may be attributed to the effect of chelate ligand. They were identified by elemental analysis and IR.
【Fund】: 国家自然科学资金
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