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《Journal of Anhui Normal University(Natural Science)》 2006-01
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Thermodynamic Optimization and Calculation of the EuCl_3-CaCl_2 Binary System

SUN Yi-min~1,MA Zhi-sen~1,QIAO Zhi-yu~2,YE Xin-yu~1,WANG Yu~1,MA Xiao-yong~1 (1.College of Chemistry and Materials Science,Anhui Normal University, Wuhu 241000,China;2.Department of Physical Chemistry,University of Science and Technology Beijing,Beijing 100083,China)  
In this paper,the Gibbs energy of liquid phases in the EuCl_3-CaCl_2 system was described by the new modified quasi-chemical model in the pair approximation for local order.Based on measured phase equilibrium data and experimental enthalpies of mixing of the binary system,a set of thermodynamic functions have been optimized by using the CALPHAD technique.The calculations show good agreement with experimental phase diagrams and thermodynamic values.
【Fund】: 安徽省教育厅重点项目(2005KJ016ZD)
【CateGory Index】: O642.4
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