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《Acta Armamentarii》 2007-01
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A Study of Structure Characterization and Thermal Decomposition of the Impurities of HNIW

LIU Jin-quan,OU Yu-xiang,WANG Yan-fei,MENG Zheng,WU Xiang-guo(College of Materials Science and Engineering,Beijing Institute of Technology, Beijing 100081,China)  
HNIW was respectively synthesized with TADBIW by use of a sub-nitrolysis/nitrolysis one-pot method and with TADFIW by use of a mixed acid method.The main impurities of HNIW were separated using a column chromatography and confirmed as PNMAIW and PNMFIW via FTIR,(()~1H NMR,) MS and element analysis.The DSC and kinetics calculations show that the initial and peak decomposition temperatures of PNMFIW are higher than those of PNMAIW and the apparent decomposition active energy of the former is twice as much as that of the latter.The reason maybe is that the formyl on the hexabasic ring is more stable than the acetyl on the pentabasic ring to the cage structure for PNIW with one substituting group.
【CateGory Index】: TQ560
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【Citations】
Chinese Journal Full-text Database 1 Hits
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【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Xu Yongjiang Ou Yuxiang Chen Boren Liu Lihua(School of Chemical Engineering and Materials Science, Beijing Institute of Technology, Beijing, 100081);STRUCTURAL IDENTIFICATION OF PENTANITROMONOFORMYLHEXAAZAISOWURTZITANE[J];ACTA ARMAMENTARII;1999-04
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3 YANG Guang Hui 1, ZHANG Hong Xing 1 , WANG Yue 2, TANG Au Qing 1,2 [WT5”BX](1. State Key Laboratory of Theoretical and Computational Chemistry; 2. Key Laboratory for Supramolecular Structure and Spectra, Institute of Theoretical Che;An ab initio Study of the Luminescence and the Pt(Ⅱ)…Pt(Ⅱ) Interaction in the Compound Pt_2(CN)_4(CNC_4H-9)_4[J];Chemical Research In Chinese Universities;2000-12
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5 ZHOU Ge, WANG Jing, HE Wen Di, TIAN Shuang He, TIAN An Min (The Faculty of Chemistry, Sichuan University, Chengdu 610064, China)WEN Zhong, ZHAO Peng Ji, XU Zhi Lei(China Academy of Engineering Physics, Mianyang 621900, China);A Study of the Electronic Structure of Energetic Material Hexanitrohexaazaisowurtzitane by B3LYP Method[J];Chemical Research In Chinese Universities;2002-07
6 OU Yuxiang,MENG Zheng,LIU Jinquan(School of Material Science and Engineering,Beijing Institute of Technology,Beijing 100081,China);Advance in high energy density compound CL-20——developments of synthesis route and production technologies of CL-20[J];Chemical Industry and Engineering Progress;2007-06
7 JIN Shao-hua,ZHAI Mi-cheng,LIU Jin-quan,ZHENG Chuan-ming,CHEN Shu-sen,SONG Quan-cai(School of Materials Science and Engineering,Beijing Institute of Technology,Beijing 100081,China);Synthesis and Properties of HNIW[J];Chinese Journal of Energetic Materials;2006-03
8 Ou Yuxiang, Liu Jinquan, Wang Yanfei, Meng Zheng(School of Materials Science and Engineering, Beijing Institute of Technology,Beijing 100081);Synthesis and Industrial Production of Five Hydrogenolysis-debenzylation Compounds from Hexabenzylhexaazaisowurtzitane[J];Chemistry;2005-10
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