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《Journal of Beijing University of Chemical Technology(Natural Science Edition)》 2013-01
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Synthesis and characterization of a neodymiun-copper(Ⅱ) coordination polymer with 2,5-pyridinedicarboxylic acid

LIU Jing ZHANG LiDan HAN ChunYing ZHANG LingJuan(School of Science,Beijing University of Chemical Technology,Beijing 100029,China)  
A novel three-dimensional coordination polymer of neodymium and copper(II) with 2,5-pyridinedicarboxylic acid,[Nd2Cu3(C7NO4)6(H2O)10·14H2O]n,has been synthesized by a hydrothermal reaction and characterized by single crystal X-ray diffraction.Crystals were dark bluish violet particles.The reaction conditions were optimized with reaction temperature 160 ℃,reaction time 3 days,pH=6,6 mL deionized water as solvent,and molar ratio of NdCl3·6H2O,copper bromide,2,5-pydc 1∶1∶3.Studies of the optical properties of the powdered sample suggested that the compound is a semiconductor with a band gap of 1.14 eV.The results of thermogravimetric analysis indicated that the compound is thermally stable up to 317 ℃.
【CateGory Index】: O641.4
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