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《Glass & Enamel》 1993-05
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Influence of Zirconium Ion-implantation on Weathering of Phosphate Glass

Tao Ying Wang Shaozhi Wang Chengyu (Dalian Institute of Light Industry)  
The amount of 1×10~(16)、5×10~(16) and 1×10~(17)ions/cm~2 (60keV) of ziroonium ions were implanted in samples of P_2O_5-Al_2O_3-B_2O_3-MgO-K_2O glasses respectively at room temperature. Accelerated weathering tests on implanted and unimplanted glasses were made under static conditions of relative humidity 75% at 60℃ for 10 days. The implanted and unimplanted samples after weathering were measured by IRRS、XPS、SEM and AAS. The experimental results show that a protective film of zirconia after weathering was formed at the glass surface of the sample implanted with Zr~+ therefore the weathering rate should be reduced.
【Fund】: 大连理工大学国家重点三束实验室的资助
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