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Study on the Colouration of Li_2O-Al_2O_3-SiO_2 Transparent Glass Ceramics

ZHANG Zhi?yong 1, ZHANG Long 2 (1. Huangshan Zheng-Tong Accountant Office, Anhui Huangshan 245000, China; 2.Shanghai Institute of Optics and Fine Mechanics, Shanghai 201800,China)  
The transition metal oxides, such as Cr 2O 3,CoO, NiO and MnO 2, were introduced to the transparent Li 2O-Al 2O 3-SiO 2 glass ceramics. The results show that the color of the glass ceramics differs significantly from that of their parent glasses,and the main wave-length of glass ceramics is longer than that of their parent glasses. The investigation on the heat treatment processes shows that the most obvious change of color occurs in the process from the nucleation to the crystallization. These phenomena may be explained by ligand field theory as well as light-scattering effect.
【CateGory Index】: TQ171.73
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