Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Beijing Normal University(Natural Science)》 2005-04
Add to Favorite Get Latest Update

CRYSTAL STRUCTURE OF RED LUMINESCENT COMLEX OF Eu(NO_3)_3(Phen)_2

Wang Mingzhao~1 Cai Guanliang~2 Peng An~(3) Tan Xin~(4)( 1)Key Laboratory of Radiopharmaceuticals, Ministry of Education; Department of Chemistry: Beijing Normal University, 100875, Beijing, China; 2)Chemical Defense Institute, PLA, 102205, Beijing, China;3)College of Life Sciences, Beijing Normal University, 100875, Beijing, China; 4)School of Life Sciences and Technology, Institute of Beijing Technology, 100081, Beijing, China)  
The red luminescent complex Eu(NO_3)_3(Phen)_2 (Phen: 1,10-phenanthroline) was synthesized, its crystal structure was measured. The complex crystallizes in monoclinic, space group C_c(#7). The cell dimensions are a=1.116()12 nm, b=1.796()3(4) nm, c=1.304()23 nm, α=90.00(0)°, β=100.573°, (γ=90.00(0)°), V=2.570()4(9) nm~(3), Z=4 and D_c=1.805()g·cm~(-3). The final R is 0.029()3. Each Eu~(3+) ion is ten coordinated by six oxygen atoms of three NO~-_3 anions and four nitrogen atoms of two Phen molecules, resulting in seriously distorted bicapped square antiprism, or bicapped square top-butter-fly-shape bottom twisted prism.
【Fund】: 北京市自然科学基金资助项目(5032004)
【CateGory Index】: O641.4
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【Citations】
Chinese Journal Full-text Database 3 Hits
1 Wang Mingzhao, Li Xiang,Ning Yalan,Cai Guanliang ( 1)Department of Chemistry, Beijing Normal University, 100875, Beijing, China; 2) Chemical Defense Institute, PLA, 102205, Beijing, China);STUDY ON A NOVEL LUMINESCENT COMPOSITE OF Eu~(3+)-AAO-TTA[J];Journal of Beijing Normal University(Natural Science);2002-01
2 WANG Ming-Zhao , JIN Lin-Pei(Department of Chemistry, Beijing Normal University, Beijing, 100875)LIU Shi-Xiong, CAI Guan-Liang, HUANG Jin-Ling(Department of Chemistry, Fuzhou University)QIN Wei-Ping, HUANG Shi-Hua (Changchun Physics Institute, Chinese Academy of Sciences);Crystal Structure and Fluorescent Spectra of Eu(DBM)_3(2,2'-bipy) Complex[J];Chemical Research In Chinese Universities;1993-03
3 JIN Lin-Pei , WANG Rui-Fen, WANG Ming-Zhao(Department of Chemistry, Beijing,Normal University, Beijing, 100875)CAI Guan-Liang, LIU Shi-Xiong, HUANG Jin-Ling(Department of Chemistry, Fuzhou University);Crystal Structure and Luminescence Spectra of Binuclear Europium m-Methylbenzoate Ternary Complex with 1,10-phenanthroline, [Eu(m-MBA)_3PHEN](H_2O)_2[J];Chemical Research In Chinese Universities;1993-09
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Wang Liya; Jin Linpei(Department of Chemixtry, Beijing Normal University, 100875, Beijing, China);SYNTHESIS AND CRYSTAL STRUCTURE STRUCTURE OF EUROPIUM 3, 4-DIMETHYLBENZOATE COMPLEX WITH 1, 10-PHENANTHROLINE[J];JOURNAL OF BEIJING NORMAL UNIVERSITY(NATURAL SCIENCE);1998-03
2 Jin Linpei;Zheng Xiaomei(Department of Chemistry,Beijing Normial University,100875, Beijing, PRC);CRYSTAL STRURE OF AQUA(2,2'-BIPYRIDYL) NEODYMIUM TRIS(4-AMINOBENZOATE)[J];JOURNAL OF BEIJING NORMAL UNIVERSITY;1994-01
3 Wang Ruifen;Wang Mingzhao;Jin Linpei;Cai Guanliang(Department of Chemistry, Beijing Normal University, 100875, Beijing, PRC)(Institute of Chemical Defence,102205, Beijing, PRC);CRYSTAL STRUCTURE OF BINUCLEAR Eu(Ⅲ) COMPLEX WITH o-METHYLBENZOIC ACID AND 1,10 -PHENANTHROLINE,Eu_2 (o-MBA)_6(PHEN)_2[J];JOURNAL OF BEIJING NORMAL UNIVERSITY;1994-02
4 Tong Jinqiang; Jin Linpei; Wang Ruifen(Department of Chemistry.Beijing Normal University, 100875, Beijing, PRC, Department of Chemistry, Hebei Normal College. 050091, Shijiazhuang, PRC);RAMAN SPECTRA OF EUROPIUM METHYLBENZOATE COMPLEXES WITH 1,10-PHENANTHROLINE AND 2,2 -BIPYRIDYL[J];JOURNAL OF BEIJING NORMAL UNIVERSITY;1994-03
5 Wang Mingzhao;Jin Linpei(Department of Chemistry, Beijing Normal Universiy,Beijing 100875)Lu Shaozhe;Zhang Jiahua(Changchun Institute of Physics,Chinese Academy of Sciences,Changchun 130021);SYNTHESIS,SPECTRA AND Eu(Ⅲ)SITES OF Eu_2(DBM)_6 4, 4'-BIPY[J];CHINESE JOURNAL OF LUMINESCENCE;1995-02
6 JIN Lin-Pei , WANG Rui-Fen, WANG Ming-Zhao(Department of Chemistry, Beijing,Normal University, Beijing, 100875)CAI Guan-Liang, LIU Shi-Xiong, HUANG Jin-Ling(Department of Chemistry, Fuzhou University);Crystal Structure and Luminescence Spectra of Binuclear Europium m-Methylbenzoate Ternary Complex with 1,10-phenanthroline, [Eu(m-MBA)_3PHEN](H_2O)_2[J];Chemical Research In Chinese Universities;1993-09
7 Li Wenlian (Changchun Institute of physics, Academia Sinica, Changchun 130021, China);Luminescence and Their Applications on Lanthanide-Organic Complexes[J];Optoelectronics.Laser;1997-01
8 LI Wen xian, WU Guo jiun, LIU Zhong shi and HAN Feng mei College of Chemistry and Chemical Engineering Inner Mongolia University, Hohhot 010021, China;Fluorescence Enhancement Character of Terbium Perchlorate and Thulium Perchlorate with Phenylcarboxymethyl Sulfoxide Coordination Compounds[J];Spectroscopy and Spectral Analysis;2002-06
9 ZHAO Na1,MA Rui-xia1,XU Li-juan1,WANG Shu-ping1,WANG Rui-fen1,ZHANG Jian-jun2 (1.College of Chemistry and Material Science,Hebei Normal University,Hebei Shijiazhuang 050016,China;2.Experimental Center,Hebei Normal University,Hebei Shijiazhuang 050016,China);Crystal Structure and Properties of Ternary Europium Complex Eu(NO_3)_3(phen)_2[J];Journal of Hebei Normal University(Natural Science Edition);2008-02
10 XU Cun-jin (Department of Chemistry, Hangzhou Teachers College, Hangzhou 310012, China);Synthesis and luminescence properties of Eu(Ⅲ) complex with 1,10-phenanthroline and salicylic acid[J];Journal of Hangzhou Teachers College;2004-04
【Co-references】
Chinese Journal Full-text Database 1 Hits
1 ZHAO Na1,MA Rui-xia1,XU Li-juan1,WANG Shu-ping1,WANG Rui-fen1,ZHANG Jian-jun2 (1.College of Chemistry and Material Science,Hebei Normal University,Hebei Shijiazhuang 050016,China;2.Experimental Center,Hebei Normal University,Hebei Shijiazhuang 050016,China);Crystal Structure and Properties of Ternary Europium Complex Eu(NO_3)_3(phen)_2[J];Journal of Hebei Normal University(Natural Science Edition);2008-02
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 WANG Ming-Zhao , JIN Lin-Pei(Department of Chemistry, Beijing Normal University, Beijing, 100875)LIU Shi-Xiong, CAI Guan-Liang, HUANG Jin-Ling(Department of Chemistry, Fuzhou University)QIN Wei-Ping, HUANG Shi-Hua (Changchun Physics Institute, Chinese Academy of Sciences);Crystal Structure and Fluorescent Spectra of Eu(DBM)_3(2,2'-bipy) Complex[J];Chemical Research In Chinese Universities;1993-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved