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《Journal of Jiangxi Normal University (Natural Sciences Edition)》 2005-01
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The Catalytic Synthesis of Borneolacetate by Using Nanometer Rare Earth Composite Solid Superacid

CHEN Hui-zong,YANG Yi-wen,LIU Yong-gen,WANG Rui-fen,GE Jun-ying,LIU Fang (Institute of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330027,China)  
In this paper, we studied the preparation of rare earth composite solid superacid SO_4~(2-)/ZrO_2-La_2O_3 and its catalytic activity in the synthesis of borneolacetate. The preparatory conditions of catalyst (SO_4~(2-)/ZrO_2-La_2O_3) were discussed, when the mass percent of La_2O_3 in carrier ZrO_2-La_2O_3 was 2%, the mol concentration of (NH_4)_2SO_4 dipping solution was 1 mol/L, baking temperature was 600 ℃ and the catalyst had high catalytic activity in the synthesis of borneolacetate. The factors influencing the reaction were also investigated.The results showed that the optimum reaction conditions were as follows: the mol ration of natural borneol to acetic acid was 1∶6, the use level of SO_4~(2-)/ZrO_2-La_2O_3 was 6% of the mass of nataral borneol, the reaction temperature was 120 ℃ and the reaction time was 8 h,the esterification yield of bornedacetate could reach 93.14% and its reaction preference could reach 99.8%. In the process of experiment, we discovered that the catalyst had good reusability, it could be activated and revivified.
【Fund】: 国家自然科学基金资助项目(20262002);; 江西省自然科学基金资助项目(0420016).
【CateGory Index】: TQ655
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