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《Journal of Jiangxi Normal University (Natural Sciences Edition)》 2005-01
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Study on the Alcoholysis of Dichlorodimethylsilane

XU Wen-yuan (School of Basic Science, East China Jiaotong University, Nanchang 330013,China)  
The alcoholysis of dichlorodimethylsilane has been studied theoretically and experimentally. Both the first and the second steps are very easy to proceed, and the first step is the Rate-Determining-Step of the alcoholyses. Dimethyldiethoxylsilane is the main product. The proportion of ethanol and dichlorodimethylsilane (2 theoretically and 1.8 experimentally) is gained. And the mode of dropping (ethanol dropping into the solvent of dichloromethylsilane) is gained as well. The results of the calculation is consistent with those of the experiments.
【CateGory Index】: O627.4
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2 CHEN Xian-jun(Chongli Steel Co.,Ltd.,Tiantie Group,Shexian 056400,China);Synthesis of Chloromethyl-ethoxy-dimethylsilane[J];Fine Chemical Intermediates;2013-03
3 WANG Liu-cheng;JIN Lin-feng;ZHAO Jian-hong;WANG Jian-she;CHENG Xiang-lin;SONG Cheng-ying;School of Chemical Engineering and Energy Resources,Zhengzhou University;;Synthesis of Dodecylmethyldimethoxysilane Silane Coupling Agent[J];Fine Chemicals;2013-11
4 Cheng Yuanmei;Weng Bofeng;Liu Yanan;Deng Li;Li Yongmei;Shaanxi Tian Hong Silicon Industrial Corporation;;Analyses of Polychlorosilanes and Methylchlorosilanes Containing in Synthesized Trichlorosilane[J];Chemistry;2014-03
5 DAI Xue-feng,CHEN Guan-xi,FENG Jian-yue(Detecting & Analyzing Department of Zhejiang University,Hangzhou 310027,China);Component Analysis of the Primary Products of Methylchlorosilane[J];Journal of Instrumental Analysis;2007-05
6 ZHANG Ai-xia,ZHOU Qin,ZENG Xiang-hong,CHEN Li (Chenguang Research Institute of Chemical Industry, China Bluestar, Chengdu 610041, Sichuan).;Progress of silicone industry in China in 2005[J];Silicone Material;2006-03
7 LI Jian-yong,DENG Feng-jie (Department of Chemistry,Nanchang University,Nanchang 330031,Jiangxi);Progresses of alcoholysis of the chlorosilane[J];Silicone Material;2011-02
8 LU Hong,CHEN Xun-jun,HU Wen-bin,WU Guo-jie(College of Chemistry and Chemical Engineering,Zhongkai University of Agriculture and Technology, Guangzhou 510225,China);Qualitative analysis by UPLC-TOFMS and quantitative analysis by UPLC/TUV of silicone monomer BMSB[J];Modern Chemical Industry;2012-06
Chinese Journal Full-text Database 2 Hits
1 XU Wen-yuan 1,LI Feng-yi 2,WANG Le-fu 1\;(1.Institute of Chemical Engineering,South China University of Technology,Guangzhou,510640 PRC;2.Institute of Applied Chemistry,Nanchang University,Nanchang,330047 PRC);Preparation of Dichlorodimethylsilane[J];Jiangxi Science;2002-03
2 Li Feng Yi Xu Wen Yuan1 Yu Jun Wen(Institute of Applied Chemistry, Nanchang University, Nanchang 330047; 1Institute of Chemical Engineering, South China University of Technology, Guangzhou 510640);Quantum Chemistry Calculation on the Alcoholysis of Dichloromethylsilane[J];Acta Physico-chimica Sinica;2003-04
Chinese Journal Full-text Database 10 Hits
1 XU Wen-yuan~1,HONG San-guo~2,LIU Xian-liang~3 (1.School of Basic Science, East China Jiaotong University,Nanchang 330013,China;2.Institute of Chemistry,Jiangxi Normal University, Nanchang 330027,China;3.Peridical Office of Journal, Jiangxi Normal University, Nanchang 330027,China);Theorotic Study on the Preparation of Dichlorodimethylsilane by Redistribution[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2004-01
2 XU Wen-yuan(School of Chemistry and Chemical Engineering,East China Jiaotong University,Nanchang 330013,China);Study on the Alcoholysis of Trichlorosilane[J];Journal of Jiangxi Normal University(Natural Sciences Edition);2007-03
3 CHANG Qiulian1,2(1.Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering,Tsinghua University,Beijing 100084,China; 2.China Coal Research Institute,Beijing 100013,China);Effect of moisture contents of methyl chloride on reaction rate for direct synthesis of dimethyldichlorosilane[J];Industrial Catalysis;2013-02
4 XU Wen-yuan (School of Basic Science, East China Jiaotong University, Nanchang 330013, China);Experimental Study on the Redistribution of Chlorotrimethyl and Trichloromethyl Silane Catalyzed by AlCl_3[J];Journal of East China Jiaotong University;2004-04
5 HAO Wei,XU Wen-yuan,ZHONG Yun,FANG Zhi-li,ZHOU Mei-hua,HU Lin(School of Basic Science,East China Jiaotong University,Nanchang 330013,China);A Study on the Alcoholysis of Vinyl Trichlorosilane[J];Journal of East China Jiaotong University;2008-04
6 LI Jianlong,ZHONG Wei (School of Chemical Engineering and Technology,Qingdao University of Science & Technology,Qingdao 266042,Shandong,China);Research progress of separation and purification of dimethyldichlorosilane[J];Chemical Industry and Engineering Progress;2011-S2
7 HAO Hui-juan,ZHOU Xin,WU Xue (Department of Chemistry,College of Science,Yanbian University,Yanji 133002,China);Synthesis of a novel quinoline derivatives and its application in recognition of mercury[J];Chemical Reagents;2011-06
8 XU, Wen-Yuan,a HE, Zhong-Yia CHEN, Yub LI, Feng-Yic HONG, San-Guoc (a Department of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013) (b Xinghuo Chemical Works, Bluestar Co., Yongxiu 330319) (c Institute of Applied Chemistry, Nanchang University, Nanchang 330047);DFT and MP2 Study on the Redistributing Preparation of Dichlorodimethylsilane Catalyzed by AlCl_3 (II)[J];Acta Chimica Sinica;2005-16
9 XU Wen-yuan1,ZHONG Yun1,LIU Xian-liang2,HE Zhong-yi1,ZHENG Long-zhen1(1.Department of Chemistry and Chemical Engineering,East China Jiaotong University,Nanchang 330013,China;2.Editorial Board of Journal,Jiangxi Normal University,Nanchang 330027,China);Study on the alcoholysis of dichloromethylvinylsilane[J];Journal of Zhejiang University(Science Edition);2007-04
10 Cao Guirong;Zhao Xueyan;Xiao Ruijie;Institute of Disaster Prevention;;The application of thermodynamic calculations in synthesis of dimethylphenyl isocyanates[J];Computers and Applied Chemistry;2014-12
Chinese Journal Full-text Database 10 Hits
1 Duan Jingkuan 1,2 , Wang Xiuli 2, Zhang Guangming 2, Li Jing 2 (1. Research Center of Material Science and Engineering, Guilin Electronic and Engineering University, Guilin 541004, China; 2. Resin Research Institute of Qilu Petrochemical Co., Zibo 255400, China);STUDY ON THE PROCESSING TECHNOLOGY OF SPECIAL MATERIAL FOR SILANE CROSSLINKING HDPE ALUMINUM COMPOSITE PIPE[J];Engineering Plastics Application;2005-01
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3 ZHANG Jian-an,YANG Jian-jun,WU Qing-yun,WU Ming-yuan(School of Chemistry and Chemical Engineering,Anhui University,Hefei 230039,China);Study on waterborne polyurethane emulsion modified with silicone[J];Journal of Anhui University(Natural Sciences);2005-06
4 XU Xiao-gang, ZHENG Chuan, GAO Wen-xiu (Xiamen University a.Department of Mechanical & Electronic Engineering;b.Department of Physics; c.Nano Engineering & Technology Center, Xiamen 361005, China);A Novel Fabricating Process of the Tunable Grating[J];Micronanoelectronic Technology;2005-03
5 TIAN Jie ,HU Shi-sheng(CAS Key Laboratory of Mechanical Behavior and Design of Materials,University of Science and Technology of China,Hefei230026,Anhui,China);Investigation on mechanical properties of the composites of aluminum foam containing silicone rubber[J];Explosion and Shock Waves;2005-05
6 SHU Hong-qun~(1,2),CAI Ming-zhong~1(1.Institute of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330027, China;2.Yingtan Vocational Technology College, Yingtan Jiangxi 335000, China);Synthesis of Poly-ω-(Methylseleno)Undecylsiloxane Platinum Complex and Its Catalytic Hydrosilylation Behavior[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2005-03
7 YE Shang-hui, SONG Cai-sheng, FU Chang-qing, LIU Yong-jun, LIU Xiao-ling(Insitute of Chemitry and Chemical Engineering Sciences,Jiangxi Normal University, Nanchang 330027,China);Synthesis and Identification of the Dimethybis(phenylmethyl)silane[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2005-04
8 BAN Wen-bin~(1,2),LIU Wei-qu~1,SHEN De-yan~(1,2),HOU Meng-hua~(1,2)(1.Guangzhou Institute of Chemistry,Chinese Academy of Science,Guangzhou510650,China;2.Graduate School of the Chinese Academy of Sciences,Beijing100039,China);Preparation of water soluble fast adhesive organosilicone fabric softener[J];China Surfactant Detergent & Cosmetics;2005-04
9 LIAO Hong-liu~1,ZHU Huai-jun~2,LI Feng-yi~2(1.The School of Chemical and Energy Engineering,South China University of Technology,Guangzhou 510640,China;2.Chemistry Department of Nanchang University,Nanchang 330047,China);Catalytic synthesis of silicone-polyether surfactant under no solvent condition[J];China Surfactant Detergent & Cosmetics;2005-06
10 ZHAO Jian-bo,SUN Yu-an,LIU Ying-fan,CHEN Chang-fu,XIE Bing,ZHENG Xian-jun (Henan Key Laboratory of Surface & Interface Science,Zhengzhou University of Light Industry,Zhengzhou,Henan 450002,China);Preparation of carbon nanotubes-supported chitosan-platinum complex and its catalytic hydrosilylation activity[J];China Surfactant Detergent & Cosmetics;2010-06
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 Yang Qiuju(Department of Chemical,Zibo Vocational College,Zibo 255314,China);Study on the Preparation and Properties of Organosilicon Modifying Acrylate Emulsion[J];Guangdong Chemical Industry;2011-02
2 XIONG Lian-ming,SHU Kuan-jin,MA Yao-long,YUAN Bin,ZHANG Yan ( School of Environment and Chemical Engineering,Nanchang Hangkong University,Nanchang 330063,China);Research advance of synthesizing vinylcyclotetrasiloxane and utilizating by-product[J];Fine and Specialty Chemicals;2013-08
3 Zhao Kun;Ji Pengyan;Liu Yin;Zhang Pengyun;Gansu Research Institute of Chemical Industry;Key Laboratory of fine Chemicals,Gansu Province;;Study on the synthesis of vinyltrifluoropropylethoxysilane[J];New Chemical Materials;2014-02
4 WANG Shanshan;JIANG Kezhi;WU Chuan;Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,Hangzhou Normal University;;The Application of GC-MS in the Analysis of Organosilicon Compounds[J];Journal of Hangzhou Normal University(Natural Science Edition);2014-06
5 Zhao Zhen1 Zhang Wen-long1 Chen Yu1,2 (1,College of Material Science & Engineering, Harbin University of Science and Technology, Harbin, 150040; 2, Guangdong Huanan Fine Chemical Research Institute, Xinhui, 529100);Applications and Research Progresses of Coupling Agents[J];Plastics Additives;2007-03
6 ZHAO Wen-guang1,SONG Qi2,CHEN Chen2,CHEN Ping1,WANG Feng2(1.College of Chemistry and Material Science,Liaoning Shihua University,Fushun Liaoning 113001,P.R.China; 2.Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian Liaoning 116023,P.R.China);Preparation of Novel Nydrophobic Catalyst and Its Catalytic Activity in Ethylbenzene Oxidation[J];Journal of Petrochemical Universities;2012-03
7 ZHOU Ting-ting1,CHEN Guan-xi1,2,WU Qing-zhou1,2,FENG Jian-yue2(1.Department of Chemistry,Zhejiang University,Hangzhou 310027,China;2.Analysis & Measurement Center,Zhejiang University,Hangzhou 310027,China);Separation and Analysis of Low-boiling Residues of Methylchlorosilanes[J];Journal of Instrumental Analysis;2009-12
8 Sang Xiao;Chemical Engineering Department of Zibo Vocational Institute;;Synthesized from Hydrolysate 107 the Influence Factors of Silicon Rubber[J];Sichuan Chemical Industry;2014-05
9 ZHANG Ai-xia,ZHOU Qin,CHEN Li(Chengrand Research Institute of Chemistry Industry Co.,Ltd,China National Bluestar,Chengdu 610041);Progress of Silicone Industry in China in 2007[J];Silicone Material;2008-03
10 LU Hong,CHEN Xun-jun,HU Wen-bin,WU Guo-jie(College of Chemistry and Chemical Engineering,Zhongkai University of Agriculture and Technology, Guangzhou 510225,China);Qualitative analysis by UPLC-TOFMS and quantitative analysis by UPLC/TUV of silicone monomer BMSB[J];Modern Chemical Industry;2012-06
【Secondary Citations】
Chinese Journal Full-text Database 8 Hits
1 Fu Jilai (China National Chemical Information Centre,Beijing 100029);Current situation and development trend of silicone industry in the world[J];New Chemical Materials;2001-09
2 Cheng Ge , Wang Yuechuan (Department of Polymer Science and Materials, State Key Laboratory of Polymer Materials, Sichuan University, Chengdu 610065);Synthesis of halogen-trimethylsilylbenzenes[J];Chemical Reagents;2001-02
3 CHENG Ge,WANG Yue chuan (Department of Polymer Science and Materials,Sichuan University,Chengdu 610065,China);Synthesis of 5,5'-Dimethyl-3,3'-bis(trimethylsilyl)biphenyl[J];FINE CHEMICALS;2000-05
4 Meng Xiangfeng (China Hualu Engineering Co.,Xi an 710054)$$$$;Process Technique of Methylchlorosilane Monomer in China and Disparity with That at Abroad[J];SILICONE MATERIAL;2000-02
5 Fu Jilai (China National Chemical Information Center,Beijing 100029);Suggestion on Development of Chinas Silicone Industry[J];SILICONE MATERIAL;2000-04
6 Chen Fade,Huang Xupeng (Hubei Research & Design Institute of Chemical Industry,Wuhan 430073);Development of Cyclohexylmethyldimethoxysilane[J];Silicone Material;2001-03
7 Wang Cheng;Tu chengjie(The Second Factory of Chenguang Research Institute of Chemical Idustry 643201);The Synthetic Technology for the Production of 400t/a Phenyl chlorosilane by Rochow Process[J];;1995-06
8 Zhang Zengyou Xia Zebin Li Shuzheng Zang Suhua (Institute of Elementary Chemistry, Nankai University 300071);A New Method for the Preparation of the Analogue of High Effective Fungicide DPX H6573[J];;1996-03
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