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《Journal of Jiangxi Normal University(Natural Science Edition)》 2018-03
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The Synthesis and Magnetic Properties of Metal Complexes of Polymethyl Methacrylate Containing Terpyridine

LUO Jin;SUN Yi;CHEN Puqing;WANG Tao;SUN Weilin;Analytical & Testing Center,Jiangxi Normal University;Jiangxi Province Key Laboratory of Chemical Biology,College of Chemistry and Chemical Engineering,Jiangxi Normal University;Department of Polymer Science and Engineering,Zhejiang University;  
Poly[4'-( 4-methacryloyphenyl)-2,2' ∶ 6',2″-terpyridine] and its three complexes Pm Phtpy-Co~(2+),Pm Phtpy-Ni~(2+),Pm Phtpy-Nd~(3+) are synthesized using 4'-(4-methacryloyphenyl)-2,2'∶ 6',2″-terpyridine as the substrate. Their structures are fully confirmed by ~1H NMR,FT-IR,and GPC. The magnetic behavior is measured as a function of the magnetic field strength at 30 kOe and as a function of temperature(5-300 K). The magnetic hysteresis loops of the complexes show a typical " S" shape at 5 K,which suggested soft ferromagnetic properties.
【Fund】: 江西省自然科学基金(20161BAB203085);; 江西省教育厅科学技术青年基金(GJJ150326)资助项目
【CateGory Index】: O631.3;O641.4
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