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Study on the Synthesis and Preparation of Tungsten(Ⅳ)and Molybdenum(Ⅳ)Carboxylato Peroxo Complexes

Shi Xiaobo;Li Chungen;Wu Shenghua (Department of Chemistry,Jiangxi Normal University,Nanchang 330027)  
n this paper,synthesis method of ten new tungsten (Ⅳ) and molybdenum (Ⅵ)peroxo complexes (NH4),[MO(O2)(C2O4)] (M=W or Mo),(NH4)2[MO (O2)2L].2H2O(M=W or Mo,L=tartrate,citrate or palate) and (NH4)4[M2O2(O2)4(C4H2O6)].4H2O(M=W or Mo) is reported.Raman and iR spectra of the solid complexes and Raman spectra of their aqueous solutions have been measured, and these spectra are used to suggest the structure of the species in the solid state and solution.Thermal stability of the peroxo complexes has also been studied.
【Fund】: 国家自然科学基金
【CateGory Index】: O641.4
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Chinese Journal Full-text Database 10 Hits
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3 GONG Hong, YANG Zhonghua, JIANG Heng *, SUN Zhaolin, ZHANG Xiaotong(Department of Material Science, Fushun Petroleum Institute, Fushun 113001, Liaoning, China);Role of Acidic Ligand for Clean Synthesis of Adipic Acid via Catalytic Oxidation of Cyclohexene[J];Chinese Journal of Catalysis;2002-02
4 WANG Xiu-li 1,2 ,KANG Zhen-hui 1,LAN Yang 1,WANG En-bo 1 (1.Faculty of Chemistry,Northeast Normal University,Changchun 130024,China; 2.Department of Chemistry,Jinzhou Normal College,Jinzhou 121000,China);Organic-inorganic hybrid polyoxometalate nanoparticles modified wax impregnated graphite electrode:preparation, electrochemistry and electrocatalysis[J];Journal of Northeast Normal University (Natural Science Edition);2002-01
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7 GONG Hong, JIANG Heng~*, LU Zhen-Bo (Department of Applied Chemistry, Fushun Petroleum Institute, Fushun 113001, China);A New “Green” Route to the Synthesis of Adipic Acid[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-07
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10 WANG Rui-Ying 1, LIU Lang 1, JIA Dian-Zeng 1*, LUO Jian-Min 2, FAN Zhao-Tian 2 (1. Institute of Applied Chemistry; 2. Physics and Chemistry Detecting Center, Xinjiang University, Urumqi 830046, China);Synthesis of Nanometer Amino Acid Heteropoly Charge-transfer Complex (HPhe)_3PMo_(12)O_(40)·2H_2O by One Step Solid State Reaction at Room Temperature[J];Chemical Research In Chinese Universities;2004-12
【Secondary References】
Chinese Journal Full-text Database 1 Hits
1 XIE Bao-hua, CAO Xiao-hua,ZHANG Kang-hua, ZHANG Yang-fan (College of chemistry and chemical engineering, Jiujiang University, Jiujiang 332005, Jiangxi, China);Progress on Applications of Tungsten Catalysts in the Green Synthesis of Adipic Acid[J];Chemical Intermediates;2008-05
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