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《Acta Sedimentologica Sinica》 2006-01
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Characteristics of Carbon Isotope and Origin of Natural Gas in Qaidam Basin

ZHAO Dong-sheng~(1,2) LI Wen-hou~(1) WU Qing-ya~(2) GAN Gui-yuan~(2)YANG Qian-zheng~(2) LI Yuan-kui~(2) HAO Xong-mei~(2) YANG Wu-ling~(2)(1.Geology Department of Northwest University,Xi'an710069;2.Qinghai Oilfield Company,CNPC,Dunhuang,Gansu736202)  
δ~(13)C_(1),δ~(13)C_(2),δ~(13)C_(3),δ~(13)C_(4)ofnatural gas isotopic composition are various in different parts of Qaidam Basin.The averageof them are-23.1‰,-24.1‰,-22.7‰ and-23.6‰ in Sanhu area around;-29.8‰,-24.7‰,-23.1‰ and-22.9‰ in Chaibeiyuan area;-39.2‰,-26.8‰,-23‰ and-23‰ in Chaixi area;-67.8‰,-39.2‰,-32.3‰ and lack ofδ~(13)C_(4)in Sanhu area.δ~(13)C_(4)δ~(13)C_(3)δ~(13)C_(2)δ~(13)C_(1)exist betweencomponent of most naturalgas isotope,and reversionof minor heavy carbon isotopic composition exist.Reginally,δ~(13)C_(1),δ~(13)C_(2),δ~(13)C_(3),δ~(13)C_(4)ofnatural gas isotopic compositiondecrease gradually fromSanhu area around,Chaibeiyuan area and Chaixi area to Sanhu area.δ~(13)C_(2)-δ~(13)C_(1)andδ~(13)C_(3)-δ~(13)C_(2) ofnatural gas isotopic composition increase gradually fromSanhu area around,Chaibeiyuan area and Chaixi area to Sanhu area,the averageof them are-0.8‰ and-0.9‰ inSanhu area around,5.1‰ and 1.3‰ in Chaibeiyuan area,14.5‰ and 2.3‰ in Chaixi area,27.9‰ and 12.5‰ in Sanhu area. δ~(13)C_(4)δ~(13)C_(3)δ~(13)C_(2)δ~(13)C_(1)exist betweencomponent of most naturalgas isotope because naturalgas of organic geneses are derived from the similar process of thermodynamic action,and reversionof minor heavy carbon isotopic composition exist because of the mixed action of natural gas from the different derivation or the difference of duration,temperatures and pressuresin developing hydrocarbon process from the same source rock.The difference between δ~(13)C_(2)-δ~(13)C_(1)and δ~(13)C_(3)-δ~(13)C_(2)in different area depend on duration,temperatures and pressuresof source rock evolution,the higher temperatures and pressuresand the longer duration of source rock evolution,the more uniformδ~(13)C distribution between naturalgas component.In the meantime,bacteria and types of kerogen have an effect on δ~(13)C_(2)-δ~(13)C_(1)andδ~(13)C_(3)-δ~(13)C_(2)to some extent.The study on carbon isotope geochemical characteristic.can not only divide types of naturalgas and discusstheir geneses in theory,but also guide the exploration of naturalgas.
【CateGory Index】: P618.13;P597
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