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《Materials Review》 2007-S2
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Microwave-assisted Synthesis of Octadecyl Acrylate Polyester

WANG Kejun, LIU Fang, HU Shanling ( College of Chemistry and Life Science, Gannan Normal University, Ganzhou 341000; College of Materials Science and Engineering,South China University of Technology, Guangzhou 510640)  
Octadecyl acrylate polyester is prepared by microwave heating from octadecyl acrylate monomer in the presence of an initiating agent, BPO, in the toluene. The effects of microwave power and processing time, the concentration of initiating agent and the solvent on the polymer reaction are investigated. IR, GPC, DSC are employed to characterize the structure, molecular weight and distribution, Tm, and the energy of melting. Microwave-assisted technology has proven to be a excellent method of providing energy for the polymerization reaction, and the molecular structure of the product is in good a-greement with those reported in the literature. The molecular weight of the polymer is 13259, with a narrow distribution of 1.50 (Mw/Mn), when treated under at a power of 195W for 15 min. The intrinsic viscosity is 13.2mL·g-1 and the yield reaches 84.6%.Superiority of microwave-assisted synthesis is fully reflected in terms of efficiency and energy-saving.
【CateGory Index】: TQ316.3
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【Citations】
Chinese Journal Full-text Database 9 Hits
1 WANG Ke-jun~(1,2),LIU Fang~1,JIA De-min~1(1.College of Materials Science and Engineering,South China University of Technology,Guangzhou 510641,China;2.Dept.of Chemistry and Life Science,Gannan Teacher's College,Ganzhou of Jiangxi Prov.341000,China);SYNTHESIS OF 191~# UNSATURATED POLYESTER BY MICROWAVE IRRADIATION[J];Fiber Reinforced Plastics/Composites;2007-01
2 YANG Huaming HUANG Chenghuan SONG Xiaolan JIN Shengming QIU Guanzhou (Department of Inorganic Materials,School of Resources Processing and Bioengineering, Central South University,Changsha 410083,China);Research Progress in Microwave Synthesis of Inorganic Nanophase Materials[J];Materials Review;2003-11
3 ZHONG Fachun, HE Jiangping, WANG Xiaochuan, ZHAO Xiaodong, ZHANG Xiaohua(Insitute of Chemical Materials, Chinese Academy of Engineering and Physics, Mianyang 621900);Structure and Properties of Epoxy Foams Prepared by Microwave Irradiation[J];Materials Review;2006-08
4 ZHONG Shengliang1, ZHANG Maisheng2, HUANG Yixiang1(1 College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022;2 School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275);Semiwork Synthesis of Zeolite 4A by Microwave[J];Materials Review;2007-01
5 Zhang Weibang, Zeng Huiyang and Li Zhuomei (Institute of Polymer Science, Zhongshan University);STUDIES ON THE SYNTHESIS AND CHARACTERIZATION OF POLY (n-ALKYL ACRYLATES) AND THEIR LOWERING EFFECT ON THE POURING-POINT OF OIL[J];Polymeric Materials Science & Engineering;1989-05
6 WANG Ke-jun~(1,2),LIU Fang~1,ZHOU Xiao-lian~1,JIA De-min~1 (1.College of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,China;2.Department of Chemistry and Life Science,Gannan Teacher's College,Ganzhou 341000,China);Microwave-assisted synthesis of octadecyl acrylate[J];Science & Technology In Chemical Industry;2005-05
7 SONG Zhao zheng 1,2 ,GE Ji jiang 2,ZHANG Gui cai 2,Zhao Fu lin 2 (1. School of Chemical Engineering University of Petroleum, Beijing 102200, China; 2. Research Center of Fine Chemicals & Oilfield Additives University of Petroleum, Dongyin;INFLUENCE OF SOLVENTS ON POLYMERIZATION OF OCTODECYL ACRYLATE[J];Acta Petrolei Sinica (Petroleum Processing Section);2001-06
8 GU Yu-rong, ZHU Xiu-lin, CHENG Zhen-ping, CHEN Jian-ying, LU Jian-mei(Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou Jiangsu 215006,China);Atom Transfer Radical Polymerization of Octadecyl Acrylate[J];Petrochemical Technology;2003-04
9 ZHOU, Zhong-Zheng HE, Yan-Zhen CAO, Min YANG, Guang-Fu (Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079);Research Advances in Microwave-Assisted Combinatorial Synthesis[J];Chinese Journal of Organic Chemistry;2006-11
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Zhang Zhen,Zhao Zhihong,Zhang Rui(The Magazine House of EPA,Jinan 250031,China)Gao Qun(Jinan Representative Department,Nanjing Military Representative Bureau,Jinan 250031,China);ADVANCE IN THE ENGINEERING THERMOSETS OF CHINA IN 2007[J];Engineering Plastics Application;2008-05
2 Liao Xuehong,Zhu Yuling(College of Chemistry and Applied Chemistry,Huanggang Normal University,Huanggang 438000,China);Single-Mode Microwave-Hydrothermal Controlling Synthesis of PbS Nanocrystals[J];Micronanoelectronic Technology;2009-08
3 LIU Chang-chun~(1,2),LI Deng-hao~3(1.Nanjing University of Technology,Nanjing 210009,China;2.Jiangsu Food Science College,Huai'an 223003,China;3.Huaiyin College of Technology,Huai'an 223001,China);SYNTHESIS AND DISPERSION OF HYPERDISPERSANT PS-b-PAA BY RAFT[J];Journal of Beijing Technology and Business University(Natural Science Edition);2006-01
4 LI Xiao-long,ZHANG Feng-qin,HE Nong-yue,WU Yang(Hunan Key Laboratory of Green Packaging and Application of Biological Nanotechnology,Hunan University of Technology,Zhuzhou 412008,China);Effects of Different Pretreatment Methods on Performance of Rice Straw Fiber[J];Packaging Engineering;2010-01
5 ZHANG Feng-qin, LI Xiao-long, HE Nong-yue, ZHU Wei-lin, HE Yi-neng(Hunan Key Laboratory of Green Packaging and Application of Biological Nanotechnology, Hunan University of Technology, Zhuzhou 412008, China);Study of Influencing Factors of Cushioning Material Preparation from Rice Straw Fiber[J];Packaging Engineering;2010-03
6 ZHAO Jing, CHEN Jin, ZHANG Meng, LIN Yuansheng (College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024; Te Xing Metallurgical Technique Exploitation Corporation of Taiyuan, Taiyuan 030002);Non-thermal Effect during Microwave Heating at Low Temperature[J];Materials Review;2007-S2
7 YANG Bin-bin1,QING Feng-ling1,2,MENG Wei-dong1,21 Key Laboratory of Science & Technology of Eco-Textile,Ministry of Education,Donghua University,Shanghai 201620,China2 Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China;Synthesis of Novel Fluorinated Acrylate Co-polymers and Their Application on Cotton Fabrics[J];东华大学学报(英文版);2010-01
8 WU Yue, JIANG Jia-yi, LIU Xiu-mei,WEN Jing (Department of Chemistry Liaoning Normal University, Dalian Liaoning 116029, China);Preparation and Construction Token of Hexadecyl Methylacrylate[J];Journal of Dalian Nationalities University;2004-03
9 Wan Lin Zheng Kunpeng Jiang Luying Wu Lifang Zhang Wei (College of Resources and Environmental Engineering,Wuhan University of Science and Technology,Wuhan 430081);Microwave-assisted Heating Synthesis of 13X-type Zeolite Drying Agent from Coal-series Kaolin[J];Non-Metallic Mines;2010-05
10 FU Xue,LI Dan-dong,YU Hai-lian,WANG Rong-hui,CAO Zu-bin~*(School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China);Preparation and Application on Depressant of Acrylate Copolymer[J];Journal of Liaoning University of Petroleum & Chemical Technology;2006-03
China Proceedings of conference Full-text Database 2 Hits
1 ZHAO Jing~1,CHEN Jin~1,ZHANG Meng~1,LIN Yuansheng~2 (1 College of Materials Science and Engineering,Taiyuan University of Technology,Taiyuan 030024; 2 Te Xing Metallurgical Technique Exploitation Corporation of Taiyuan,Taiyuan 030002);Non-thermal Effect during Microwave Heating at Low Temperature[A];[C];2007
2 WANG Kejun~1,LIU Fang~2,HU Shanling~1 (1 College of Chemistry and Life Science,Gannan Normal University,Ganzhou 341000; 2 College of Materials Science and Engineering,South China University of Technology, Guangzhou 510640);Microwave-assisted Synthesis of Octadecyl Acrylate Polyester[A];[C];2007
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 DING Ming tong, DU Xian zhi, CHENG Fan, ANG Feng (College of Physics and Electrical Information, Anhui Normal University, 241000, Wuhu, Anhui, China);RESEARCH AND DEVELOPING OF Y-ZrO_2 RARE-EARTH TOUGHENING CERAMICS[J];Journal of Anhui Normal University(Natural Science);2000-04
2 Cheng Si Wen Dijiang(Suzhou University);STUDY PROGRESS IN TOUGHENING OF UNSATURATED POLYESTER RESINS[J];Fiber Reinforced Plastics/Composite;2003-03
3 YANG Xiaoyi, ZHANG Gaoyong, LI Qiuxiao, WANG Feng(Research Institute of Daily Chemical Industry, Taiyuan030001,China);Production and application of 4A-zeolite[J];China Surfactant Detergent & Cosmetics;2003-01
4 ZHONG Shengliang ZHANG Maisheng SU Qiang (School of Chemistry and Chemical Engineering,Sun Yat-Sen(Zhong Shan)Universty,Guangzhou 510275);Rapid Synthesis of Spherical Zeolite 4A at Low Temperature by Ultrasound[J];Materials Review;2005-04
5 Yang Shenghong, Zhang Xiaoming, Zhang Tingjie, Wang Keguang, Zhu Yubin (Northwest Insititute for Nonferrous Metal Research, Xi'an 710016);TiO_2 Nano Powders Prepared by Means of Microwave Radiation[J];Rare Metal Materials and Engineering;2000-05
6 Xiang Daoping, Liu Ying, Zhao Zhiwei, Gao Shengji, Tu Mingjing (College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China);Synthesis and Characterization of Nanocrystalline Ti(C_(0.45),N_(0.55)) Solid Solution Powders[J];Rare Metal Materials and Engineering;2006-S2
7 Zhang Canying Zhu Haitao Wang Jixin Chang Shangbo (Institute of Materials Science and Engineering,Qingdao University of Science and Technology,Qingdao 266042,China);Preparation of CuO Nanoparticles by Ultrasonic Vibration and Microwave Irradiation[J];Rare Metal Materials and Engineering;2007-S2
8 LU Zixing; TIAN Changiin; XIE Ruoze (Peking university) (Southwest Institute of Structural Mechanics);THE COMPRESSED PROPERTIES OF POLYURETHANE RIGID(PUR) FOAM[J];CHINESE JOURNAL OF MATERIAL RESEARCH;1994-05
9 FU Zhi Feng , LIU Hai Tao, SHI Yan, JIAO Shu Ke [WT5”BX](Department of Polymer Engineering, College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China) [WT5HZ];Synthesis of PSt-b-PBA-b-PSt and PMMA-b-PBA-b-PMMA Triblock Copolymers by Atom Transfer Radical Polymerization with Ethyl α,α-Dibromoacetate as Difunctional Initiator[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-06
10 Zhang Weibang,Feng Ke and Li Zhuomei(The Institute of Polymer Science Zhongshan University,Guangzhou);SYNTHESES OF POLY(n-ALKYL METHACRYLATES) AND THEIR EFFECT ON THE POUR-POINT-DEPRESSION OF OIL[J];Polymeric Materials Science & Engineering;1987-04
China Proceedings of conference Full-text Database 1 Hits
1 Wang Jiangying Chang Aimin Wu Jun (Xinjiang Institute of Physics,Urumqi,830011,China);Microwave Sintering of the NiMn_2O_4 Nano-powder[A];[C];1998
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