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《Journal of Northeast Normal University (Natural Science Edition)》 2005-01
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Synthesis of Cs_3PMo_(12)O_(40)·12H_2O nanoparticles of polyoxometalates with Keggin structure by W/O microemulsion method

ZHANG Su-xia,WANG En-bo (Faculty of Chemistry,Northeast Normal University,Changchun 130024,China)  
The nanoparticles of polyoxometalates (POMs) with Keggin structure,Cs_3PMo_(12)O_(40)·12H_2O,was prepared by the microemulsion media method which was performed in AOT/n-heptane/water system.TEM photographs of the Cs_3PMo_(12)O_(40)·12H_2O nanoparticles showed that the mean diameters of the spherical particles is 60 nm.It have been found that,under the same reaction condition the mean diameters of the nanoparticles increased to ca.200 nm when the concentration of reactant POMs was more than 50 mol/m~3.IR spectrum of the nanoparticles indicated that Keggin structure of Cs_3PMo_(12)O_(40)·12H_2O nanoparticles still remain.XRD pattern of the nanoparticles revealed that these solids are of crystallization.
【Fund】: 国家自然科学基金资助项目(39870895)
【CateGory Index】: O614
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