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《Geochimica》 2004-06
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Modes of occurrence of selenium in bl ack Se-rich rocks of Yutangba

ZHU Jian-ming 1 ,LI She-hong 1 ,Zuo-wei 1,2 ,I.Sykorova 3 ,SU Hong-can 4 ,ZHENG Bao-shan 1 ,J.Pesek 5 1.Institute of Geochemistry,Chinese Academy of Sciences,Guiyang550002,China;2.Graduate School of Chinese Academy o f Sciences,Beijing100039,China;3.Institute of Rock Structure and Mech anics AS CR,V Holeovi.kách41,18209Prague8,Czech Republic;4.Maternity and Child-care Center in E nshi Prefecture,Hubei445000,China;5.Faculty of Science,Charles University of Prague Albertov6,Praha2,12843,Czech Republic Correspondence should be addressed to ZHU Jian-ming(E-mail:jmzhu69@sohu.com)Received May 21,2004;revised September 13,2004;accepted September 14,2004;published November,2004  
Yutangba,located in the northern part of Shuanghe Town of Enshi City in SW Hubei Province,is an area of high-Se in China,and it is also the only site in the world where a sudden o ccurrence of Se poisoning took place.Selenium is present mainly in the bla ck Se-rich rocks(carbonaceous chert and carbonaceou s shale)of Upper Permian Maokou Formation which is 210m north of Yutangba.In Se-rich rock s,native selenium and copper(iron)selenide assemblages have been disc overed.These minerals include nati ve selenium,krutaite,klockmannite,mandarinoite,naumannite,Se-bearing pyrite,Se-bearing chalcopyrite and unidentified Fe-Se minerals.Of them,the assemblage of native selenium,k rutaite and klockmannite is mainly l ocated within the carbonaceous chert near the fault surface,and so are Se-bearing pyrite and Se-bearing chalcopyrite.However,the assemblage of native selenium and krutaite is just found i n carbonaceous mudstone.Mandarinoite and unidentified Fe-Se minerals can be found in the weathered carbonaceous chert that was exposed.Our results i ndicate that native selenium widely exists,and other selenium minerals and their assemblages are discrete in black S e-rich rocks and only found in some sp ecial sites.That Cu-Se minerals are easil y found also shows that copper may pla y a significant role in the geochemic al mobility and transformation of sele nium in the supergene environment of Yutangba.
【Fund】: 国家自然科学基金(4010300740133010)
【CateGory Index】: P618.76
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