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《Geochimica》 2011-02
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Simulation experiments on the thermochemical sulfate reduction system of n-hexadecane and magnesium sulfate

YUE Chang-tao1,LI Shu-yuan1,XU Ming2,ZHANG Yong-han1 and ZHONG Ning-ning3 1.State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Beijing 102249,China;2.New Energy Office in Daqing Oilfield Co.,Ltd.,Daqing 163453,China;3.Faculty of Natural Resource and Information Technology,China University of Petroleum,Beijing 102249,China  
Thermal simulation experiments on the thermochemical sulfate reduction(TSR) system of n-hexadecane and magnesium sulfate were carried out using an autoclave operated at specified temperature and pressure in the presence of water.Properties of the gas-oil-solid 3-phase products were analyzed by some advanced analytical methods including gas chromatography,microcoulometry,capillary gas chromatography combined with a pulsed flame photometric detector(GC-PFPD),FT-IR and X-ray diffraction.The results show that the reaction can proceed at 450~550 ℃ to produce MgO,S,C,H2S,CO2,and a series of organic sulfur compounds such as mercaptans,sulfoethers and thiophenes as the main products.The reaction kinetics was studied.According to the reaction model,the calculated activation energy of the reaction is 54.88 kJ/mol.
【Fund】: 国家自然科学基金(40702019)
【CateGory Index】: O621.25
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