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《Geochimica》 2015-01
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Experimental study on hydrocarbon retention-expulsion of Es4 formation source rock in the Dongying Depression

YAN Yong-he;ZOU Yan-rong;QU Zhen-ya;CAI Yu-lan;WEI Zhi-fu;PENG Ping-an;Petro China Xinjiang Oilfield Company;State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences;University of Chinese Academy of Sciences;Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences;  
A large amount of oil has been generated from the excellent source rock of the Es4 formation in the Dongying Depression, Bohai Bay Basin. The evolving trend of the source rock is analyzed by using the IH vs. Tmaxplot. Combining the simulation of the hydrocarbon retention potential, which is acquired by the solvent swelling experiment, with the hydrocarbon generation characteristics and process of this area, the retention and expulsion history of the Es4 formation are restored. With increasing maturity, some samples evolved from the same hydrocarbon-generated parent material can be regarded as a natural profile. The results of the retention simulation show that the volumetric swelling ratio and the amount of retention are decreasing with the increasing maturity, and that the immaturity sample has the largest retention hydrocarbon potential. The group-type fractions of the liquid hydrocarbon which retained in the source are not the same, saturates have the minimum hydrocarbon retention and it means that saturates are most easily expulsed from the source rocks. However, the NSOs(resins and asphaltenes) have the largest retention hydrocarbon potential. Combining the hydrocarbon retention history with the generation history of the basin, the whole retention-expulsion process of the Dongying Depression can be obtained. Therefore, the hydrocarbon retention experiment and evaluation method for the natural profile samples are established.
【Fund】: 国家重点基础研究发展计划项目(2014CB239101);; 国家自然科学基金(41173054);; 中国科学院广州地球化学研究所135项目(Y234021001)
【CateGory Index】: P618.13
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