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《GEOCHIMICA》 1996-04
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FRACTIONATION DIFFERENCE OF STERANES AND TERPANES IN COAL AND MUDSTONE DURING HYDROCARBON EXPULSION

Dai Qinglin;Hao Shisheng;Lu Shuangfang;Zhang Aiyun(Petroleum University, Beijing 100083)(Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640)(Daqing Petroleum College, Anda 151400)(China University of Geosciences, Beijing 10  
The simulation experiments of hydrocarbon expulsion have been conducted at low temperature (150℃) to study the fractionation of steranes and terpanes in coal and mudstone.The results show that hydrocarbon expulsion has influenced the distribution of steranes and terpanes in coal and mudstone. The geochromatography of sterane and terpane in coal is obviously different from that in mudstone during hydrocarbon expulsion. The distributions of sterane and terpane in expelled hydrocarbon of coal are different from those in residual hydrocarbon of coal and, therefore, it is difficult to explain the relationship between expelled and residual hydrocarbons of coal based on the sterane and terpane parameters. The remarkable difference in geochromatographic effects of sterane and terpane in coal and mudstone suggests that hydrocarbon expulsion should be taken into account when steranes, terpanes and other biomarkers are used to study the formation of hydrocarbon from coal. New methods and indicators are highly desirable for this study.
【Fund】: 博士学位论文课题
【CateGory Index】: P618.130.5
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