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《Journal of Shanghai University of Electric Power》 2006-01
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The Agglomeration and Dissolution of Pt/C Catalyst in Phosphoric Acid

ZHANG Jun-xi~ 1,XU Na ~2,WEI Zeng-fu~3 (1.Electrochemical Research Group,Shanghai University of Electric Power,Key Laboratory of State Power Corporation of China,Shanghai 200090,China;2.Northeast University of Electric Power,Jilin 132012,China; 3.Guangdong Power Test and Research Institute,Guangzhou 510600,China)  
The effects of the crystallite size and the dissolution on the electrocatalytic behavior of carbon-supported platinum ageing in phosphoric acid are investigated by using XRD/TEM and elec-trochemical measurement.The distribution of crystallite size of Pt tends to shift to right with increasing ageing time,meanwhile the dissolution of Pt takes place under open circuit potential but not under cathodic polarization.Result shows that the decrease of electrochemical surface areas of Pt/C catalyst is responsible for the agglomeration and dissolution of platinum crystallites.The agglomeration of Pt crystallite can be explained by the migration and coalescence growth mechanism because there is no potential effect during the growth of Pt crystallite.The mechanism of the agglomeration and the dissolution of carbon-supported platinum are discussed.
【Fund】: 上海市重点培育学科(P1304);; 上海市教委重点学科建设项目(第4期)资助
【CateGory Index】: TM911.4
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【References】
Chinese Journal Full-text Database 1 Hits
1 Zhang Junxi~1,Cao Xiaowei~ 1,2 ,Zhang Lingsong~ 1,4 ,Yan Licheng~3,Zhang Wanyou~4( ~1 Electrochemical Research Group,Shanghai University of Electric Power,Key Laboratoryof State Power Corporation of China,Shanghai 200090; ~2 School of Environmental and Chemical Engineering,Shanghai University,Shanghai 200072; ~3 Hangzhou Teachers University,Hangzhou 310036; ~4 Department of Applied Chemistry,Northeast Dianli University,Jilin 132000);The Carbonation of Carbon Source and its Choice in the Carbon Coating Treatment of LiFePO_4[J];Chemistry;2009-04
【Co-references】
Chinese Journal Full-text Database 3 Hits
1 Zhang Jingping, Zhao Chengda, Wang Rongshun (Department of Chemistry, Northeast Normal Univeristy, Changchun);Electronic Energy Bands of the Conducting Polymer Poly (1,4-dithianaphthalene)[J];Chemical Research In Chinese Universities;1990-09
2 LIAO Yanfen,LUO Zhongyang,WANG Shurong,YU Chunjiang,CEN Kenfa istry of Education, Zhejiang University, Hangzhou310027, China);MECHANISM OF RAPID PYROLYSIS OF CELLULOSEⅠ. EXPERIMENTAL RESEARCH[J];Journal of Fuel Chemistry and Technology;2003-02
3 DONG Ning-ning (Hainan Tobacco Monopoly Administration, Haikou 570105, China);Study of Carbohydrate Compounds at Different Temperatures by Pyrolysis-Gas Chrometography-Mass Spectrometry[J];Journal of Chinese Mass Spectrometry Society;2004-01
【Secondary References】
Chinese Journal Full-text Database 8 Hits
1 YANG Liu,HE Gang,HONG Jianhe,HE Mingzhong(Faculty of Materials Science and Chemical Engineering,China University of Geosciences,Wuhan 430074);Review of the Influence of Carbon Sources and Its Coating Method on the Electrochemical Performance of LiFePO_4/C Composite Materials[J];Materials Review;2011-19
2 CHEN Ying-qin,HE Han-bing,LIU Chang,LU Xiao-hua(College of Chemistry and Chemical Engineering,Key Laboratory of Materials-Oriented Chemical Engineering,Nanjing University of Technology,Nanjing,Jiangsu 210009,China);Thermal Decomposition of Glucose and Sucrose by Kinetics Analysis[J];The Chinese Journal of Process Engineering;2010-04
3 Zhang Fuping,Ji Yong,Li Andong,Fan Hao,Jiang Yuanwen,Gu Chendi(Key Laboratory of Analytical Chemistry for Life Science,Ministry of Education,Department of Chemistry,Nanjing University,Nanjing 210093);Progresses and Challenges in Studies on Cathodic Materials of Li-Ion Battery[J];Chemistry;2011-10
4 OU Jun ke1,Lin Lin1,GUO Yong2*,WANG Qiang3,XIAO Dan1,2(1.College of Chemical Engineering,Sichuan University,Chengdu 610065,China; 2.College of Chemistry,Sichuan University,Chengdu 610064,China; 3.Panhua Science and Technology Co.,Ltd.,Panzhihua 617000,China);Electrochemical performance of LiFePO_4 synthesized by hydrothermal method[J];Chemical Research and Application;2011-12
5 XU Shou-dong1,2,ZHUANG Quan-chao1,ZHU Ya-bo1,2(1 Li-ion Batteries Laboratory,School of Materials Science and Engineering China University of Mining and Technology,Xuzhou 221116,P.R.China;2 School of Chemical Engineering and Technology,Jiansu);Preparation and Electrochemical Properties of Li_2MnSiO_4/C Used Different Carbon Source[J];Synthetic Materials Aging and Application;2013-02
6 Zhu Jianxin;Li Jun;Huang Huimin;Tao Xun;Huang Jiwei;School of Light Industry and Chemical Engineering,Guangdong University of Technology;;Research progress in core/shell structure anode material for lithium ionic batteries[J];New Chemical Materials;2013-09
7 Li Jincai,Jiang Hongying,Gu Dawei,Li Jishu,Shen Linjiang(School of Sciences,Nanjing University of Technology,Nanjing210009,China);Preparation and oxidation process of LiFePO_4/C composites[J];China Sciencepaper;2012-09
8 QI Wen-Juan1,LUO Yong-Chun1,2,KANG Long1,ZHANG Guo-Qing1(1.College of Materials Science and Engineering,Lanzhou University of Technology,Lanzhou 730050,China;2.State Key Laboratory of Gansu Advanced Non-Ferrous Metal Materials,Lanzhou University of Technology,Lanzhou 730050,China);Synthesis of Carbon-coated LaFeO_3 and Electrochemical Properties of the Composites in Alkaline Solution[J];Journal of Inorganic Materials;2012-12
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