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《Discovery of Nature》 1991-01
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CHEMICAL MODELING OF ATP-DRIVEN ELECTRON TRANSPORT

Wu Yefan (Department of Biology, Xiamen University)  
Most investigaters believe that MgATP is bound,not to the Fe_4S_4~* center,but to some other part of Fe-Protein. Chemical-modeling studies of ATP-driven electron-transfer in nitrogenase reaction show that ATP can complex with Fe_4S_4~* Cluster.These resulting may be taken as strong evidence in support of the view that MgATP and Mg ADP are all coordinated to the Fe_4S_4~* center of the Fe-Protein,through some of PO_4 groups,rather than to other part of the protein.
【Fund】: 国家自然科学基金
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