Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chinese Journal of Luminescence》 2001-03
Add to Favorite Get Latest Update

Synthesis and Spectral Characteristics of Sm ~( 3+) Doped Na_3La_2(BO_ 3)_ 3

ZHANG Guo chun 1, FU Pei zhen 2, WANG Guo fu 2, GUO Fan 1, GUAN Xiang guo 1 (1. Department of Chemistry, University of Science and Technology of China, Hefei 230026, China; 2. Beijing Center for Crystal Research and Development, Chinese Acade  
In recent years, the borate luminescence materials have received much attention owing to their low synthetic temperature and high luminescent efficiency. In order to search for the new luminescent material , the synthesis and luminescence properties of Na 3(La 1- x Sm x ) 2(BO 3) 3( x =0~0 10) were firstly reported in this paper. The samples in polycrystalline form were synthesized by the conventional solid state reaction. The mixture of Na 2CO 3,La 2O 3,Sm 2O 3 and H 3BO 3 with an excess of 5 mol% were preheating at 500℃ for 10 hours, then sintered 24 hours at 720~750℃for Na 3(La 1- x Sm x ) 2(BO 3) 3( x =0 005~0 10), and 935℃ for Na 3La 2(BO 3) 3. In the course of experiment, the purity of all samples was checked by X ray diffraction (XRD) . The single phase powder of Na 3(La 1- x Sm x ) 2(BO 3) 3 in range of 0 0~1 0mol% were obtained when repeated heat treatment caused no further changes in the X ray powder diffraction patterns. X ray diffraction analysis shows that all these compounds are isomorphous with Na 3La 2(BO 3) 3, which belongs to orthorhombic systems, space group Amm 2. This indicats that the La 3+ ions( r =0 105nm) in Na 3La 2(BO 3) 3 can be partly replaced by the smaller rare earth ions Sm 3+ ( r =0 096nm) without change of crystal structure. The infrared spectra of the compounds Na 3La 2(BO 3) 3 (a), Na 3(La 0 995 Sm 0 005 ) 2(BO 3) 3 (b) and Na 3(La 0 94 Sm 0 06 ) 2 (BO 3) 3 (c) scanned between 400~ 2 000cm -1 in the transmittance mode were measured . The results were in agreement with the characteristic values of the BO 3- 3 groups. The minor difference observed in the infrared spectra of (b) and (c) at 450~550 cm -1 might be due to the changes in the Sm and La ions and their ionic radii. The luminescent properties of Sm 3+ in Na 3La 2(BO 3) 3 host were investigated by the excitation and emission spectra at room temperature. The emission spectrum obtained for Na 3La 2(BO 3) 3∶Sm 3+ under 400nm excitation at room temperature in range of 500~750nm was shown in Fig.2(a). There were four main emission peaks at near 564, 599, 645 and 707nm, among which the intensity of the 599nm line was the highest. These emission peaks were all narrow sharp peak not broad bands. They originated from the f f transitions of Sm 3+ ions 4f electrons, which assigned to 4G 5/2 → 4H 5/2 transition between 550~570nm, 4G 5/2 → 6H 7/2 transitions between 580~610nm, 4G 5/2 → 6H 9/2 transition between 630~655nm and 4G 5/2 → 6H 11/2 transitions between 700~ 710nm , respectively. They belonged to the characteristic emission of Sm 3+ ions. The excitation spectrum for Sm 3+ 599nm emission recorded at room temperature showed lines corresponding to transitions 6H 5/2 →( 4K , 4L ) 17/2 (345nm), 6H 5/2 →( 4D , 6P ) 15/2 (362nm), 6H 5/2 → 4L 17/2 (375nm), 6H 5/2 → 4K 11/2 (400nm), 6H 5/2 → 4M 19/2 ( 6P , 4P ) 5/2 (418nm), and 6H 5/2 → 4I 13/2 ( 4I 9/2 ) (475nm). As we can see in Fig.2(b). The intensity of the transition at 400nm was found to be the highest in all the spectra. It showed that the strongest fluorescence emission at 599nm could be obtained under 400nm excitation . At room temperature, the emission spectra of Na 3(La 1- x Sm x ) 2(BO 3) 3 at different concentration were recorded by the excitation of 400nm. The relative peak heights can change with the concentration of Sm 3+ , while the peak positions remain practically unchanged. The relationship between fluorescent intensities of 599nm emission peak of Sm 3+ and ac
【Fund】: 国家自然科学基金资助项目 ( 5 9872 0 36 )
【CateGory Index】: O482.31
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 ZHAO Huiling,WANG Mingwen,LIU Shixiang,ZHANG Song,JI Chunyan,FANG JinSchool of Applied Science,University of Science and Technology Beijing,Beijing 100083,China;Sensitized luminescence of Eu~(3+) in Sr_8Si_4O_(12)Cl_8∶Eu~(3+),M~(3+)(M~(3+)=Sm~(3+),Al~(3+))[J];Journal of University of Science and Technology Beijing;2008-01
2 WANG Zhijun1,2,PAN Feng1,TAO Feng1,2,SUN Yufeng1,2, CAI Weili3,YAO Lianzeng3(1 School of Mechanical and Automotive Engineering,Anhui Polytechnic University,Wuhu 241000;2 Anhui Provincial Laboratory of High Performance Nonferrous Metals Material,Wuhu 241000;3 Department of Materials Science and Engineering,University of Science and Technology of China,Hefei 230026);Hydrothermal Synthesis and Luminescent of Hexagonal NaYF_4∶Ln~(3+) (Ln=Sm,Pr)Microprisms[J];Materials Review;2011-20
3 LIN Ying,GAO Shao-kang,WANG Gui-mei,SHI Wei-mei(College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou,Fujian 350002,China);Preparation and photoluminescence of a red-emitting phosphor KGd(WO_4)_2:Sm~(3+)[J];Journal of Fuzhou University(Natural Science Edition);2008-01
4 LI Qi-Hua PENG Yi-An CAO Xiao-Mei LIU Li-Min ZHU Xiao-Juan LEI Chun-Hua (Institute of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,P.R.China);Photoluminescence of Eu~(3+) in M_3La(BO_3)_3(M=Ca,Sr,Ba)[J];Chinese Journal of Spectroscopy Laboratory;2004-01
5 SHI Shi-kao~(1,2),LI Jun-min~1,ZHOU Ji~(2)1.College of Chemistry,Hebei Normal University,Shijiazhuang 050091,China2.State Key Lab of New Ceramics and Fine Processing,Department of Materials Science and Engineering,Tsinghua University,(Beijing) 100084,China;Luminescence Spectra of Sm~(3+) Doped Sr_2CeO_4 Synthesized through Co-Precipitation Process[J];Spectroscopy and Spectral Analysis;2005-10
6 YANG Zhiping,HAN Yue,SONG Yanchun,ZHAO Qing,ZHOU Dongzhan,LIU Yufeng(College of Physics Science and Technology of Hebei University,Baoding 071002,Hebei,China);Preparation and Luminescence Properties of Ba_(2-x)B_2O_5:xSm~(3+) Red-Emitting Phosphor[J];Journal of the Chinese Ceramic Society;2012-03
7 DU Ning1,2,Huang Hong-yun1,Han Zhe1(1.Department of Basic Courses,Tangshan college,Tangshan 063000,Hebei,China;2.College of Physic Science & Technology,Hebei University;Baoding 071002,Hebei,China);Luminescent properties of BaMg_2(PO_4)_2:Sm~(3+) red-emitting phosphor[J];Journal of Functional Materials and Devices;2012-03
8 YANG Zhi-ping,ZHAO Yin-hong,ZHAO Qing,HAN Yue,SONG Yan-chun, ZHOU Dong-zhan,LIU Peng-fei(College of Physics Science & Technology,Hebei University,Baoding 071002,China);Synthesis and luminescence properties of a novel red NaY(MoO_4)_2:Sm~(3+) phosphor[J];Journal of Optoelectronics.Laser;2012-10
9 YANG Zhiping;LIU Lipeng;LIANG Xiaoshuang;DONG Hongyan;HOU Chuncai;WANG Can;College of Physics Science and Technology,Hebei University;College of Electronic and Information Engineering,Hebei University;;Preparation and Luminescence Properties of Sr_3Y(PO_4)_3∶Sm~(3+) Phosphor[J];Journal of the Chinese Ceramic Society;2014-03
10 YANG Zhi-ping;LIANG Xiao-shuang;ZHAO Yin-hong;HOU Chun-cai;WANG Can;DONG Hong-yan;LIU Li-peng;College of Physics Science and Technology,Hebei University;College of Electronic and Information Engineering,Hebei University;;Preparation and Luminescence Properties of Reddish-orange Phosphors Ca_3Y_2(Si_3O_9)_2∶Sm~(3+)[J];Acta Photonica Sinica;2014-03
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 LI Yan-bing,TAO Feng,SUN Yu-feng,WANG Zhi-jun (Coll.of Mech.Engn.,Anhui Polytechnic University,Wuhu 241000,China);Synthesis and characterization of Nd-doped YF_3 frustum-octahedron micro/nano[J];Journal of Anhui University of Technology and Science(Natural Science);2010-02
2 ZHAO Su ling,HOU Yan bing,DONG Jing feng (Institute of Optoelectronic Technology,Northern Jiaotong University,Beijing 100044,China);Upconversion Luminescence of Rare Earth Ions[J];SEMICONDUCTOR OPTOELECTRONICS;2000-04
3 CHEN Ru-fen(Department of Chemistry,Hebei Normal University,Shijiazhuang 050016,China);Progress of Studies on Application and Preparation of Nanometer CeO_2[J];Micronanoelectronic Technology;2005-08
4 YANG Ru TAO ZhenLin QIN Jie LI Min(State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Phase composition and luminescence properties of neodymium-doped yttrium aluminum garnet (Nd∶YAG) ceramic powders[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2009-04
5 ( 1) Department of Applied Chemistry, Beijing University of Chemical Technology, Beijing, 100029; 2) Central Iron & Steel Research Institute, Beijing, 100081);The synthesis of a yellow emitting rare earth borate phosphor[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;1998-04
6 Zheng Minhui Zhen Xiuxin Zhao Zhigang Department of Physical Chemistry;Preparation and Characterization of Yb Doped SrCeO_3 Based High Temperature Proton Conductor[J];Journal of University of Science and Technology Beijing;1993-03
7 LUO Shiyong, ZHANG Jiayun Metallurgy School, UST Beijing, Beijing 100083, China;Defect Chemistry of Stronitum Titanate[J];Journal of University of Science and Technology Beijing;2001-05
8 Wang Minquan; Ma Lixin; Fan Xianping(Zhejiang University)(Nanjing University of Aeronautics & Astronautics);Study on Concentration Effects of Rare Earth Ions in Phosphate Glasses[J];GLASS & ENAMEL;1996-02
9 RUAN Gang, DUAN Chang-kui (Institute of Applied Physics, Chongqing University of Posts and Telecommunications, Chongqing 400065,P.R.China);Parameterization of calculated Pr~(3+) energy levels and experiment:a brief report[J];Journal of Chongqing University of Posts and Telecommunications;2005-01
10 ZHANG Song1,LIU Guixia1,DONG Xiangting1,WANG Jinxian1,SUN De2(1.School of Chemistry and Environmental Engineering,Changchun University of Science and Technology,Changchun,130022;2 School of Chemical Engineering,Changchun University of Technology,Changchun 130012);Preparation and Properties of YF_3:Eu~(3+) Luminesence nanobundles[J];Journal of Changchun University of Science and Technology(Natural Science Edition);2009-04
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 Yan Liu,Shi-xiang Liu,Ming-wen Wang,Wen-jun Li,Ting Zhang,and Xia Zhang School of Applied Science,University of Science and Technology Beijing,Beijing 100083,China;Synthesis and luminescence properties of Eu~(3+),Sm~(3+) doped(Y_xGd_(1-x))_2O_3:Si~(4+),Mg~(2+) long-lasting phosphor[J];矿物冶金与材料学报(英文版);2010-03
2 GENG Xiujuan 1,2,TIAN Yanwen1,CHEN Yongjie 2,XIAO Linjiu 2(1 School of Materials and Metallurgy,Northeastern University,Shenyang 110004;2 Department of Applied Chemistry,Shenyang Institute of Chemical Technology,Shenyang 110142);Progress in Studies on Tungstate and Molybdate Red Emitting Phosphor Used for White-LED[J];Materials Review;2010-13
3 He Xianghong, Zhou Jian, Lian Ning (Jiangsu Techers University of Technology, Changzhou 213001, China);Luminescence Performance of Novel Sr_2CeO_4:RE~(3+)(RE = Eu,Sm,Dy) Phosphors with Tunable Emission Colors[J];Rare Metal Materials and Engineering;2007-05
4 FU Jian1,2,SUN Li1,LIU Xiao-dong2,3,SONG Zhao-yuan2,3,LIU Dan2,LIU Dong-ping2(1.School of Mechanical Engineering,Dalian Jiaotong University,Dalian Liaoning 116028,China;2.Institute of Optoelectronic Technology,Dalian Nationalities University,Dalian Liaoning 116605,China;3.Institute of Infrared Optical Fibers and Sensors,Yanshan University,Qinhuangdao Hebei 066004,China);Nonlinear Optical Performance of Nd~(3+)-Doped Borosilicate Glass[J];Journal of Dalian Nationalities University;2009-01
5 XIONG Xiao-Su SHI Peng-Tu CHEN Hong-Jun LIU Hui-Yan CHENG Yi-Min(Hunan Province Product Commodity Quality Supervision Testing Institute,Changsha 410007,P.R.China);Study on the Synthesis and Luminescent Properties Analysis of CaO-SiO_2-B_2O_3:Eu~(2+) Glasses[J];Chinese Journal of Spectroscopy Laboratory;2009-03
6 FU Zhen-xing1,2,ZHENG Hai-rong1*,LIU Bi-rui2 1.College of Physics and Information Technology,Shaanxi Normal University,Xi'an 710062,China 2.College of Physics and Information Technology,Ningxia Normal University,Guyuan 756000,China;Spectroscopic Study on the Energy Transfer Effect in Sm~(3+)/Eu~(3+) Codoped Tetragonal LaOF Nanocrystals System[J];Spectroscopy and Spectral Analysis;2011-08
7 ZHOU Wei,L Shu-chen(Province Key Laboratory of Functional Nano-size Materials,Harbin Normal University,Harbin 150080,China);Preparation and Luminescent Properties of Nanocrystalline ZrO_2:Dy~(3+)[J];Acta Photonica Sinica;2008-10
8 TAN Xin-xin,LU Shu-chen(School of Physics & Electron Engineering,Harbin Normal University,Harbin 150080,China);Preparation and Luminescent Propeties of Er~(3+) and Er~(3+)/Yb~(3+)Codoped ZrO_2-Al_2O_3[J];Acta Photonica Sinica;2010-07
9 FU Zhen-xing,LIU Bi-rui (College of Physics and Information Technology,Ningxia Normal University,Guyuan,Ningxia 756000,China);Energy Transfer Effect of Sm~(3+)/Eu~(3+) Co-doped in LaOF Nanocrystals System with Hexagonal Phase[J];Acta Photonica Sinica;2011-02
10 YANG Zhi-ping,ZHAO Yin-hong,ZHAO Qing,HAN Yue,SONG Yan-chun, ZHOU Dong-zhan,LIU Peng-fei(College of Physics Science & Technology,Hebei University,Baoding 071002,China);Synthesis and luminescence properties of a novel red NaY(MoO_4)_2:Sm~(3+) phosphor[J];Journal of Optoelectronics.Laser;2012-10
China Proceedings of conference Full-text Database 3 Hits
1 Liu Wenpeng,Zhang Qingli,Sun Dunlu,Gu Changjiang,Luo Jianqiao,Wang Di,Jiang Haihe,Yin Shaotang The key laboratory of photonic devices and materials,Anhui Province,Anhui Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Anhui Hefei,230031;Crystal Growth and Spectral Properties of Sm:GGG Crystal[A];[C];2010
2 WEI Xin-jiao, YANG Zhong-min , LIU Yue-hui, CHEN Dong-dan (Institute of Optical Communication Materials, South China University of Technology, Guangzhou 510641, China);Preparation and the Luminescence Properties of Ce~(3+) /Sm~(3+) in Borosilicate Glasses[A];[C];2007
3 WANG RenQing (New Energy Technology & Application Research Center,Jiangxi University of Finance & Economics,Nanchang,JiangXi 330013,China);Preparation and Spectrum Properties of the CaCO_3-based green Phosphor[A];[C];2010
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved