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《Chinese Journal of Luminescence》 2017-09
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Raman Spectra and Crystal Structure of Ⅳ Materials

YANG Xue-xian;NING Yang-hua;WANG Xiao-yun;ZHAO He-ping;Materials Preparation Laboratory,School of Physics and Mechanical & Electrical Engineering,Jishou University;  
The correlation function of the size-bond parameter-Raman shift was formulated based on the bond order-length-strength( BOLS) correlation and core-shell model. The quantitative information of the bond length,bond energy and the effective atomic coordination number( CN) of the Ⅳmaterials was obtained. It is clarified that the size-induced phonon softening arises intrinsically from the undercoordinated atoms. Developed approach empowers the Raman technique in deriving quantitative.
【Fund】: 国家自然科学基金(11602094 11564013 11564012);; 湖南省自然科学基金(2015JJ6094);; 湖南省教育厅优秀青年项目(15B189);; 湖南省高校科技创新团队支持计划资助项目~~
【CateGory Index】: O657.37;O76
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