Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Environmental Science & Technology》 2010-05
Add to Favorite Get Latest Update

Simultaneous Determination of Two Kinds of Agricultural Chemicals in Soil by a New Amino Acid-derived Stationary Phase for HPLC

DENG Zhi-hua,LIU Yun-gen,XIA Hong-yun,CUI Ya-wei,LIANG Qi-bin (Department of Environmental Science and Engineering,South West Forestry College,Kunming 650224,China)  
By N-Benzyloxycarbonyl-L-Phenylglycine-L-Phenylglycine-derived Silica Gel Stationary Phase(BCPGPGSP),a simple and reliable positive-phase high performance liquid chromatographic (HPLC) method for the routine analysis of cypermethrin and fenvalerate in soil has been established. HPLC determination for the sample was performed in a BCPGPGSP column and detected at 254nm. Using a mixed solvent of hexane-dichloromethane(80~10,V/V)as the mobile phase,and the flow rate was 1.0mL/min.The method was proved to be liner in the ranges of 0~2.0mg/L for cypermethrin and fenvalerate. The relative standard deviations of inter-assay (n=4)were 5.70% for cypermethrin analysis and 5.5% for fenvalerate analysis. The recoveries of cypermethrin and fenvalerate were 81.0%~96% and 88.0%~96.7% respectively. The method has been successfully applied to the simultaneous determination of the cypermethrin and fenvalerate in soil.
【Fund】: 国家自然科学基金项目资助(30160092)
【CateGory Index】: X839.2
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【Citations】
Chinese Journal Full-text Database 4 Hits
1 ZHOU Shi-ping1,2,DUAN Chang-qun1,LIU Hong-cheng3,LIU Jian-xiang2,YANG Li-bo2,YANG Ju2(1.Laboratory for Conservation and Utilization of Bio-Resource && School of Life Science,Yunnan University,Kunming 650091,China;2.Department of Basic Courses,Southwestern Forestry College,Kunming 650224,China;3.Supervision and Testing Center for Farm Products Quality Ministry of Agriculture,Kunming 650223,China);Degradation of Cypermethrin in Celery Cultivated in the Greenhouse[J];Journal of Agro-Environment Science;2006-02
2 SHEN Cui-li,FAN Zhi-xian,ZHU Qing-shu(College of Chemical Engineering,Qingdao University of Science and Technology,Qingdao 266042,China);Residual Analysis of Cypermethrin in Corn and Soil[J];Journal of Qingdao University of Science and Technology(Natural Science Edition);2006-03
3 Zhou Xiaolong Sun Tao Wang Jianmei Zhang Min Qiao Kunyun(Inspection and Analysis Central, Xinjiang Agriculture Academy of Science, Urumuqi 830000,China);Determination of the Residues for the kinds of Chlorothalonil and Pyrethriods in Vegetables by Gas Chromatography[J];Chinese Journal of Scientific Instrument;2005-S1
4 Deng Zhihua1,Xia Hongyun1,Yuan Liming2,Ai Ping2(1.Department of Environmental Science and Engineering,South West Forestry College,Kunming 650224,China;2.Department of Chemistry,Yunnan Normal University,Kunming 650031,China);Preparation and Evaluation of N-Benzyloxycarbonyl-L-Phenylglycine-L-Phenylglycine-derived Silica Gel Stationary Phase for High Performance Liquid Chromatography[J];Yunnan Chemical Technology;2007-02
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 ZHENG Wei-Hua~1, ZHAO Jian-Zhuang~1,MA De-Ying~2,HOU Shi-Cong~3(~1Beijing Agricultural College, Beijing 102206;~2Xinjiang Agricultural University, Xinjiang,830052;~3China Agricultural University ,Beijing 100094);Development of Determination of Deltamethrin[J];Journal of Beijing Agricultural College;2003-04
2 LI Li-Jun,LI Cheng,XU Chao,ZHANG Yi-wen and SONG Hang(Department of Pharmaceutical and Biological Engineering,Sichuan University,Chengdu 610065);Determination of amino groups immobilized on amino-propyl-silica-gel surfaces by HPLC with reversible chemical reaction[J];Chinese Journal of Analysis Laboratory;2009-04
3 ZHENG Yong-bo 1,WANG Hai-ying 2 (1.Shandong Province Rizhao City Economic Development Zone Kuishan Street Office,Rizhao 276800,China; 2.Qiqihar City Diseae Prevention and Control Center,Qiqihar 161006,China);The determination of pyrethroid pesticide residues in peanut by gas chromatographic method[J];Journal of Science of Teachers College and University;2005-01
4 WANG Ying-jian(Liaoning Petrochemical Vocational and Technology College,Jinzhou,Liaoning 121001);The Monitoring Pyrethroid Pesticide Residue in Vegetables[J];Northern Horticulture;2010-02
5 LIU Fan,XIONG Zhi-chao,ZHANG Ling-yi,ZHANG Wei-bing (East China University of Science and Technology,Shanghai 200237,China);Methods for Cleaning and Regeneration of High Performance Liquid Chromatographic Columns[J];Analysis and Testing Technology and Instruments;2010-02
6 SHAN Juan1,2,YAO Guo-qi1,WANG Wen-bo3,CAO Bing1(1.Maize Institute,Shandong Academy of Agricultural Sciences,Jinan 250100,China;2.College of Agronomy,Shandong Agricultural University,Taian 271018,China;3.Central Laboratory of Shandong Academy of Agricultural Sciences,Jinan 250100,China);Gas Chromatographic Analysis of Beta-cypermethrin Residue in Maize[J];Shandong Agricultural Sciences;2010-06
7 CHEN Ming~1,et al(1.College of Environmental and Energy Engineering,Beijing University of Technology,Beijing 100022,China);Residues of Pyrethroid Pesticides in Wastewater of the Sewage Treatment Plant[J];Environmental Monitoring in China;2007-01
8 CHEN Ming,REN Ren,WANG Zi-jian,LIN Xing-tao,CHEN Sha,WU Shao-hua,LIU Li-li,ZHANG Shu-fen(1.College of Environmental and Energy Engineering,Beijing University of Technology,Beijing 100022,China;2.State Key Laboratory of Environmental Aquatic Chemistry,ResearchCenter for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China);Residues of the Tyrethrin Pesticides in Water from the Industrial and Urban Sewage in Beijing[J];Safety and Environmental Engineering;2005-04
9 LIU Yong-bo,JIA Li-hua,XUE Rui-fang,ZHANG Ming-xia(Qingdao Municipal Drainage Monitoring Centre,Qingdao 266002,China);RAPID GC-MS DETERMINATION OF RESIDUAL PYRETHROID PESTICIDES IN VEGETABLES AND FRUITS[J];Physical Testing and Chemical Analysis(Part B:Chemical Analysis);2006-08
10 Wei Xinlin1,Liu Ying1,Zhang Shaoen2,Wang Yuanfeng1 (1. School of Life and Envirnoment,Shanghai Normal University,Shanghai 200234,China; 2. Nankai Biotechnology Limited company,Hangzhou,Zhejiang 310051,China);Synthesis and Identification of Fenvalerate Specific Artificial Antigen[J];Academic Periodical of Farm Products Processing;2009-03
China Proceedings of conference Full-text Database 1 Hits
1 Yang Chengdui Song Lihui Liu Mixin Chen Peirong Department of Chemistry,Tsinghua University Beijing 100084,China;Determination of Fenvalerate Residues by GC-MS/MS[A];[C];2006
【Secondary Citations】
Chinese Journal Full-text Database 6 Hits
1 FAN Zhi-xian,ZHU Jie-li,XU Yun-cheng,HOU Zhi-guang,CHEN Dan,SHANG Me i,WANG Yang-hong(Jilin Agricultural University,Changchun 130118,China);Dynamics of Chlorpyrifos -Methyl Residues on Cabbage and Soil[J];Journal of Agro-environmental Science;2003-02
2 LI Chang Fang 1,HE Qiang 1,LUO Shi Hua 1,XU Wei Song 1,SUN Hai Bin 2 ( 1Guangdong Institute for the Control of Agrochemicals,Guangzhou 510500,China; 2Institute of Plant Protection,Guangdong Academy of Agricultural Science,Guangzhou 510640,China);Residue Studies on Cypermethrin in Litchi and Soil[J];Pesticides;2004-07
3 Gao Tianbing,and Tian Jingai (National Institute for the Control of Pharmaceutical and Biological Products,Beijing 100050) Zhang Shuming (Institute of Medicinal Plant Development,Chinese Academy of Medical Sciences & Peking Union Medical College, Bei;Determination of Residual Amount of Cypermethrin, Fenvalerate and Deltamethrin in Chinese Herbal Medicines by Capillary Gas Chromatography(CGC-ECD)[J];CHINESE JOURNAL OF PHARMACEUTICAL ANALYSIS;1999-05
4 Liu Qiankai & Zhu Guonian (Department of Plant Prolecion, Zhejiang Agricultural University, Hangzhou 310029);Studies on the residue and dissipation of alphacypermethrin on the Chinese cabbages , cucumbers and tangerines.[J];Journal of Zhejiang Agricultural University;1993-02
5 WANG Yi, ZHANG Li-ta, ZHENG Fei-neng, CHEN Fu-liang, LIANG Wen-pingInstitute of Plant Protection , Chinese Academy of Agricultural Sciences , Beijing 100094; Center for Molecular Science , Institute of Chemistry , Chinese Academy of Sciences , Beijing;The Effect of Adjuvants on Penetration of Beta-cypermethrin Across the Epidermis of Cabbage Leaf[J];Scientia Agricultura Sinica;2002-01
6 LAI Zi-ni,PANG Shi-xun,WEI Tai-li,YANG Wan-ling(Pearl River Fisheries Research Institute,Chinese Academy of Fishery Sciences,Fishery Ecoenvironment Monitoring Center of Pearl River Valley,Ministry of Agriculture,Guangzhou 510380,China);Determination and residual elimination of cypermethrin in fishery waters[J];Journal of Fishery Sciences of China;2005-02
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved