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《Environmental Science & Technology》 2013-02
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TG-FTIR Analysis on Pyrolysis Characteristics of Waste Plastics

SANG Sheng-huan,DUAN Yu-feng,CHEN Hui-chao, MAO Yong-qiu,ZHANG Ping-ping(Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education,School of Energy and Environment,Southeast University,Nanjing 210096,China)  
Pyrolysis and emission characteristics of waste plastics of a paper mill were investigated at different heating rates by using thermogravimetric analysis coupled with Fourier transfer infrared spectrometer(TG-FTIR).Results showed that the process of pyrolysis was divided into two stages including dechlorination and fracture of carbon chain by forming smaller molecules hydrogen compounds.Mass loss and peak slightly increased with increasing heating rate.Doyle method was used to analyze activation energy of waste plastic pyrolysis and it turned out that the activation energy increased with the extent of pyrolysis reaction.Dechlorination followed the three-dimensional diffusion spherically symmetric model and Jander equation was the probable function,while the fracture of carbon chain followed two-dimensional cylindrical symmetric model. Emission gases in the process of pyrolysis were almost the same at different heating rates.Hydrogen chloride and most hydrocarbons were released at the first stage and the second stage of pyrolysis respectively.
【CateGory Index】: X793
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【Citations】
Chinese Journal Full-text Database 10 Hits
1 Xu Xi, Wang Qi (Sichuan University,Chengdu 610065);NEW TECHNIQUES APPLICABLE TO POLYMER RECYCLING[J];Engineering Plastics Application;1999-03
2 Huang Haibin,Liu Feng,Li Lijuan (Faculty of Civil and Transportation Engineering,Guangdong University of Technology,Guangzhou 510006,China);REUTILIZATION OF PLASTIC AND APPLICATION OF RECYCLED PLASTIC IN CONSTRUCTION MATERIALS[J];Engineering Plastics Application;2009-07
3 Xue Daming, Quan Xie, Zhao Yazhi, Si Xiuhua, Yang Fenglin ( Res. Inst. of Environ. Eng., Dalian Univ. of Technol., China );Analysis of energy consumption and acquisition in thermal and catalytic cracking process of waste polyethylene products[J];JOURNAL OF DALIAN UNIVERSITY OF TECHNOLOGY;1997-04
4 LIAO Rui-jin1,ZHOU Xuan1,YANG Li-jun1,XIANG Bin2(1.State Key Laboratory of Transmission & Distribution Equipment and Power System Safety and New Technology,Chongqing University,Chongqing 400044,P.R.China; 2.Chongqing EHV Bureau,Chongqing 400030,P.R.China);The mid-infrared spectra characteristic of the transformer oil-paper insulation in thermal ageing process[J];Journal of Chongqing University;2011-02
5 Xu Pianpian and Zhang Fanxian (Xiamen University, Xiamen 361005);Production of Gasoline from Waste Plastics by Catalytic Cracking[J];ENVIRONMENTAL PROTECTION OF CHEMICAL INDUSTRY;1998-01
6 LI Chunyu1,JIANG Xuguang1,FEI Zhenwei1,AN Chunguo1,CHI Yong1,YAN Jianhua1,YU Kai2,FU Juanjuan2,PAN Jinhua2,SHI Zheng2(1State Key Laboratory of Clean Energy Utilization,Zhejiang University,Hangzhou 310027,Zhejiang,China;2Huzhou Industry and Hospital Waste Treatment Center Co.,Ltd.,Huzhou 313000,Zhejiang,China);TG-FTIR analysis on combustion characteristics of tannery sludge[J];CIESC Journal;2010-05
7 ZHANG Chong-min, YAN Guo, LI Chao, WANG Wen-zhong ( Inst. Anshan Iron & Steel Technol., Anshan 114002, China; Northeastern Univ., Shenyang 110006, China);Kinetics of Burning Waste Plastics[J];ENGINEERING CHEMISTRY & METALLURGY;2000-02
8 Ma Shibai Yin Jianjun Lu Jun Gao Jinsheng(East China University of Science and Technology, Shanghai, 200237);STUDY ON THE TREATMENT AND RECOVERY AS RESOURCE OFPVC WASTE: (l) KINETIC ANALYSIS OF PVCPYROLYSIS DECHLORINATION[J];Environmental Chemistry;2001-02
9 ZHENG Xuegang,TANG Lihua,NI Yanhui,YING Weiyong,ZHU Zibin(Research Institute of Chemical Technology ECUST, Shanghai 200237, China);Study on Dehydrochlorination of PVC Materials[J];Journal of East China University of Science and Technology;2003-06
10 Zhou Hu Lu Jidong Zhou HaoshengState Key Lab. of Coal Combustion, HUST 430074, China.;Study of the Prolysis of PVC with the Coupling of a TGA and FTIR[J];JOURNAL OF HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY;2000-09
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Yin Weiying, Ma Huaxian, Ren Junhe, Ren Minli, Zhang Heming, Yang Xizhen (Shandong University of Technology,Jinan 250061);THE THERMAL ANALYSES INVESTIGATION FOR PKS[J];Engineering Plastics Application;1998-07
2 Liu Minying, Gao Lijun, Zhao Qingxiang, Wang Yudong, Sun Huili, Li Xiangkui (Department of Materials & Engineering, Zhengzhou University 450052);STUDY ON THE THERMAL PROPERTY OF PF NYLON 1212[J];Engineering Plastics Application;2001-07
3 Fei Bin Qiu Jin(Qingdao Haier Joint Stock Co.Ltd.,Qingdao 266101,China) (3M China Ltd.,Beijing 100176,China);APPLICATION OF PLASTIC MATERIALS IN REFRIGERATOR MANUFACTURING[J];Engineering Plastics Application;2010-07
4 Huang Haibin(Guangdong Zhonggong Architectural Design Institute Co.Ltd,Guangzhou 510034,China);Mechanical Performance Research on Modified Concrete with Recycled ABS/PC Powder[J];Engineering Plastics Application;2012-04
5 Zhou Jie Department of Machinery Manufacturing;DEVELOPMENT AND APPLICATION OF FOUNDRY LECITHIN BINDER[J];;1988-03
6 JIAO Zhen-zhen et al(College of Material Science and Technology,Beijing Forestry University,Wood Science and Engineering of Education Ministry/Beijing Key Laboratory,Beijing 100083);Study on the Technology of Giant Reed liquefaction in Phenol[J];Journal of Anhui Agricultural Sciences;2008-12
7 ZHU Ren fa 1, DAI Ya 1, LI Cheng lie 2 (1.Hefei Institutes of Economic and Technology, 230052, Hefei, Anhui, China;2.East China University of Science and Technology, 200237, Shanghai, China);STUDY ON OXIDIZATION ABSORB SULPHUR OF De-SOx ADDITIVES BY IN SITU-TG[J];JOURNAL OF ANHUI NORMAL UNIVERSITY(NATURAL SCIENCE);1999-04
8 Zou Lizhuang; Wang XiaoLing; Zhang Peijian; Zhou Baoxue(Yantai Teacher's Collge)(Shandong Normal University);Study of Dehydration and Oxidative Decomposition Co(BPh_4)_2· 8H_2O by Thermoanalytical Method[J];Journal of Anhui Normal University(Natural Science);1994-02
9 HE Feigang(Department of Chemistry,Shaanxi Institute of Education,Xi'an 710061,Shaanxi,China);Study on the Thermal Decomposition and Its Kinetics of K_3(Al(C_2O_4)_3)·3H_2O and K_3(Cr(C_2O_4)_3)·3H_2O[J];Journal of Ankang University;2009-02
10 PANG Min1,WANG Chuang-gui1,LIU Xian-miao2(1.School of Forestry and Landscape Architecture,Anhui Agricultural University,Hefei 230036;2.Research Institute of Wood Industry,Chinese Academy of Forestry,Beijing 100091);The thermal-reaction between paper mill sludge and adhesive[J];Journal of Anhui Agricultural University;2008-03
China Proceedings of conference Full-text Database 9 Hits
1 YU Ge,GAO Yaping (Xi’an City Fire Department,Xi’an 710061);Study on Thermal Decomposition Feature of PVC Wallpaper[A];[C];2008
2 LI Lijuan, HUANG Haibin, LIU Feng (Faculty of Civil and Transportation Eng., Guangdong University of Technology, Guangzhou 510006, Guangdong, China);Mechanical Test on Modified Concrete with Recycled Plastic Particles[A];[C];2009
3 Huiyi TANG,Hua WANG,Yubi ZHANG,Lixin ZHANG,Weifan LUO Chongqing Instrument Materials Research Institute,National Instrument Functional Materials Engineering Technology Research Center,Chongqing,China,400700;Effect of the Microstructure of SiC Thermocouple Thermowells on Their Service Lifes[A];[C];2011
4 ZHANG Jin-yong,BAI Gang,ZHANG Ke-ke, HE Yu-hang, YANG Shun (Colledge of Material.Northwestem Polytechnical Univercity,xi'an 710072,China Dep.of Mater.Sci&.,Henan University of Sci &Tech.,Luoyang,471003,China);Effect of Rare Earth on the Microstructure And Performance of SnAgCuRE Solder for Micro-joining[A];[C];2006
5 Wu Fuzhong, Li Junqi, Jin Huixin~* (Material Science and Metallurgy Engineering College of Guizhou University of Technology, Guiyang 550003, China);Pulverized Coal and Waste Plastic Mixture Combustion under Blast Furnace Blasting Temperatur[A];[C];2004
6 Li Junqi, Wang Hua (School of Graduate, Kunming University of Science and Technology, Kunming, 650093, China;School of Material and Metallurgy, Guizhou University, Guiyang 55003, China);Combustion Characteristics of Waste Plastics in Alumina Manufacturing Process with Bay-suiter Combination Method[A];[C];2006
7 Yu Guangwei~1 Liao Hongqiang~1 Cai Jiuju~2 (1.Shougang Environmental Protection Industry Department,Beijing,100041; 2.State Key Laboratory of Bio-industry,Northeastern University,Shenyang 110004);The Emission of HCl During Co-pyrolysis of PVC and Coal by TG-FTIR[A];[C];2009
8 Li Fei~1, Zhao Zengli~1, Li Haibin~1,Ma Xiaoqian~2,Chen Yong~1(1.Guangzhou Institute of Energy Conversion, Guangzhou 510640, china:2.South China University of Technology, Guangzhou 510640, china);SYUDY ON PYROLYTIC CHARACTERISTICS OF ABS PPO AND POM[A];[C];2005
9 Yu Qingchun~(1,2,3),Yang Bin~(1,2,3*),Ma Wenhui~(1,2,3),Ii Zhihua~(1,2,3),Dai Yongnian~(1,2,3) (1.National Engineering Laboratory for Vacuum Metallurgy,Kunming University of Science and Technology,Kunming 650093,China;2.Vacuum Metallurgy Key Laboratory for Nonferrous Metal of Yunnan Province,Kunming University of Science and Technology,Kunming 650093,China; 3.Faculty of Material and Metallurgy Engineering,Kunming UniversityOf Science and Technology,Kunming,650093,China);Study of Carbothermic Reduction of Magnesia in Vacuum[A];[C];2008
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Yu Jie(Xian University of Architecture and Technology,Xian 710055,China);Legal Research on the Municipal Domestic Waste Sorting in China[J];Environmental Science and Management;2009-04
2 ZHANG Jin-xi ZHANG Qi LI Shuang (Key Laboratory of Traffic Engineering,Beijing University of Technology,Beijing 100022,China);Feasibility of EPS Aggregate as the Anti-freezing Material of Road[J];Journal of Beijing University of Technology;2007-09
3 LU Bo1,LIU Zhi-jun2,CHEN Nu3,LIN Kun4,WANG Guang-an4 (1.School of Civil Engineering & Architecture,Chongqing Jiaotong University,Chongqing 400074,China;2.Chongqing Highway Department,Chongqing 400040,China;3.Chongqing Highway Construction Quality Examination Center,Chongqing 400040,China;4.Chongqing Yubei District Communication Department,Chongqing 400068,China);The First Test Road with Environmental Protection in Chongqing[J];Journal of Chongqing Jiaotong University;2007-02
4 Yang Lijun1 Liao Ruijin1 Sun Huigang2 Sun Caixin1 Xiang Bin1 (1. State Key Laboratory of Transmission & Distribution Equipments and Power System Safety and New Technology Chongqing University Chongqing 400044 China 2. ABB Corporate Research Beijing 100016 China);Investigation on Properties and Characteristics of Oil-Paper Insulation in Transformer During Thermal Degradation Process[J];Transactions of China Electrotechnical Society;2009-08
5 HU Jian-hang1,WANG Hua1,LIU Hui-li1,ZHANG Feng-xia2,MA Xu-dong1(1.Institute of Environment-Harmonious Energy New Technology,Kunming University of Science and Technology,Kunming 650093,China;2.Kunming Metallurgy College,Kunming 650033,China);Gasification-melting Technology of Municipal Solid Waste[J];Environmental Science & Technology;2008-11
6 SUN Xiao-jie,WANG Hong-tao,LU Wen-jing(Department of Environmental Science and Engineering,Tsinghua University,Beijing 100084,China);Discussion on Municipal Solid Waste Collection and Classification Model in China[J];Environmental Science & Technology;2009-10
7 CHENG Bowen~1,REN Yuanlin~1,WANG Yuanlong~2,DING Changkun~1(1.Tianjin Municipal Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University,Tianjin 300160,China; 2.School of Chemistry and Chemical Technology,Shanghai Jiao Tong University,Shanghai 200240,China);Synthesis and characterization of cellulose carbamate[J];Journal of Textile Research;2007-08
8 YIN RuiyuQI YuanhongYE Caiyan(Central Iron and Steel Research Institute);FEASIBILITY AND FUTURE OF INJECTING PLASTICSCRAP INTO BF IN CHINA[J];IRON AND STEEL;1999-03
9 DOU Peng1, YANG Dao-wu1, LI Yi2, GONG Jie2 (1. College of Chemistry and Biology Engineering, Changsha University of Science & Technology, Changsha 410076, China; 2. College of Electrical and Information Engineering, Changsha University of Science & Technology, Changsha 410076, China);Analyze Aging Characteristics of Transformer Oil Based on Infrared Spectroscopy and Chaos Theory[J];High Voltage Engineering;2009-04
10 Li Bin, Wang Jianqi, Ding Yangbing (National Flame Retarded Materials Laboratory, Beijing Institute of Technology, Beijing);INVESTIGATION OF THERMAL DEGRADATION, FLAME RETARDANCE AND SMOKE SUPPRESSION OF RIGID PVC BY USING CONE CALORIMETER[J];POLYMERIC MATERIALS SCIENCE & CNGINEERING;1999-05
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