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《Environmental Science & Technology》 2017-02
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Study on Preparation and Magnetic Properties of Mn-Zn Ferrites by Using Waste Dry Batteries

LI Caixia;PENG Kun;Hunan Meteorological Service Center;College of Materials Science and Engineering,Hunan University;  
Mn-Zn ferrites with excellent soft magnetic properties were synthesized by co-precipitation and calcinations method using waste dry batteries through the process of dissolution,impurity removal and adjusting the composition of solution. The phase structures were investigated by XRD analysis,and the magnetic properties were investigated by VSM and LCR techniques. Results indicated that solution composition,degree of removal impurity and calcinations temperature are the key factors influencing the performance of ferrite. With the optimal magnetic properties of ferrite prepared by the solution of Fe∶Mn∶Zn ratio of 69∶16∶15 through removal of deep impurity,a single spinel ferrites and excellent soft magnetic properties can be obtained by removing impurity in solution and calcined at 1 200 ℃ for 4 h,its saturation magnetic induction intensity was about 432 mT and its permeability up to 8 200.
【Fund】: 国家自然科学基金(51571087)
【CateGory Index】: TM277;X705
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