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《Journal of Liaoning Shihua University》 2018-03
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Progress in Photoinduced Atom Transfer Radical Polymerization

Cui Haiqing;Cui Ye;Liu Furui;Lei Liangcai;Li Haiying;College of Chemistry,Chemical Engineering and Environmental Engineering,Liaoning Shihua University;  
Photoinduced ATRP is a controlled radical polymerization in the presence of UV/visible light and can be used to synthesize functional polymer materials which can control the molecular structure.The polymerization kinetics was studied by changing illumination time,intensity and frequency of the light source.The amount of transition metal catalyst in photoinduced ATRP polymerization is reduced to less than 100μg/g,which makes industrial application of controlled free radical technology possible.In this paper,the research progress of direct/indirect light-induced atom transfer radical polymerization(ATRP)is reviewed from the aspects of light source,catalyst,ligand and initiator.
【Fund】: 国家自然科学基金项目(21544008);; 辽宁省科技厅产业基地发展建设计划项目(2011415048)
【CateGory Index】: TQ316.322
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