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《CHINESE JOURNAL OF ANALYTIEAL CHEMISTRY》 2000-10
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Tribasic Cross-linker Molecular Imprinted Chiral Stationary Phase

Wang Jinfang,Zhou Liangmo, Liu Xueliang,Wang Qinghai,Zhu Daoqian (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012)  
Molecular imprinted polymers against N-Cbz-L-Trp utilizing 2-VP + AM as combined functional monomer and trimethylolpropane trimethacrylate (TRIM) as tribasic cross-linker were prepared and evaluated in HPLC mode.Comparing with molecular imprinted polymer (MIP) utilizing ethylene glycoldimethacrylate (EDMA) as cross-linker, it was found that MIP utilizing TRIM as cross-linker showed higher cross-link intensity and baseline chiral Separation of the template enantiomer was achieved on a shorter column. More functional monomers were used and more template molecules were imprinted in the MIP utilizing TRIM as cross-linker. This could result in more recognition cavities in the polymer and the number of the imprinted cavities in unit weight of chiral stationary phase was greater. So the capacity factor was increased and column capacity was high enough for preparation. Meanwhile, the higher specific recognition ability of the imprinted cavities to the imprinted molecule and enantiomers alike leads to the higher chiral cross-selectivity because of more ordered arrangement of the tribasic cross-linked MIP.
【Fund】: 国家自然科学基金资助项目
【CateGory Index】: O621
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【References】
Chinese Journal Full-text Database 5 Hits
1 ZHU QiuJin~(1,2) GU XiaoHong~1 TANG Jian~(1) WANG LinXiang~1 FENG Yu~1 LI GaoYang~1(1.Key Laboratory of Food Science and Safety,Ministry of Education,Southern Yangtze University,Wuxi Jiangsu 214036;2.School of Life Science,Guizhou University,Guiyang Guizhou 550025;3.Testing & Analysis Centre,Southern Yangtze University,Wuxi Jiangsu 214036,China);Interaction of 17β-estradiol and its structural analogues with functional monomers[J];北京化工大学学报(自然科学版);2007-01
2 ZHU Qiu-jin1,2,TANG Jian1,2,3,*,DAI Jun3,GU Xiao-hong3,CHEN Shang-wei3 (1.Key Laboratory of Food Science and Safety, Ministry of Education, Southern Yangtze University, Wuxi 214036, China;2.School of Food Science, Southern Yangtze University, Wuxi 214036, China;3.Analysis and Testing Centre, Southern Yangtze University, Wuxi 214036, China);Synthesis and Characterization of Molecularly Imprinted Microspheres as β-estradiol Antibody Binding Mimics[J];食品科学;2006-10
3 JIAO Feipeng HUANG Kelong YU Jingang PENG Xiahui ZHAO Xuehui NING Fengrong (College of Chemistry and Chemical Engineering,Central South University,Changsha 410083);Study on Process of Thermodynamics for Chiral Separation of Naproxen in Molecular Imprinting[J];材料导报;2005-08
4 HU, Shu Guo a WANG, Shan Wei b HE, Xi Wen , a ( a State Key Laboratory of Functional Polymer Materials for Adsorption and Separation Department of Chemistry, Nankai University, Tianjin 300071) ( b Center Lab of Nankai University, Tianjin 300071);Study of Paracetamol Molecularly Imprinted Polymers Applied to Solid Phase Extraction[J];化学学报;2004-09
5 LIU Hai-yan, YANG Geng-liang, LI Hai-ying, SUN Su-fang ,CHEN Yi ( College of Chemistry and Environmental Science,Hebei University, Baoding 071002,China; Center for Molecular Sciences, Institute of Chemistry,The Chinese Academy of Sciences,Beijing 100080,China);Immobilized Emzyme as Chiral Stationary Phases in HPLC[J];河北大学学报(自然科学版);2003-01
【Citations】
Chinese Journal Full-text Database 4 Hits
1 WANG Jin - Fang ZHOU Liang - Mo MENG Zi - Hui WANG Qing - Hai ZHU Dao - Qian ( Dalian Institute of Chemical Physics , The Chinese Academy of Sciences , Dalian, 116012 ) ( The People' s Liberation Army Academic of Military Medicine Sciences , Beijing, 100850 );Highly Efficient Molecule Imprinting Chiral Stationary Phase Utilizing Combined Basic Functional Monomers[J];化学学报;1999-10
2 MENG Zihui , WANG Jinfang , ZHOU Liangmo WANG Qinghai and ZHU Daoqian(Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012, China);New cocktail functional monomers in making molecule imprinting polymer with high chiral selectivity[J];Progress in Natural Science;1999-10
3 Meng Zihui, Zhou Liangmo, Wang Jinfang, Wang Qinghai, Zhu Daoqian (Dalian Institute of Chemical Physics, Dalian ll60l2);Cmbined Interaction in Molecule Imprinting Chiral Stationary Phase[J];分析化学;1998-10
4 Meng Zihui, Wang Qinghai, Zhu Daoqian, Zhou Liangmo (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Application of Molecular Imprinting in Chira1 Separation[J];分析化学;1997-03
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 MENG Jingyan;AN Ming;LI Hongyu;Institute of farm products process utilization,Shanxi academy of agricultural science;;Brief discussion on detection technology of food safety[J];食品工程;2015-01
2 TANG Wan-jin;ZHAO Tong;ZHOU Chun-hong;ZHANG Hai-xia;School of Chemistry and Chemical Engineering,Lanzhou University;Gansu Food Quality Supervision and Inspection Center;;Preparation of a molecularly imprinted polymer of ofloxacin with combined functional monomers[J];兰州大学学报(自然科学版);2014-01
3 Rao Cheng1,Huang Xian2(1.Department of Pharmacy,Union Clinical Medical College,Fujian Medical University,Fuzhou,Fujian,China 350001;2.Department of Pharmacy,Affiliated UnionHospital,Fujian Medical University,Fuzhou,Fujian,China 350001);Application of Affinity Chromatography in Screening Active Constituents from Natural Medicine[J];中国药业;2010-12
4 Wang Lili Su Liqiang Liang Yunkai (College of Chemistry and Chemical Engineering,Qiqihar University,Heilongjiang Qiqihar 161006);Preparation of Molecularly Imprinted Polymer of Cyprodinil and Its Characteristics[J];化工时刊;2009-03
5 Zhou Qing,Zhu Mingfang,Tang Rui,Zhang Hongwu(Guangdong Pharmaceutical University,Guangzhou 510006,China);SYNTHESIS AND CHARACTERIZATION OF 5,7-DIHYROXYFLAVONE MOLECULARLY IMPRINTED POLYMERS[J];化学分析计量;2008-05
6 WANG Chao-li, LEI Xiao, XIAO Xiang, WANG Jin, HE Wen-li (Science College of Hunan Agricultural University, Changsha 410128, China);Tradition Method in Metribuzin Imprinted Polymer[J];现代农药;2007-06
7 LIN Qui-ming1,HE Jian-feng2,Liu Lan2,DENG Qin-ying 2(1.Information of Educational Technology Center Foshan University,Foshan 528000,China;2.School of Chemistry and Chemical Engineering,Sun Yet-sen University,Guangzhoou 510275,China);Study on the effect of recognized characteristics of quercetin imprinted polymers with different functional monomers[J];化学研究与应用;2007-10
8 LI Li1,WU Wen-xiang2,YANG Geng-liang3(1.Light Industry Branch,Hebei Polytechnic University,Tangshan 063020,China;2.Center of ContinuedEducation,Langfang Teachers College,Langfang 065000,China;3.Institute of Chemistry,Chinese Academy of Sciences, Beijing 100080,China);Molecularly Imprinted Polymer as Stationary Phase in HPLC for the Separation and Recognition of Sulfamethoxazole[J];分析测试学报;2007-03
9 LIU You-qin,XU Li,YAN Yun,XU Yue-hua(Department of Applied Chemistry,College of Sciences,South China Agricultural University,Guangzhou 510642,China);Development of Molecularly Imprinted Polymer Sensor[J];分析测试学报;2007-03
10 CHEN Chang-bao,ZHOU Jie~*,WU Chun-hui(College of Chemistry and Material Science,Science,Shandong Agricultural University,Tai'an 271018,China);Progress in molecular imprinting technique[J];化学研究与应用;2006-08
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 YANG Zuo-guo,XU Zhen-liang(Research Institute of Chemical Engineering,East China University of Science and Technology,Shanghai 200237,China);Molecular Imprinted Polymers of Dibenzoyl-L-Tartaric Acid with Recognition Properties Prepared by Thermal Polymerization Method Ⅰ.Optimizing the Thermal Polymerization Conditions[J];华东理工大学学报(自然科学版);2005-05
2 ZHU Xiu-fang, HOU Neng-bang, WANG Guo-song, CAO Qiu-e, DING Zhong-tao(Department of Chemistry, Yunnan University, Kunming 650091, China);Rapid Screening for Non-convalented Molecular Imprinted Systems[J];云南化工;2005-01
3 Zheng Ximing 1,2 Tu Weiping 1 (1 Institute of Chemical Engineering of SCUT,Guangdong Guangzhou 510640; 2 Department of Chemistry and Environment Engineering,Nanping Teachers College,Fujian Nanping 353000);Particle Size and Size Distribution of Molecularly Imprinted Polymeric Microspheres[J];化工时刊;2004-06
4 LU, Chun-Yanga HE, Hai-Chengb MA, Xiang-Xiaa ZHANG, Jiaa HE, Xi-Wen ,a ( a Department of Chemistry, State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071) ( b Department of Chemistry, Langfang Normal College, Langfang 065000);Preparation and Evaluation of Molecularly Imprinted Polymers Using Herbicide Picloram as Template[J];化学学报;2004-08
5 Li Ping Rong Fei Xie Yibing Zhu Xinle Yuan Chunwei ( 1Department of Biomedical Science and Medical Engineering, Southeast University, Nanjing 210096, China) ( 2Department of Bioengineering, Beijing University of Aeronautics and Astronautics, Beijng 100083, China);Study on binding characteristics of (S)-naproxen imprinted polymer and performance of its complexes during preparation[J];东南大学学报(自然科学版);2003-04
6 SUN Rui-feng, LUO Hui, SUI Hong-yan, SHEN Zhong-yao (Institute of Biochemical Engineering, Dept. Chem. Eng., Tsinghua University, Beijing 100084, China);Application of Stoichiometric Displacement Model for Retention to the Chromatographic Separation by Molecular Imprinting Polymer[J];过程工程学报;2003-02
7 LEI Jian-Du, TAN Tian-Wei * (Department of Biochemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China);Chiral Separation on Naproxen and Determination of Chromatography Equilibrium Constant Using Molecular Imprinting[J];高等学校化学学报;2002-11
8 LEI, Jian-Du TAN, Tian-Wei (Department of Biochemical Engineering, Beijing University of Chemical Technology, Beijing 100029);Chiral Separation of Ketoprofen and Thermodynamic Study in Molecular Imprinting[J];化学学报;2002-07
9 LEI Jian du, TAN Tian wei (Department of Biochemical Engineering,Beijing University of Chemical Technology,Beijing 100029, China);Chiral separation of naproxen on molecular imprinted polymers[J];现代化工;2001-08
10 Liu Qin, Zhou Yongxin, Meng Zihui, Wang Qingqing, Hu Xuying, Liu Yintang (Beijing Institute of Pharmacology and Toxicology, Beijing 100850);Determination of Nerve Agent Degradation Products in Rice by Molecule Imprinting Polymer-Solid Phase Extraction and Capillary Electrophoresis[J];分析化学;2001-04
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LIU Yu-jian;LIU Zhi-min;XU Zhi-gang;Faculty of Science,Kunming University of Science and Technology;;Chiral separation and determination of naproxen enantiomers in chiral drugs[J];化学研究与应用;2017-01
2 TAO Qiang;ZHANG Juankun;LIU Yingzi;JU Xiaocui;ZUO Juanjuan;Key Laboratory of Industrial Fermentation Microbiology,Ministry of Education,Tianjin Key Laboratory of Industrial Microbiology,College of Biotechnology,Tianjin University of Science & Technology;;Quick Detection of DINP in Samples by Molecular Imprinted Sensor[J];天津科技大学学报;2016-05
3 Huang Yunan;Lu Kuan;Zhu Qiujin;School of Liquor & Food Engineering, Guizhou University;Key Laboratory of Agricultural and Animal Products Store and Processing of Guizhou Province;;Studies on Preparation and Release Characteristics of Allyl Isothiocyanate Molecularly Imprinted Polymer[J];中国食品学报;2016-08
4 HAN Shuang;Harbin Institute of Petroleum;;Study on Application of Molecularly Imprinted Polymer in the Field of Separation[J];当代化工;2016-03
5 ZUO Hai-gen;DING Yuan;LIU Shu-fen;ZHANG Hao-bin;GUO Ping;ZHU Jian-xin;Jiangxi Entry-Exit Inspection and Quarantine Bureau;College of Science,Nanjing Agricultural University;College of Environmental and Chemical Engineering,Nanchang Hangkong University;;Research and Application of Estradiol Molecular Imprinting Technique[J];理化检验(化学分册);2014-08
6 ZHANG Tie-li*,LIU Zheng-yuan,ZHANG Hui,MENG Qing-zhao (Tangshan Key Laboratory of Biology&Chemistry,Department of Chemistry,Tangshan Teachers College,Tangshan 063000,China);Preparation and molecular recognition properties of indole-3-acetic acid-imprinted polymers[J];化学研究与应用;2013-07
7 Fan,Cunhua Yang,Yiqun Zhao,Wei Xiao,Yu Luo,Jing Liu,Xiaoya*(The Key Laboratory of Food Colloids and Biotechnology,Ministry of Education,School of Chemical and Material Engineering,Jiangnan University,Wuxi 214122);Research on Amphiphilic Copolymer MIP Micelles Electrochemical Sensor[J];化学学报;2013-06
8 WANG Ji-hong(Expermental Center,MinXi Vocational and Technical College,Longyan 364021,China);Study on extracting fisetin from Toxicodendron sylvestre[J];实验室科学;2012-06
9 LU Kuan1,ZHU Qiu-jin1,2(1.College of Life Science,Guizhou University,Guiyang 550025,China; 2.Food Science & Engineering Research Center,Guizhou University,Guiyang 550025,China);The recognition mechanism and evaluation method of molecular imprinting technique based on β-cyclodextrins[J];功能材料;2012-S1
10 HAN Yan-ting,MA Jin-qin,YUE Xuan-feng,ZHANG Jing(Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province, College of Chemistry and Chemical Engineering, Shaanxi Normal University,Xi′an 710062,Shaanxi,China);Preparation of lysozyme based molecularly imprinted polymers and its chromatographic evaluation[J];陕西师范大学学报(自然科学版);2012-04
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