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《Chinese Journal of Analytieal Chemistry》 2002-04
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Non-covalently Molecularly Imprinted Polymer as a Chiral Stationary Phase to Resolve the Enantiomers of Carnitine Hydrochloride

Li Xiaotao 1, Jiang Guangguang 2, Shi Yuehua 1, Xu Zhude *1 1(Department of Chemistry, Zhejiang University, Hangzhou 310027) 2(Department of Chemical Engineering, Zhejiang University, Hangzhou 310027)  
Molecularly imprinted polymers (MIPs) were synthesized using L carnitine as the template, ethylene glycol dimethacrylate as the cross linker, methacrylic acid (MAA) and acrylicamine (AA) as the functional monomer respectively. The prepared polymers were applied as the liquid chromatographic chiral stationary phase to test their resolution ability for racemic carnitine hydrochloride. The results showed that racemic carnitine hydrochloride could be efficiently resolved on the MAA MIPs with a separation factor of 1.89.
【Fund】: 浙江省分析测试基金资助项目 (No .0 0 12 6)
【CateGory Index】: O658
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