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《Chinese Journal of Analytical Chemistry》 2003-01
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Determination of Lomefloxacin by Charge-Transfer Reaction with Micelle-Stabilized Ultraviolet Spectrophotometry

Du Liming *, Xu Qingqin, Cao Ximin, Liang Lili, Huo Yaqiong (Analytical and Testing Center, Shanxi Normal University, linfen 041004)  
A new ultraviolet spectrophotometric method for the determination of lomefloxacin (LMX) has been developed based on the charge transfer reaction with micelle stabilized. The UV spectrum characteristics of charge transfer complex formed between LMX as the donor and chloranil (TCBQ) as the acceptor in cetylpyridinium bromide (CPB) micellar system was studied. Experimental results shows that stability of the complex is remarkably enhanced by CPB micellar system. The composition of the complex was found to be 1∶1 by Bent French and molar ratio methods. Beer′s law is obeyed in the range of 0.8~54 mg/L of LMX. r =0.9994. The apparent molar absorptivity of LMX complex at 323 nm is 3.56×10 4 L·mol -1 ·cm -1 . The proposed method has been applied to the determination of LMX in tablets. The recoveries are 97.8%~100.5%. The relative standard deviation is 0.9%~2.4%.
【Fund】: 山西省自然科学基金资助课题 (No .2 0 0 110 16)
【CateGory Index】: O657.3
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Chinese Journal Full-text Database 10 Hits
1 Liu Erbao *1,2 ,Wei Hongqing 1,Zhang Aihong 1,Han Suqin 1,Ji Xinghu 1,Cheng Jieke 2 1(Department of Chemistry,Shanxi Normal University,Linfen 041004) 2(Department of Chemistry,Wuhan University,Wuhan 430072);Determination of Lomefloxacin by Chemiluminesence[J];Chinese Journal of Analytical Chemistry;2004-07
2 Wang Xiaorong *, Li Guihua, Tang Qinghua, Pan Linlin, Fan Shuyun (Department of Chemistry, Yantai Teachers University, Yantai 264025);Spectrophotometric Determination of Quinine by Charge-Transfer Reaction Between Quinine and Chloranilic Acid with Micelle-Sensitized[J];Chinese Journal of Analytical Chemistry;2004-08
3 Du Liming*, Fu Mi, Du Yaqin (Center of Analysis and Test, Shanxi Normal University, Linfen 041004);The Fluorescence Characteristics of Charge Transfer Complexes of Norfloxacin and Their Application[J];Chinese Journal of Analytical Chemistry;2005-03
4 Du Liming~*, Zhang Lifang, Yang Baogang, Hu Pengjuan(Center of Analysis and Test, Shanxi Normal University, Linfen 041004);Spectrophotometric Determination of Astemizole by Change-transfer Reaction[J];Chinese Journal of Analytical Chemistry;2005-08
5 Li Huakan~ (Jinzhou Medical College, Jinzhou 121001) Xiao Jingkun (Environment Science and Engineering College, Dalian Maritime University, Dalian 116026);Spectrophotometric Determination of Clarithromycin Based on the Charge Transfer Reaction between Clarithromycin and Purpurin[J];Chinese Journal of Analytical Chemistry;2005-09
6 CHEN Huai-xia~*,XU Hai-e,LI Yue-ying(Faulty of Chemistry and Material Science,Hubei University,Wuhan 430062);The Effect of Surfactant Micelles on the Dissociation Constants and the Colour-changing Points and Ranges of Acid-base Indicators[J];Journal of Analytical Science;2006-03
7 TAO Yu-long*1,AODENG Gao-wa1,ZHOU Xing-jun1,A Juan2 (1.College of Chemistry and Chemical Engineering,Neimongol University,Hohhot 010021;2.Department of Basic Curriculum,Agricultural University.Inner Mongolia.Hohhot 010019);Spectrophotometric Determination of Enoxacin Based on Charge Transfer Reaction[J];Journal of Analytical Science;2007-01
8 CHAI Yi feng ,WU Yu tian andLI Xiang(Department of Pharmaceutical Analysis ,College of Pharmacy ,Second Military edical University ,Guohe Road 32 5 , Shanghai 2 0 0 4 33);Pharmaceutical Analysis (Ⅱ)[J];Analytical Laboratory;2004-07
9 DU Li-ming, ZHOU Jing, YUAN Jian-mei Analytical and Testing Center, Shanxi Teacher's University, Linfen 041004, China;Fluorescence Spectroscopy Determination of Lomefloxacin by Charge Transfer Complex Formation with Chloranilic Acid[J];Spectroscopy and Spectral Analysis;2004-12
10 ZHAO Hui,LI Zhan-ling (Department of Chemistry,Zhoukou Normal University,Zhoukou 466000,China);Advance in research for spectrophotometric determination by charge-transfer reaction[J];Chemical Reagents;2008-09
China Proceedings of conference Full-text Database 1 Hits
1 ;衍生化气相色谱法测定药物制剂中的培氟沙星[A];[C];2005
Chinese Journal Full-text Database 1 Hits
1 Hu Changqin,Jiang Jiang and Gu Daozhao (National Institute for the Control of Pharmaceutical and Biological Products,Beijing 100050);Specificity of Chloranil Charge transfer Reaction for Determination of the Content of Fluoquinolone Antibiotics[J];CHINESE JOURNAL OF PHARMACEUTICAL ANALYSIS;1999-06
Chinese Journal Full-text Database 5 Hits
1 LIU Hao QU Ling-Boa LIN Lina XIANG Bing-Renb(Department of Pharmacy,Guangdong Vocational College of Chemical Engineering and Pharmaceutics,Guangzhou 510520,P.R.China)a(Department of Chemistry,Zhenzhou University,Zhenzhou 450052,P.R.China)b(Center for Instrumental Analysis,China Pharmaceutical University,Nanjing 210009,P.R.China);Study on Charge Transfer Reaction and Fluorescence Characteristic of Ofloxacin[J];Chinese Journal of Spectroscopy Laboratory;2007-03
2 DU Li-ming, ZHOU Jing, YUAN Jian-mei Analytical and Testing Center, Shanxi Teacher's University, Linfen 041004, China;Fluorescence Spectroscopy Determination of Lomefloxacin by Charge Transfer Complex Formation with Chloranilic Acid[J];Spectroscopy and Spectral Analysis;2004-12
3 Yao Wu (Department of Chemistry, Huangshan University, Huangshan245041, China);The Progress of Studies on the Analysis and Determination of Fluoroquinolone by chemiluminescence and electrochemiluminescence methods[J];Journal of Huangshan University;2010-03
4 ZHUANG Huirong(Department of Chemistry and Enviromental Science, Linyi Teachers' College,Linyi Shandong 276005,China);Charge Transfer Complex and it's Application in Pharmaceuticals Analsis[J];Journal of Linyi Teachers' College;2002-06
5 SI Qin~1 AODENG Gao-wa~(1**) TAO Yu-long~1 A Juan~21.College of Chemistry and Chemical Engineering,Neimongol University,Hohhot 010021,China;2.Department of Basic Curriculum,Agrieuhural University,Inner Mongolia,Hohhot 010019,China;Spectrophotometric determination of norfloxacin based on charge transfer reaction[J];Chinese Journal of Pharmaceutical Analysis;2007-01
Chinese Journal Full-text Database 10 Hits
1 CHU Ming-jie et al(School of Science,Anhui Agricultural University,Hefei,Anhui 230036);Application of Ionic Liquids in Extraction and Chromatography[J];Journal of Anhui Agricultural Sciences;2008-14
2 WAN Qing,CHENG Zheng,WANG Jian(Anhui Tongling Institute for Drug Control,Tongling244000,China);Determination of pediatric compound sulfamethoxazole granules with RP-HPLC[J];Anhui Medical and Pharmaceutical Journal;2005-09
3 WU He-zhen~1,JIANG Yu~2 (1.Anqing Vocational Technology College,Anqing 246003; 2.Huaining Middle School of Anhui Province,Huaining 246100,China);The Application of Fluorescein-phenosafranine Energy Transter System to the Determination of DNA[J];Journal of Anqing Teachers College(Natural Science Edition);2005-03
4 FENG Jianzhang, ZHONG Hengwen (Department of Chemistry, Peking University);Charge Transfer Reaction and Its Application in Analytical Chemistry Ⅰ. Determination of Propranolol Hydrochloride[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1991-06
5 ZHOU Xuguang, JIANG Xiaozhen,FENG Jianzhang (Department of Chemistry, Peking University);Study on Charge Transfer Reaction of Sulfadiazine with Benzoquinones Reagent[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1993-02
6 XU Bianzhen\ ZHAO Fenglin\ TONG Shenyang (College of Chemistry and Molecular Engineering,Peking University.Beijing,100871);Spectrophotometric Determination of Amrinone in Pharmaceutical Preparations Based on Charge Transfer Complex[J];ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS;1997-06
7 GUO Hong ling GUO Xiao yong YAN Bao zhen (College of Science, Beijing University of Chemical Technology, Beijing 100029, China);Formation of CTC by 2-chloro-5-methoxyl-p-benzoquinone and tertiary amines in acetonitrile[J];Journal of Beijing University of Chemical Technology;2003-03
8 Nie Lihua Zhao Huichun Wang Xuebin Wang Xu (Department of Chemistry, Beijing Normal University, 100875, Beijing, China);STUDY ON THE INTERACTION OF BOVINE SERUM ALBUMIN AND FLEROXACIN BY FLUORESCENCE METHOD[J];Journal of Beijing Normal University(Natural Science);2001-01
9 Cao Erxin Zeng Yonghuai Gao Hongyan (Department of Chemistry, Beijing Normal University, 100875, Beijing, China);ADSORPTIVE VOLTAMMETRIC BEHAVIOR OF LOMEFLOXACIN AND ITS APPLICATION[J];Journal of Beijing Normal University(Natural Science);2001-02
10 Hu Changwen;Gao Lijuan;Wang Enbo(Department of Chemistry,Vortheast Normal University.Changchun,130024)Okuhara Toshio;Misono Makoto (Department of Applied Chemistry,Fuculty of Engineering,the University of Tokyo,Tokyo,113);Acid Strength and Catalytic Property of Heteropolyacids of Keggin Structure Having Tungsten as the Addenda Atom-Effects of the Central Atom of H_αXW_(12)O_(40)[J];JOURNAL OF NORTHEAST NORMAL UNIVERSITY (NATURAL SCIENCE EDITION);1995-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LI Li et al (Department of Chemistry,Zunyi Normal College,Zunyi,Guizhou 563002);Determination of Chlorpyrifos-methyl by H_2O_2-luminol Chemiluminescence Method[J];Journal of Anhui Agricultural Sciences;2009-31
2 LIU Zhao (Fujian Inspection and Research Institute for Product Quality,Fuzhou,Fujian 350002,China);The Research on Charge Transfer Reaction Between Teyptophan and Tetracloro-Benzoquinone[J];Quality and Technical Supervision Research;2010-05
3 YAN Mei,HAN Yan-yan,XU Yuan-yuan,XIA Yang,CAI Yan-yan,ZHANG Li-na,WEI Qin(School of Chemistry & Chemical Engineering,University of Jinan,Jinan 250022,China);The Application of Capillary Electrophoresis to the Pharmaceutical Separation and Analysis[J];Analysis and Testing Technology and Instruments;2008-02
4 LIU Jia-chuan,LI Hua-kan,WANG Yu-hua (Department of Chemistry,Liaoning Medical College,Jinzhou 121001);Spectrophotometric Determination of Metoclopramide Based on the Charge-Transfer Reaction between Metoclopramide and Purpurin[J];Journal of Analytical Science;2010-03
5 YU Li-li,LI Hua-kan,ZHAO Gui-zhi(Department of Chemistry,Liaoning Medical College,Jinzhou,Liaoning 121001);Study on the Charge Transfer Reaction Between Atenolol with Quinalizarin[J];Journal of Analytical Science;2010-05
6 Fu Ruo-nong(Department of Chemistry Beijing Institute of Technoligy, Beijing 100081);Advances on gas chromatography in China in recent two years(Ⅱ)[J];Analytical Laboratory;2005-05
7 LIU Wei,PEI Cui-jin and ZHANG Zhu-jun~*(College of Chemistry and Materials Science,Shaanxi Normal University,Xi'an 710062);A flow-injection chemiluminescence method for determination of hydrobenzole hydrochloride[J];Chinese Journal of Analysis Laboratory;2006-07
8 LIU Bao-sheng1,FU Li2,WANG Yun-ke1,CAO Dong-lin3 and L Yun-kai1(1.Center of Physics and Chemistry,Hebei University,Baoding 071002;2.Department of Chemistry,Langfang Teachers College,Langfang 065000;3.Hebei University of Engineering,Handan 056038);Determination of lomefloxacin by spectrophotometry with ternary complex of copper-lomefloxacin-tetrabro-mofluorescein[J];Chinese Journal of Analysis Laboratory;2007-09
9 XU Xing-zhi,ZHANG Yin,YANG Ya-ling* and LIU Mou-sheng(Faculty of Life Science and Technology,Kunming University of Science and Technology,Kunming 650224);Fluorescence spectrometric determination of benzylpenicillin residues in milk by charge-transfer reaction[J];Chinese Journal of Analysis Laboratory;2011-07
10 LI li1,FENG Lin2,LI Liang-liang1 and LIU Yan1(1.Department of Chemistry,Zunyi Normal College,Zunyi 563002;2.College of Chemistry,Chongqing Normal University,Chongqing 400047);Study on the chemiluminescence system of KMnO_4-luminol-diosmetin[J];Chinese Journal of Analysis Laboratory;2011-10
China Proceedings of conference Full-text Database 2 Hits
1 Wang lexin 1,2 Zhao zhimin 2 (1 Heilongjiang Bayi Agricultural University,Daqing 163319;2 Nanjing University of Aeronautics and Astronautics,Nanjing 210016);Research on resonance scattering spectroscopic of normal serums and abnormal serums[A];[C];2010
2 Li Xianwen, Du Jianxi, Hao Xinmin (Science School, Guangdong Ocean University, Zhanjiang 524088, P.R. China);Study on Quinine Sensor by Ion Sensitive Field Effect Transistor[A];[C];2006
【Secondary Citations】
Chinese Journal Full-text Database 5 Hits
1 Zhou Xuguang(Jinzhou Medical College)Feng Jianzhang . Tong Shenyang(Department of Chemistry. Peking University , Beijing 100871);Charge Transfer Reaction and Its Application in the Analytical ChemistryⅢ . Study on the Determination of the Norfloxacin[J];Chinese Journal of Analytical Chemistry;1993-02
2 Zhou Xuguang; Wang Yongjie; Zhang Yaqiu; Feng Li;(Jinzhou Medical College, Jinzhou 121001)Zhang Na(Liaoning College of Traditional Chinese Medical Science, Shenyang 110032);Charge-Transfer Reactions Between Electron Acceptors and Norfloxacin[J];Chinese Journal of Analytieal Chemistry;1996-10
3 Xuan Chunsheng; Ren Suocai; Song Jianling and Wang Zhongying(Applied Chemical Department. Taiyuan University of Technology, Taiyuan, 030024);Spectrophotometric Determination of Ciprofloxacin using Tetrachlorobenzoquinone[J];CHINESE JOURNAL OF PHARMACEUTICAL ANALYSIS;1996-03
5 ZHAO Yi-Shu;HU Ling;WANG Xiu-Li (Department of Basic Courses,Anhui College of Traditional Chinese Medicine,Hefei 230038);SPECTROPHOTOMETRY OF NORFLOXACIN WITH CHARGE TRANSFER REACTION[J];CHINESE JOURNAL OF PHARMACEUTICALS;1995-12
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