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《Chinese Journal of Analytical Chemistry》 2006-06
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Chiral Separation Ability of Metal-Complexing Imprinted Polymer for L-mandelic Acid

Liu Ying,Ding Guosheng,Xu Xiuming,Hao Weiqiang,Wei Guilin,Wang Junde~*(Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116012)  
Metal-complexing imprinted polymer for L-mandelic acid was prepared using Cu(Ⅱ)-\iminodiacetic acid as functional monomer,trimethylolpropane trimethacrylate as crosslinker and methanol as porogenic agent.Chiral separation ability of metal-complexing imprinted polymer to D,L-mandelic acid was investigated by high performance liquid chromatography.The mobile phase conditions(pH,methanol content, buffer concentration,etc.) could significantly influence the chiral separation ability of metal-complexing imprinted(polymer).Highly chiral selective to the template molecule by metal-complexing imprinted(polymer) was achieved as pH 7-9 of the mobile phase;the chiral separation ability of metal-complexing(imprinted) polymer was increased with the increase of methanol content and buffer concentration.It is suggested the feasibility to prepare highly selective molecularly imprinted polymer in polar solvent.
【Fund】: 国家自然科学基金资助项目(No.29635026)
【CateGory Index】: O631.3;O657.7
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Chinese Journal Full-text Database 2 Hits
1 Lai Jiaping, He Xiwen *, Guo Hongsheng (Department of Chemistry, Nankai University, Tianjin 300071) Liang Hong (Chemistry and Life College, Guangxi Normal University, Guilin 541004);A Review on Molecular Imprinting Technique[J];Chinese Journal of Analytieal Chemistry;2001-07
2 Huang Xiaojia, Wang Junde *, Liu Xueliang, Cong Runzi (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Preparation and Evaluation of Alkyl-amine Reversed Phase High Performance Liquid Chromatographic Packing[J];Chinese Journal of Analytieal Chemistry;2002-08
Chinese Journal Full-text Database 10 Hits
1 He Yonghong, Gao Zhixian, Chao Fuhuan (Institute of Hygiene and Environmental Medicine, Academy of Military Medical Sciences, Tianjin 300050);The Progress of the Study on Molecular Imprinting-Based Biomimetic Sensors[J];Chinese Journal of Analytical Chemistry;2004-10
2 Zhang Jing, He Langchong *, Fu Qiang (College of Medicine, Xi′an Jiaotong University, Xi′an 710061);Preparation of Strychnine Molecularly Imprinted Monolithic Column[J];Chinese Journal of Analytical Chemistry;2005-01
3 Jiang Ming~ 1,2 , Lin Yi~2,Zhang Jianghua~ 1 , Mei Surong~1, Lü Bin~1 ~1(Key Laboratory of Environment & Health of Ministy of Education, Institute of Environmental Medicine, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan 430030) ~2(School of Pharmacy, Tongji Medical College, Huazhong University of Science and Technology, Wuhan 430030);Determination of Ultra-trace Bisphenol A in Water Samples by Chromatography with Large Volume Direct Injection[J];Chinese Journal of Analytical Chemistry;2006-10
4 WANG Sui,CHANG Xi-jun GONG Guo-quan College of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou 7300 00,China;Studies on Photoluminescence Characteristics of Curcumin in Acrylamide Polymer[J];Spectroscopy and Spectral Analysis;2004-03
5 ZHANG Jie 1,WANG Yong-jian *2 ,YU Ao 1 (1.College of Chemistry,Nankai University,Tianjin 300071,China;2.Key Laboratory of Bioactive Materials,Ministry of Education,Nankai University,Tianjin 300071,China);The application of molecular imprinting technique in steroid recognition and analysis[J];Chemical Reagents;2005-06
6 SUN, Bao-Wei WU, Li-Qing LI, Yuan-Zong (Key Laboratory of Bioorganic and Molecular Engineering, Department of Chemical Biology, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871);Experimental and Theoretical Study on p-Hydroxybenzoic Acid Imprinted Polymers with Different Functional Monomers[J];Acta Chimica Sinica;2004-06
7 WANG Xia~(1,2), LI Yong-min~(1*), CHEN Li-ren~(1*)(1.Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000,Gansu,China;2.Graduate School of the Chinese Academy of Sciences, Beijing 100039,China);Progress in Preparation of Monolithic Column for Capillary Electrochromatography[J];Chemical Researches;2005-01
8 LI Hong xia 1,2 ,ZHANG Jun jie 1,2 ,HE Xi wen 1* ,LI Lan ying 2 (1.Department of Chemistry,Nankai University,Tianjin 300071,China; 2.Department of Chemistry,Hebei Science and Technology University,Tangshan 063009,China);Highly selective separations by capillary electrochromatography with molecular imprint-based stationary phases[J];Chemical Research and Application;2002-05
9 DUAN Yu,Du Zong-liang~*,LI Rui-xia,WU Da-cheng (Institute of Textile,Sichuan University,Chengdu 610065,China);Silica-based stationary phases containing polar functionalities for high performance liquid chromatography[J];Chemical Research and Application;2004-02
10 ZHOU Qin,YUAN Xiao-yi(Department of Environmental Engineering,South China University of Technology.Guangzhou 510640,China);Application of Molecular Imprinting Technique in the Environmental Field[J];Bulletin of Science and Technology;2005-01
【Secondary Citations】
Chinese Journal Full-text Database 8 Hits
1 Meng Zihui, Wang Qinghai, Zhu Daoqian, Zhou Liangmo (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Application of Molecular Imprinting in Chira1 Separation[J];Chinese Journal of Analytieal Chemistry;1997-03
2 Zhou Jie, Han Hongyan, He Xiwen , Shi Huiming (Department of Chemistry, Nanism. University, Tianjin, 300071);Selective Enrichment and Direct Determination of Trace Drug by Solid-phase Extraction[J];Chinese Journal of Analytical Chemistry;1999-01
3 Liu Qin, Zhou Yongxin , Liu Yintang (Beijing Institute of Pharmacology and Toxicology, Beijing 100850);Recent Progresses in Research on Molecular Imprinting Sensors[J];Chinese Journal of Analytical Chemistry;1999-11
4 GUO Hong Sheng, HE Xi Wen , DENG Chang Hui, LI Yi Jun (Department of Chemstry, The Key Lab of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071, China);Studies of Selective Enrichment and Recognized Characteristics of Paracetamol Molecular Template Polymer[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-03
5 ZHOU Jie, HE Xi Wen *, YANG Wan Long, SHI Hui Ming (Department of Chemistry, Nankai University, Tianjin, 300071);Studies on Character of Adsorption and Recognition of Etharidine Template Polymer[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1998-09
6 Meng Zihui (Institute of Pharmacology and Toxicology, Academy of Military Medical Sciences, Beijing 100850,China) Wang Jinfang Zhou Liangmo Wang Qinghai\ Zhu Daoqian (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 11601;Progress of Molecule Imprinting Technique[J];PROGRESS IN CHEMISTRY;1999-04
7 Meng Zihui; Wang Jinfang; Zhou Liangmo; Wang Qinghai and Zhu Daoqian(Dalian Institute of Chemical Physics, the Chinese Academy of Sciences, Dalian, 116012) (Academy of Military Medicine Sciences, Beijing, 100850);Beaded Molecule Imprinted Polymer for Stereo Isomer Separation[J];Chinese Journal of Chromatography;1999-04
8 Zhou Jie,He Xiwen (Department of Chemistry,Nankai University,Tianjin 300071);Application of Molecular Template Polymers in Analytical Chemistry[J];JOURNAL OF INSTRUMENTAL ANALYSIS;1998-05
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